用低热固相反应法制备铝钴复合掺杂的Ni(OH)2样品,研究其结构和电化学性能.XRD测试结果表明,同时掺杂摩尔分数为20%的Al和摩尔分数为5%的Co的α-Ni(OH)2样品在6 mol/L KOH中浸泡6个月仍保持稳定的α型结构;该样品经30次充放电循环仍保持α型结构.电化学测试结果表明,该样品的放电比容量和大电流放电性能均明显好于摩尔分数为20%的Al的单掺杂α-Ni(OH)2和球形β-Ni(OH)2.
参考文献
| [1] | ZHANG Qian(张倩),XU Yan-Hui(徐艳辉),WANG Xiao-Lin(王晓琳).Rare Metal Mater Eng(稀有金属材料与工程)[J],2003,32(10):825 |
| [2] | Faure C.J Power Sources[J],1991,35:279 |
| [3] | WANG Zhan-Liang(王占良),TANG Zhi-Yuan(唐致远),LEI Rong(雷荣).Liaoning Chemi Ind(辽宁化工)[J],2001,30(2):58 |
| [4] | Guerlou-Demourges L,Denage C,Delmas C.J Power Sources[J],1994,52:269 |
| [5] | XU Yan-Hui(徐艳辉),CHEN Chang-Cheng(陈长聘),WU Jun(吴俊),et al.Chinese J Power Sources(电源技术)[J],1999,23(4):209 |
| [6] | Indira L,Mridula D,et al.J Power Sources[J],1994,52:93 |
| [7] | Armstrong R D,Briggs G W D,et al.J Appl Electrochem[J],1998,18:215 |
| [8] | Watanabe K,Koseki M,Kumagai N.J Power Sources[J],1996,58:23 |
| [9] | Faure C,Delmas C,Wilimann P.J Power Sources[J],1991,36:497 |
| [10] | WANG Rui(王锐),HYANG Yong-Pan(黄永攀),et al.Chinese J Quantum Electronics(量子电子学报)[J],2004,21(3):387 |
| [11] | LENG Yong-Jun(冷拥军),LIU Bing(刘兵),et al.Chinese J Power Sources(电源技术)[J],2000,24(6):326 |
| [12] | ZHANG Hong-Bing(张红兵),PU Tan(浦坦),LI Dao-Huo(李道火).Chinese J Power Sources(电源技术)[J],2004,28(5):281 |
| [13] | ZHOU Yi-Ming(周益明),XIN Xin-Quan(忻新泉).Chinese J Inorg Chem(无机化学学报)[J],1999,15(3):273 |
| [14] | YANG Shu-Ting(杨书廷),CHEN Gai-Rong(陈改荣),YIN Yan-Hong(尹艳红),et al.Chinese J Appl Chem(应用化学)[J],2001,18(9):689 |
| [15] | XIAO Hui-Ming(肖慧明),WANG Jian-Ming(王建明).Chinese J Inorg Mater(无机材料学报)[J],2004,19(3):463 |
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