利用过量的4，4＇-二氨基二苯醚和卤代烃反应合成烷基化衍生物N，N＇-二[2-(羟基乙氧基)乙基]-4，4＇-二氨基二苯醚，以此作为富π电子供体和缺π电子环二(1，1＇-二甲基-4，4＇-联吡啶)对苯撑大环化合物(CPQT)自组装形成准轮烷，利用1HNMR化学位移变化跟踪该准轮烷在酸碱调控下的分子开关功能．结果表明，准轮烷(B-CPQT)的形成很可能是二苯胺醚中的醚键O与CPQT上的吡啶环的a-H形成氢键的结果．
The reaction of an excess of 4, 4＇-oxydianiline (A) with alkyl halide has been foundeffective to synthesize N, N＇ -bis [2-(hydroxyethoxy)ethyl]-4, 4＇ -oxydianiline (B). It is found thattwo new pseudotaxanes (A-CPQT、B-CPQT) are formed in solution by self-assembly of electron donor4, 4 ＇ -oxydianiline (A) and (B) with electron accepter cyclobis (paraquat-phenylene) tetracationiccyclophane(CPQT), respectively, which can be reversibly switched by acid-base action. The processis monitored by 1H NMR technique. The results showed that pseudorotaxane(B-CPQT) formation isprobably encouraged by the hydrogen bonding sites.: oxygen atoms along the polyether chains fromdianiline rings form the [ C－H…O ] bonding with the hydrogen atoms in α position to the nitrogenatom in the bipyridinium rings on the cyclophane.
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