用固相反应与液相反应2种方法合成了几种吡唑啉酮衍生物的铜(II)配合物,并用元素分析、IR、TG-DTA及XRD等测试技术对其进行了表征. 分析结果表明,由于固、液相反应机理不同使得反应产物不同,液相反应产物分子式符合M2L2·nH2O(n=0,1) 或M(HL)2·H2O,而固相反应产物分子式符合M(H2L)·2OAc·nH2O(n=1,2).
参考文献
| [1] | Sasaki Y,Freiser H. Inorg Chem[J],1983,22:2 289 |
| [2] | Liu S X,Gao S. Polyhedron[J],1998,17:81 |
| [3] | Arion V,Wieghardt K,Weyhermueller T. Inorg Chem[J],1997,36:661 |
| [4] | Angelo M,Stefano B,Simona G, et al. J Org Chem[J],2003,672:123 |
| [5] | JIA Dian-Zeng(贾殿增),XIN Xin-Quan(忻新泉). Acta Chim Sin(化学学报)[J],1993,51:358 |
| [6] | Xin X Q,Zheng L M. J Solid State Chem[J],1993,106:451 |
| [7] | Ye X R,Jia D Z,Yu J Q, et al. Adv Mater[J],1999,11:941 |
| [8] | Yao X B,Zheng L M,Xin X Q. J Solid State Chem[J],1995,117:333 |
| [9] | JI Ya-Li(吉亚丽),LIU Lang(刘浪),JIA Dian-Zeng(贾殿赠), et al. Chin J Struct Chem(结构化学)[J],2002,21(5):553 |
| [10] | LIU Lang(刘浪),JIA Dian-Zeng(贾殿赠),YU Kai-Bei(郁开北). Chin J Struct Chem(结构化学)[J],2004,23(1):112 |
| [11] | LIU Lang(刘浪),JI Ya-Li(吉亚丽),JIA Dian-Zeng(贾殿赠), et al. Acta Chim Sin(化学学报)[J],2003,61(6):893 |
| [12] | Havanur G H,Mahale V B. Ind J Chem[J],1987,26A:1 063 |
| [13] | Liu L,Jia D Z,Ji Y L. Synth React Inorg Met-Org Chem[J],2002,32(4):739 |
| [14] | Nakamoto K(著). HUANG De-Ru(黄德如),WANG Ren-Qing(汪仁庆) Transl(译). Infared and Raman Spectra of Inorganic and Coordination Compounds(无机和配位化合物的红外和拉曼光谱),1st Edn(第1版)[M]. Beijing(北京):Chemical Industry Press(化学工业出版社) |
| [15] | Sawaf A K E,West D X. Transition Met Chem[J],1998,23:649 |
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