{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"发展了一种可见光诱导的活泼烯烃串联自由基环化合成含氟异喹啉二酮的反应.在可见光诱导下,多种N-烷基-N-甲基丙烯酰基苯甲酰胺与二氟溴乙酸乙酯发生自由基串联环化反应,以66％～75％的产率合成了一系列具有潜在生理活性的二氟烷基化异喹啉二酮.此研究为合成具有潜在药用价值的氟取代异喹啉二酮提供了一条高效、条件温和的途径.","authors":[{"authorName":"李捷","id":"1c0ddcd1-dc80-4262-9fa6-1f46d87ac9ae","originalAuthorName":"李捷"},{"authorName":"刘益林","id":"18c9a59e-fc8a-4dd4-b399-89e601ecc22c","originalAuthorName":"刘益林"},{"authorName":"邓佑林","id":"fc7709f3-bafe-4183-a339-88a4885c2947","originalAuthorName":"邓佑林"},{"authorName":"王文新","id":"8005b88f-c581-4613-ad1b-0fc384af4223","originalAuthorName":"王文新"},{"authorName":"王硕文","id":"6f2c3ab2-18ea-416f-bf83-907fc3a398ca","originalAuthorName":"王硕文"},{"authorName":"李增增","id":"ac764c64-865f-43ed-807d-e5e8cbd87b1d","originalAuthorName":"李增增"},{"authorName":"唐石","id":"16ba3320-5085-45fb-846d-ea216d935a5a","originalAuthorName":"唐石"}],"doi":"10.11944/j.issn.1000-0518.2016.06.150316","fpage":"677","id":"536975cc-c9f8-4050-b243-7b5cfe59e8bb","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"6b78e679-e622-4ece-9aef-34c076c31617","keyword":"可见光诱导","originalKeyword":"可见光诱导"},{"id":"b2581081-8461-4644-8619-2055e1592c40","keyword":"二氟烷基化","originalKeyword":"二氟烷基化"},{"id":"bf464e99-48b9-4dcb-9681-b3e06946a1db","keyword":"铱光催化剂","originalKeyword":"铱光催化剂"},{"id":"c82435e7-64bd-464a-8501-122120a490d5","keyword":"异喹啉二酮","originalKeyword":"异喹啉二酮"}],"language":"zh","publisherId":"yyhx201606009","title":"可见光诱导烯烃环化合成二氟烷基化异喹啉二酮","volume":"33","year":"2016"},{"abstractinfo":"发展了一种可见光诱导的活泼烯烃与全氟碘代烷串联加成环化合成多氟异喹啉二酮的反应.在可见光诱导下,多种N-丙烯酰基-N-丁基苯甲酰胺衍生物与全氟碘代烷发生自由基串联加成环化反应,以54％～80％的产率合成了一系列的多氟取代异喹啉二酮衍生物.为具有潜在药用价值的多氟取代异喹啉二酮合成提供了一条高效、条件温和、绿色的新途径.","authors":[{"authorName":"邓佑林","id":"4cd6ae03-8cd3-49d9-93c4-a5a2a8d02211","originalAuthorName":"邓佑林"},{"authorName":"唐石","id":"09f8cc89-dcb9-44fe-a06f-353fbe56ec85","originalAuthorName":"唐石"},{"authorName":"张倩","id":"88d57e49-d74d-4095-b3dd-7d6b0d5a0297","originalAuthorName":"张倩"},{"authorName":"王琼","id":"b5088180-1781-4456-96fb-2df2e9ae7855","originalAuthorName":"王琼"},{"authorName":"彭梦璐","id":"94d9fda2-8873-49c4-9be3-25ac99f1ad66","originalAuthorName":"彭梦璐"},{"authorName":"于丽敏","id":"e1b8500d-338b-4e8e-93fe-80e2122a0f70","originalAuthorName":"于丽敏"}],"doi":"10.11944/j.issn.1000-0518.2016.06.150317","fpage":"685","id":"527963dd-f38f-420d-a510-6ed293b4ed15","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"acb81202-fa88-4432-839a-97913d680390","keyword":"可见光诱导","originalKeyword":"可见光诱导"},{"id":"c0805c69-d98b-4248-a932-07a78e8652e9","keyword":"C-H环化","originalKeyword":"C-H环化"},{"id":"d7d813e9-d1e1-448b-8a64-b19459d6630d","keyword":"全氟烷基碘","originalKeyword":"全氟烷基碘"},{"id":"51706f00-df52-40b3-842c-d885e733f7d8","keyword":"多氟取代异喹啉二酮","originalKeyword":"多氟取代异喹啉二酮"}],"language":"zh","publisherId":"yyhx201606010","title":"可见光诱导烯烃串联加成环化合成多氟烷基化异喹啉二酮","volume":"33","year":"2016"},{"abstractinfo":"本文以FeSO4为原料,添加微量EDTA可见光诱导,空气氧化Fe(OH)2?:悬浮液,室温(20 ℃)制备了γ-FeOOH,探讨了各种因素对产物的影响.结果表明:用NaOH作沉淀剂,pH值为8.6,在EDTA作用下可见光诱导有利于低晶γ-FeOOH的生成;pH值在8.0～8.6范围内,随pH值的降低,产物γ-FeOOH的晶化度逐渐提高;用NH3·H2O作沉淀剂,可得到粒径较大的筏状γ-FeOOH.","authors":[{"authorName":"","id":"5072aaf9-2397-4f66-b723-9f4762aaed22","originalAuthorName":""},{"authorName":"陈汝芬","id":"d309dcdc-ff93-4146-b556-28a2b9ae14b0","originalAuthorName":"陈汝芬"},{"authorName":"","id":"b528116a-fcb5-4094-950f-149342b2c5e8","originalAuthorName":""},{"authorName":"魏雨","id":"19c4e57f-8c8e-4fbd-9221-9c0f46b24f70","originalAuthorName":"魏雨"},{"authorName":"","id":"c44498db-610a-469e-af01-c50160f644b2","originalAuthorName":""}],"doi":"","fpage":"1008","id":"768cd5d3-20c2-4cba-a902-ecf2a46e782b","issue":"4","journal":{"abbrevTitle":"RGJTXB","coverImgSrc":"journal/img/cover/RGJTXB.jpg","id":"57","issnPpub":"1000-985X","publisherId":"RGJTXB","title":"人工晶体学报"},"keywords":[{"id":"b2d9678a-4b7b-4e0d-a817-6c1326b04944","keyword":"γ-FeOOH","originalKeyword":"γ-FeOOH"},{"id":"57d45c9a-b119-4963-98ac-ef125daa295b","keyword":"合成","originalKeyword":"合成"},{"id":"ad15bf33-7055-43b1-afa0-7836f1cebe43","keyword":"EDTA","originalKeyword":"EDTA"},{"id":"1b500b16-0637-4381-9a9a-564f358f1ace","keyword":"可见光","originalKeyword":"可见光"}],"language":"zh","publisherId":"rgjtxb98200804047","title":"EDTA作用下可见光诱导合成γ-FeOOH的探讨","volume":"37","year":"2008"},{"abstractinfo":"本文介绍了一种新型的可见光固化(VLC)树脂,通过与一般过氧化物固化的乙烯基酯树脂的机械性能和耐腐蚀性能比较可以看出,两者性能相当.但使用可见光,而非对人体有害的紫外光,安全环保,应用广泛;快速固化,苯乙烯挥发极少,操作简便,无需繁琐的添加促进剂及固化剂和脱泡过程.提高生产效率的同时,大幅度降低施工成本.","authors":[{"authorName":"江先龙","id":"091e3c61-dbbe-4f17-988a-38b3c8fa8397","originalAuthorName":"江先龙"},{"authorName":"大谷和男","id":"01471f55-c47d-428c-bc14-e5fa525bd142","originalAuthorName":"大谷和男"}],"doi":"10.3969/j.issn.1003-0999.2006.03.007","fpage":"24","id":"eb2d4ff2-15fa-44b5-9a20-f9734500f8ef","issue":"3","journal":{"abbrevTitle":"BLGFHCL","coverImgSrc":"journal/img/cover/BLGFHCL.jpg","id":"6","issnPpub":"1003-0999","publisherId":"BLGFHCL","title":"玻璃钢/复合材料"},"keywords":[{"id":"42c625d1-58ac-44c0-9564-bc69f97a7c4c","keyword":"可见光固化","originalKeyword":"可见光固化"},{"id":"253e5a34-1652-4555-ac81-42355ff6f509","keyword":"乙烯基酯树脂","originalKeyword":"乙烯基酯树脂"},{"id":"c1be2e70-c5e4-417b-abc0-6dea2badd7fd","keyword":"过氧化物固化","originalKeyword":"过氧化物固化"}],"language":"zh","publisherId":"blgfhcl200603007","title":"可见光固化树脂的研究","volume":"","year":"2006"},{"abstractinfo":"在水热条件下,以异丙醇为诱导剂,制备出结晶良好的具有白钨矿结构的BiVO_4四方管状颗粒.采用XRD、SEM、UV-Vis DRS考察了BiVO_4颗粒的物相、形貌和光催化性能.结果表明,BiV_4微米管表现出明显的四方对称性.长约5～8/μn,管径约1/μn,管壁厚为100～150nm.并在可见光范围内表现出了优良的可见光催化活性.同时,探讨了异丙醇添加量和保温时间对BiCO_4物相和颗粒彤貌的影响,研究表明,当异丙醇添加量为20%、保温时间为1h时即可得到发育良好的BiV_4微米管.","authors":[{"authorName":"于亚芹","id":"b9c8f5e3-732c-44f4-b112-12da18feae8a","originalAuthorName":"于亚芹"},{"authorName":"柳伟","id":"989a4b95-33b5-43d0-96ea-b83a27e13048","originalAuthorName":"柳伟"},{"authorName":"曹立新","id":"f0bd7864-5dd0-44b5-b2d6-4092b8ab6726","originalAuthorName":"曹立新"},{"authorName":"苏革","id":"4e68945d-e907-4f2b-a68d-d8603c83bcb9","originalAuthorName":"苏革"},{"authorName":"张岚","id":"ac8fa77c-b026-43c6-82d9-b73e8071231b","originalAuthorName":"张岚"},{"authorName":"徐超","id":"1b0c9ef0-0b8a-4649-bcbd-9d780d5814e4","originalAuthorName":"徐超"}],"doi":"","fpage":"29","id":"fda4d408-6619-4652-884b-fa8bc03540f9","issue":"6","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"3b89a1fc-4a5e-4afb-baea-f072c4c11d79","keyword":"钒酸铋","originalKeyword":"钒酸铋"},{"id":"e8dd9233-711b-43c6-9d90-12c3e1bba45e","keyword":"水热处理","originalKeyword":"水热处理"},{"id":"01138123-6b6f-4fb8-bb4e-d399b13ba741","keyword":"微米管","originalKeyword":"微米管"},{"id":"46a5bdc5-9fa1-422f-b023-827d4caea8e4","keyword":"光催化","originalKeyword":"光催化"}],"language":"zh","publisherId":"cldb201006009","title":"异丙醇诱导合成BiV0_4微米管及其可见光光催化性能研究","volume":"24","year":"2010"},{"abstractinfo":"实现资源和能源利用高效化、操作简单化、条件温和化、环境友好化以及产物高效选择性是有机合成的重要研究方向，而探索绿色温和条件下构建化学键的有效方法是有机合成领域的基本挑战之一。伴随着金属有机化学的发展，过渡金属催化的偶联反应已经成为构建碳-碳和碳-杂键的有效手段，而传统的交叉偶联一般是基于亲核试剂与亲电试剂之间的反应，需要进行预官能团化和再官能团化的步骤。近年来，在此基础上发展起来的氧化偶联反应利用合适的氧化剂实现两个亲核试剂直接构建化学键也得到了国内外有机化学家的广泛关注。氧化偶联反应的发展极大地提高了构建碳-碳键及碳-杂键的效率，尤其是利用交叉脱氢偶联实现直接的碳-氢键或杂-氢键的活化直接构建化学键，避免了传统偶联过程中的预官能团化步骤，为直接利用简单的原料实现高效、复杂的有机合成开辟了一条新的道路。越来越多的第一过渡金属催化的氧化偶联反应涉及到单电子转移的过程，这种自由基氧化偶联模式在绿色化学的发展中具有光明的前景。可见光是一种可再生的资源，可见光催化符合绿色合成、环境友好和可持续发展的理念，在有机合成领域中引起了广泛的关注。建立在光诱导的单电子转移过程的基础上，可见光催化为实现温和条件下构建化学键提供了一种新的思路。虽然很多的有机分子不能有效吸收可见光，但是利用可见光催化剂(光敏剂)在电子和能量转移过程中的独特优势，能够有效实现在可见光作用下的一系列光化学反应。光催化是有机合成构建新物质的一种有效的手段，随着光催化在有机合成领域中的发展，一系列新型温和而有效的可见光催化的氧化偶联反应也逐渐被报道。虽然过渡金属催化的氧化偶联反应已经取得了重大的进展，但是利用可见光催化的策略以实现两个亲核试剂之间化学键的构建作为一个新的领域，近年来才刚刚发展起来。尤其是结合可见光催化条件温和、环境友好的特点和氧化偶联反应的原子经济性特点，将可见光诱导的单电子转移过程运用到交叉脱氢偶联反应，引起了广泛的关注。光催化氧化偶联反应不仅解决了传统偶联中的步骤经济性和原子经济性的问题，同时也具备了可见光反应温和环保的特点。近几年来已经发展了多种类型的光催化氧化偶联反应，包括光催化氧化含氮化合物的偶联反应、光催化氧化脱羧偶联反应、以及光催化交叉偶联放氢反应等。但是在光催化氧化偶联领域的相关报道大多局限于含氮化合物和易氧化的底物的活化氧化，因此任然存在着很多的挑战。本文总结了最近几年来的不同反应类型的可见光催化的氧化偶联的研究和进展。而对这些反应的理解和认识，可以为人们发展更多的高效率和高选择性的可见光催化氧化偶联反应提供帮助。","authors":[{"authorName":"张国亭","id":"17f46b38-7f16-4d6b-9d6c-e61195a20af4","originalAuthorName":"张国亭"},{"authorName":"边长亮","id":"dd83ac11-344e-4bbc-90ad-b9b00fbcca57","originalAuthorName":"边长亮"},{"authorName":"雷爱文","id":"780effbb-2088-420d-a9c5-fff4a4f1e591","originalAuthorName":"雷爱文"}],"doi":"10.1016/S1872-2067(15)60885-3","fpage":"1428","id":"ff634ddf-117b-46e5-af12-50733d93a215","issue":"9","journal":{"abbrevTitle":"CHXB","coverImgSrc":"journal/img/cover/CHXB.jpg","id":"18","issnPpub":"0253-9837","publisherId":"CHXB","title":"催化学报 "},"keywords":[{"id":"8ecdc334-a07e-4c5e-908c-d1369a7116a9","keyword":"氧化交叉偶联","originalKeyword":"氧化交叉偶联"},{"id":"b927ba1c-c6a2-42c8-bbf7-026837685366","keyword":"光催化","originalKeyword":"光催化"},{"id":"e59c6baa-47f5-4404-ac4e-a5c62aa2e143","keyword":"可见光","originalKeyword":"可见光"},{"id":"4ba6c790-bc42-44fb-904e-a70b801db181","keyword":"均相催化","originalKeyword":"均相催化"},{"id":"bf4b3d44-dd66-4694-833a-2ee35957d64f","keyword":"单电子转移","originalKeyword":"单电子转移"}],"language":"zh","publisherId":"cuihuaxb201509005","title":"可见光参与的氧化偶联反应研究进展","volume":"","year":"2015"},{"abstractinfo":"TiO2(锐钛矿)的禁带宽度限制了其光诱导特性的广泛应用,非金属元素掺杂为TiO2在可见光辐射环境下的应用提供了新的机会.详细介绍了非金属元素(N、C、S、F)掺杂TiO2的制备方法和可见光催化活性研究的最新进展,讨论了制备工艺与掺杂TiO2可见光催化活性的关系,深入分析了非金属元素对TiO2可见光催化活性的诱导机理.制备工艺显著影响了掺杂元素的化学态和含量,从而决定了掺杂TiO2带隙中局域态的特征.带隙中局域态特征正是影响掺杂TiO2可见光催化活性的关键因素.文章也对未来的研究方向进行了展望.","authors":[{"authorName":"顾德恩","id":"9c96690e-4005-4443-8e9c-bcfb22e9d330","originalAuthorName":"顾德恩"},{"authorName":"杨邦朝","id":"710649d0-2302-4ac0-ae25-da8bd4682720","originalAuthorName":"杨邦朝"},{"authorName":"胡永达","id":"8dd1c619-87e9-4c5c-b756-328c5021b147","originalAuthorName":"胡永达"}],"doi":"","fpage":"1","id":"df901f8d-b888-4f1e-a57e-f25d1c88b598","issue":"1","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"2855e1ae-5b55-461b-b31c-208f5dac3cc7","keyword":"二氧化钛","originalKeyword":"二氧化钛"},{"id":"985e1188-15a8-4517-8140-3e81eb628f68","keyword":"非金属元素","originalKeyword":"非金属元素"},{"id":"a63bf532-4158-47df-bca3-5d8cfe91ef78","keyword":"掺杂","originalKeyword":"掺杂"},{"id":"bba5961e-4276-4170-b843-97bc6d9963b3","keyword":"可见光","originalKeyword":"可见光"},{"id":"bd9afff5-b1ff-482b-b505-5e63ab54e4b0","keyword":"光催化活性","originalKeyword":"光催化活性"}],"language":"zh","publisherId":"gncl200801001","title":"非金属元素掺杂TiO2的可见光催化活性研究进展","volume":"39","year":"2008"},{"abstractinfo":"综述了近年来可见光激发光催化剂的研究进展,重点介绍了常用光催化剂TiO2、ZnO、CdS可见光化的研究,以及其它新型可见光响应光催化剂的研究进展.最后简要分析了光催化剂存在的问题和未来的发展动向.","authors":[{"authorName":"张俊敏","id":"1c8ec78f-e27a-4c1f-81a0-3321602378db","originalAuthorName":"张俊敏"},{"authorName":"奚丽荷","id":"6d450c65-c387-459b-b04e-25ac13169a64","originalAuthorName":"奚丽荷"},{"authorName":"朱忠其","id":"93fa4e02-b183-483a-b53c-6080e539246b","originalAuthorName":"朱忠其"},{"authorName":"张谨","id":"d80989cb-7922-4b57-b06c-c3334c681619","originalAuthorName":"张谨"},{"authorName":"柳清菊","id":"7aff6dac-a513-45c7-946e-98c73b1fa5a8","originalAuthorName":"柳清菊"}],"doi":"","fpage":"92","id":"1b12d027-8438-4d2d-96d1-a8566d9f353a","issue":"z2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"0a81822b-11b0-4188-82e1-6eca4769b7ec","keyword":"催化剂","originalKeyword":"催化剂"},{"id":"4ccac105-6f73-44aa-8767-68a4309fc9b6","keyword":"TiO2","originalKeyword":"TiO2"},{"id":"aeeae242-1d2d-42f5-9b80-68ccac5767a2","keyword":"ZnO","originalKeyword":"ZnO"},{"id":"6c2f0438-40fc-497e-8d89-02963f4ded11","keyword":"CdS","originalKeyword":"CdS"},{"id":"17223889-9a28-4cef-8281-52bff323c752","keyword":"可见光激发光催化剂","originalKeyword":"可见光激发光催化剂"}],"language":"zh","publisherId":"cldb2007z2034","title":"可见光激发光催化剂的研究进展","volume":"21","year":"2007"},{"abstractinfo":"对铌元素可见光谱进行了计算机模拟,研究了铌元素的可见光谱特征.使用光栅看谱镜和棱镜看谱镜对合金中铌元素可见光谱进行看谱分析研究,摄制了彩色图谱.讨论合金中铌元素的定性和半定量分析方法,结果能满足材料牌号鉴别的需要.","authors":[{"authorName":"刘平","id":"122fe30f-e7be-4fa7-a869-8c7bd6420420","originalAuthorName":"刘平"},{"authorName":"刘浩新","id":"21bc235e-cced-4e33-9715-d253790033ca","originalAuthorName":"刘浩新"}],"doi":"10.3969/j.issn.1004-244X.2007.05.018","fpage":"63","id":"804cb596-9271-40df-966e-dd7e19a6165b","issue":"5","journal":{"abbrevTitle":"BQCLKXYGC","coverImgSrc":"journal/img/cover/BQCLKXYGC.jpg","id":"4","issnPpub":"1004-244X","publisherId":"BQCLKXYGC","title":"兵器材料科学与工程 "},"keywords":[{"id":"f9dabb10-d299-4d3a-aadc-db4c673d569a","keyword":"铌","originalKeyword":"铌"},{"id":"b1f49547-434a-4feb-9796-8b2bdf69d9c6","keyword":"看谱","originalKeyword":"看谱"},{"id":"d75e1ae4-d18e-4c20-b130-1f9450c4c04a","keyword":"可见光谱","originalKeyword":"可见光谱"},{"id":"59dd239e-5a51-4f03-86a3-c118bec3f90f","keyword":"模拟","originalKeyword":"模拟"},{"id":"a253c4b1-661e-4361-90b5-e2104c8d4c84","keyword":"定性","originalKeyword":"定性"},{"id":"3a66f719-7780-4a7f-a890-350adff54597","keyword":"半定量","originalKeyword":"半定量"}],"language":"zh","publisherId":"bqclkxygc200705018","title":"铌元素可见光谱及其应用研究","volume":"30","year":"2007"},{"abstractinfo":"利用可见光催化分解水制氢是利用太阳能的有效方法之一,从材料组成、结构、催化性能及改性等方面介绍了几类重要的可见光催化材料的研究进展,并展望了未来的发展方向.","authors":[{"authorName":"冉锐","id":"1e8bf626-de0c-4286-987b-c9e6519cac4a","originalAuthorName":"冉锐"},{"authorName":"吴晓东","id":"e22d2328-1511-4b16-8e65-ab0552fddb80","originalAuthorName":"吴晓东"},{"authorName":"翁端","id":"64ad5b9b-aa96-4105-9949-cb3202a17d97","originalAuthorName":"翁端"}],"doi":"","fpage":"39","id":"c6466cba-9d0b-4bca-9893-606bc2921e43","issue":"z2","journal":{"abbrevTitle":"CLDB","coverImgSrc":"journal/img/cover/CLDB.jpg","id":"8","issnPpub":"1005-023X","publisherId":"CLDB","title":"材料导报"},"keywords":[{"id":"6abe2333-3f14-4e40-b04e-8bfa233d442e","keyword":"光解水制氢","originalKeyword":"光解水制氢"},{"id":"3b227776-e4aa-4d3d-a2b1-8b71e2b772d8","keyword":"可见光催化","originalKeyword":"可见光催化"},{"id":"738ff1a8-6e82-40ae-8e9c-233181d74752","keyword":"光催化材料","originalKeyword":"光催化材料"}],"language":"zh","publisherId":"cldb2004z2013","title":"光解水制氢的可见光催化材料的研究进展","volume":"18","year":"2004"}],"totalpage":885,"totalrecord":8849}