用电化学阳极氧化法一步合成具有电致变色的自支撑导电聚(聚(N-乙烯基咔唑))(PPVK)膜.电导率为0.012 S/cm.循环伏安研究表明,PPVK膜具有良好的氧化还原可逆性,且在三氟化硼乙醚溶液中PPVK膜的电化学活性非常稳定.红外光谱分析结果表明,PVK二次聚合发生在苯环上.荧光光谱分析结果表明.PPVK膜是一种良好的蓝色荧光物质.交流阻抗谱研究表明,PPVK的阳极氧化过程(0.5-1.9 V)可以分为P掺杂区(0.5-1.3 V)、过渡区(1.4-1.5 V)和过氧化区(1.6-1.9 V)3个电位区域.
参考文献
[1] | skotlleim T A,Elsembaumer R L,Reynolds J R.Handbook of Conducting Polymer[M],2nd Edn.New York:MarcelDekker,1998:695 |
[2] | Huang J,Niu Y,Yang W,Mo Y,Yuan M,Cao Y.Macromolecules[J],2002,35:6080 |
[3] | Thomas J K R,Lin J T,Tao Y T,Ko C W.J Am Chem Soc[J],2001,123:9404 |
[4] | Ran V I.Santhanam K S V.J Sol/d State Electrochem[J],1998,2:99 |
[5] | Onishi K,Advincula R C,Karim S M A,Nakai T,Masuda T.Polym Prepr[J],2002,43:171 |
[6] | Lǚbben J.Onishi K,Advincula R,Baba A,Knoll W.Polym Prepr[J],2004,45:783 |
[7] | Marrec P.Dano c,Simonet N G,Simonet J.Synth Met[J],1997,89:171 |
[8] | Deng S,Advincula R c.Chem Mater[J],2002,14:4073 |
[9] | Baba A,Onishi K,Knoll W,Advincula R C.J Phys Chem B[J],2004,108:18949 |
[10] | Shi G Q,Jin S,Xue G,Li C.Science[J],1995,267:994 |
[11] | Nie G M,Xu J K,Zhang S S,Han X J.JAppl Electrochem[J],2005,36:937 |
[12] | Otero T F,Larreta-Azelain E.Polymer[J],1988,29:1522 |
[13] | SHE Ping-Ping(佘平平),WANG Zheng-nao(汪正浩).Acta Chin Sin(化学学报)[J],2006,64:997 |
[14] | Zhang S S,Nie G M,Han X J,Xu J K,Li M s,Cai T.Electrochim Acta[J],2006,51:5738 |
[15] | Betova I,Bojinov M,Lankinen E,Sundholm G.J Electroanal Chem[J],1999,472:20 |
[16] | Bobacka J,Lewenstam A,Ivaska A.J Electroanal Chem[J],2000,489:17 |
[17] | Sezer E,Ustamehmetoglu B,Sarat;A S.Synth Met[J],1999,107:7 |
[18] | Knoll K,Schroek R R.JAm Chem soc[J],1989,111:7 989 |
[19] | Zhang D H,Qin J G,Xue G.Synth Met[J],1999,106:161 |
[20] | Chung T C,Kaufman J H,Heeger A J,Wudl F.Phys Rev B[J],1984,30:702 |
[21] | Thompson B C,Schotfland P,Zong K,Reynolds J R.Chem Mater[J],2000,12:1563 |
[22] | Abthagir S P,Saraswathi R.Thermochim Acta[J],2004,424:25 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%