用多种方法合成了对二炔苯的β-环糊精包结物,通过1H NMR、XRD、DSC等方法对其进行了表征,并对其荧光性能做了初步的研究,结果表明,对二炔苯进入β-环糊精空腔使环糊精的H-3和H-5的化学位移向高场移动,环糊精的脱水峰向低温移动. 在包结物中,对二炔苯不再以晶体形式存在,荧光分析表明,形成包结物后环糊精能有效防止对二炔苯分子间的π-π堆积作用.
参考文献
| [1] | Bunz U H F.Chem Rev[J],2000,100:1 605 |
| [2] | Halkyard C E,Rampey M E,Kloppenburg L,et al. Macromolecules[J],1998,31:8 655 |
| [3] | Cornil J,Dos Santos D A,Crispin X,et al. J Am Chem Soc[J],1998,120:1 289 |
| [4] | A.Zhu Z G,Swager T M.Org Lett[J],2001,3(22):3 471B.Pschirer N G,Miteva T,Evans U,et al. Chem Mater[J],2001,13:2 691C.Huang W Y,Matsuoka S,Kwei T K,et al. Macromolecules[J],2001,34:7 809 |
| [5] | A.Zhu Z G,Swager T M.Org Lett[J],2001,3(22):3 471B.Pschirer N G,Miteva T,Evans U,et al. Chem Mater[J],2001,13:2 691C.Huang W Y,Matsuoka S,Kwei T K,et al. Macromolecules[J],2001,34:7 809 |
| [6] | A.Zhu Z G,Swager T M.Org Lett[J],2001,3(22):3 471B.Pschirer N G,Miteva T,Evans U,et al. Chem Mater[J],2001,13:2 691C.Huang W Y,Matsuoka S,Kwei T K,et al. Macromolecules[J],2001,34:7 809 |
| [7] | Cacialli F,Wilson J S,Anderson H L,et al. Nature Mater[J],2002,1:160 |
| [8] | Szejtli J.Chem Rev[J],1998,98:1 743 |
| [9] | MacBride J A H.Synth Commun[J],1996,26(12):2 309 |
| [10] | Astilean S,Ionescu C,Cristea G H,et al. Biospectroscopy[J],1997,3(3):233 |
| [11] | Schneider H J,Hacket F,Rudiger V,et al. Chem Rev[J],1998,98:1 755 |
| [12] | Bojinova T,Coppel Y,Viguerie N L,et al. Langmuir[J],2003,19:5 233 |
| [13] | Bunz U H F,Enkelmann V,Kloppenburg L,et al. Chem Mater[J],1999,11:1 416 |
| [14] | LIU Yu(刘育),YOU Chang-Cheng(尤长城),ZHANG Heng-Yi(张衡益). Supermolecular Chemistry(超分子化学)[M]. Tianjin(天津):Nankai University Press(南开大学出版社),2001 |
| [15] | TONG Lin-Hui(童林荟). Cyclodextrin Chemistry(环糊精化学)[M]. Beijing(北京):Science Press(科学出版社),2001 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%