以2,6,8,12-四乙酰基-2,4,6,8,10,12.六氮杂四环[5,5,0,03,1105,9]十二烷(TAIW)为原料,利用硝化剂N2O5在HNO3介质中硝化硝解TAIW制得CL-20.该方法可避免浓H2SO4污染,最佳反应条件为:反应温度为40℃,反应时间为1 h,n(TAIW):n(N2O5):n(HNO3)=1:4:36,产率为86.1%,纯度达到99%.产物经元素分析、核磁共振、质谱等测试技术对其结构进行了检测和表征.
参考文献
| [1] | Simpson R L,Urtiaw P A,Ornellas D L,Wardle G P.Prop Explos Pyrotech[J],1997,22(5):249 |
| [2] | Eaton P E,Xiong Y,Gilardi R.J Am Chem Soc[J],1993,115:10 195 |
| [3] | Olah G A,Squire D R.Chemistry of Energetic Materials[M].San Diego:Academic Press,1991 |
| [4] | CHEN Shu-Sen(陈树森),QIU Wen-Ge(邱文革),YU Yong-Zhong(于永忠).Acta Armamentarii(兵工学报)[J],2000,21 (2):116 |
| [5] | Millar R W,Colclo M E,Desai H.Novel Syntheses of Energetic Materials Using Dinitrogen Pentoxide[M].UK:British Crown,1996 |
| [6] | Nielsen A T,Chafin A P,Christian S L,Moore D W,Nadler M P,Nissan R A,Vanderah D J.Tetrahed[J],1998,54:11793 |
| [7] | OU Yu-Xiang(欧育湘),LIU Jin-Quan(刘进全),WANG Yan-Fei(王艳飞),MENG Zheng(孟征).Chinese Chem Bull(化学通报)[J],2005,68(10):731 |
| [8] | Wardle R B,Hinshaw J C.US 6 147 209.6[P],2000 |
| [9] | Freaques C.RFI 060 425[P],1954 |
| [10] | Crampton M R,Hamid J,Millar R,Ferguson G.J Chem Soc Perkin Trans2[J],1993,7:923 |
| [11] | Patil D G,Brill T B.Combust Flame[J],1991,87:45 |
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