直接甲醇燃料电池中甲醇替代燃料的研究进展

应用化学, 2008, 25(10): 1125-1129. doi: 10.3969/j.issn.1000-0518.2008.10.001

直接甲醇燃料电池中甲醇替代燃料的研究进展

马德娜 ^1, , 袁青云 ^2, , 唐亚文 ^3, , 高颖 ^4, , 初园园 ^5, , 陆天虹 ^6,

1.南京师范大学化学与环境科学学院,南京,210097

2.南京师范大学化学与环境科学学院,南京,210097

3.南京师范大学化学与环境科学学院,南京,210097

4.哈尔滨师范大学理化学院化学系,哈尔滨

5.哈尔滨师范大学理化学院化学系,哈尔滨

6.南京师范大学化学与环境科学学院,南京,210097

基金项目: 江苏省教育厅自然科学基金(05KJB150061) 江苏省自然科学基金(BK2006224) 国家自然科学基金(20573029;20573057) 国家高技术研究发展计划(863计划)(2006AA05Z137;2007AA052143;2007AA052159)

关键词：直接甲醇燃料电池 , 甲醇替代燃料 , 乙醇 , 甲酸

Research Progress on Methanol-alternative Fuels for Direct Methanol Fuel Cell

介绍了甲醇替代燃料,如乙醇、甲酸等的研究进展. 研究发现,用甲酸作燃料要比甲醇具有很多优点,如甲酸无毒,不易燃,存储和运输安全方便,而且它对Nafion膜的透过率低,氧化性能好. 它在氧化时不产生使催化剂中毒的中间产物CO. 在众多研究过的甲醇替代燃料中,甲酸被认为最有可能代替甲醇的燃料.

参考文献

[1]	YI Bao-Lian(衣宝廉).Fuel Cell(燃料电池)[M].Beijing(北京):Chemical Industry Press(化学工业出版社),2000
[2]	XIE Xiao-Feng(谢晓峰),FAN Xing-He(范星河).Fuel Cell Technique(燃料电池技术)[M].Beijing(北京):Chemical Industry Press(化学工业出版社),2004
[3]	LU Tian-Hong(陆天虹),XING Wei(邢巍).J Adv Mater Ind(新材料产业)[J],2003,118:3
[4]	MAO Zong-Qiang(毛宗强),LU Tian-Hong(陆天虹),XING Wei(邢巍).Fuel Cell(燃料电池)[M].Beijing(北京):Chemical Industry Press(化学工业出版社),2005
[5]	Wang J,Wasmus S,Savinell R F.J Electrochem Soc[J],1995,142:4 218
[6]	Tacconi N R,Lezna R O,Beden B,Hahn F,Lamy C.J Electroanal Chem[J],1994,379:329
[7]	Tremiliosi-Filho G,Gonzalez E R,Motheo A J,Belgsir E M,Léger J M,Lamy C.J Electroanal Chem[J],1998,444:31
[8]	Iwasita T,Rasch B,Cattaneo E,Vielstich W.Electrochim Acta[J],1989,34:1 073
[9]	Fujiwara N,Friedrich K A,Stimming U.J Electroanal Chem[J],1999,472:120
[10]	Arico A S,Creti P,Antonucci P L,Antonucci V.Solid-State Lett[J],1998,1:66
[11]	Lamy C,Lima A,LeRhun V,Deline F,Coutanceau C,Léger J M.J Power Sources[J],2002,105:283
[12]	Zhou W J,Zhou Z H,Song S Q,Li W Z,Sun G Q,Tsiakaras P,Xin Q.Appl Catal B:Environ[J],2003,46:273
[13]	Zhou W J,Li W Z,Song S Q,Zhou Z H,Jiang L H,Sun G Q,Xin Q,Poulianitis K,Kontou S,Tsiakarsa P.J Power Sources[J],2004,131:217
[14]	Qi Z G,Kaufman A.J Power Sources[J],2002,112:121
[15]	Qi Z G,Kaufman A.J Power Sources[J],2003,5 201:1
[16]	Takky D,Beaten B,Leger J M,Lamy C.J Electranal Chem[J],1983,145:461
[17]	Takky D,Beaten B,Leger J M,Lamy C.J Electranal Chem[J],1985,193:159
[18]	Takky D,Beaten B,Leger J M,Lamy C.J Electranal Chem[J],1988,256:127
[19]	Kelaidopoulou A,Apelidou E,Papoutsis A,Polychroniadis E K,Kokkinidis G.J Appl Electrochem[J],1998,28:1 101
[20]	Kadirgan F,Benden B,Lamy C.J Electroana Chem[J],1982,136:119
[21]	Kadirgan F,Benden B,Lamy C.J Electroanal Chem[J],1983,142:135
[22]	Benden B,Kadirgan F,Kahyaoglu A,Lamy C.J Electroanal Chem[J],1982,135:329
[23]	Rice C,Ha S,Masel R I,Waszczuk P,Wieckowski A.J Power Sources[J],2002,111:83
[24]	Rice C,Ha S,Masel R I,Wieckowski A.J Power Sources[J],2003,115:229
[25]	Rhee Y W,Ha S,Masel R I.J Power Sources[J],2003,117:23
[26]	Ha S,Rice C,Masel R I,Wieckowski A.J Power Sources[J],2003,112:655
[27]	US Code of Federal Regulations,21 CFR 186.1316,21 CFR 172.515
[28]	Rhee Y W,Ha S,Rice C,Masel R I.J Power Sources[J],2003,117:35
[29]	Capon A,Parsons R.J Electroanal Chem[J],1973,45:205
[30]	Wieckowski A,Sobkowski J.J Electroanal Chem[J],1975,63:365
[31]	Yang Y Y,Sun S G,Gu Y J,Zhou Z Y,Zhen C H.Electrochim Acta[J],2001,46:4 339
[32]	Lee J Y,Strasser P,Eiswirth M,Ertl G.Electrochim Acta[J],2001,47:501
[33]	Macia M D,Herrero E,Feliu J M,Aldaz A.J Electroanal Chem[J],2001,500:498
[34]	Waszczuk P,Barnard T M,Rice C,Masel R I,Wieckowski A.Electrochem Comm[J],2002,4:599
[35]	Napporn W T,Laborde H,lager J M,Lamy C.J Electroanal Chem[J],1996,404:153
[36]	Babu P K,Kim H S,Chung J H,Oldfield E,Wieckowski A.J Phys Chem B[J],2004,108:20 228
[37]	Arenz M,Stamenkovic V,Schmidt T J,Wandelt K,Ross P N,Markovic N M.Phys Chem Chem Phys[J],2003,5:4 242
[38]	Arenz M,Stamenkovic V,Ross P N,Markovic N M.Surf Sci[J],2004,573:57
[39]	Thomas F S,Masel R I.Surf Sci[J],2004,573:169
[40]	Hernandez F,Baltruschat H.Langmuir[J],2006,22:4 877
[41]	Tang J,Kibler L A,Kolb D M.Chinese J Electrochem[J],2003,9:126
[42]	Ayman K,Travis C,Abhaya D.J Catal[J],2006,243:420
[43]	Penner S,Jenewein B,Gabasch H,Kl tzer B,Wang D,Knop-Gericke A,Schl gl R,Hayek K.J Catal[J],2006,241:14
[44]	Cárdenas G,Oliva R,Reyes P,Rivas B L J.Mol Catal A:Chem[J],2003,191:75
[45]	Ryszard P,Roman S.Phys B:Condensed Matter[J],2005,367:165
[46]	Diaz R,Arbiol J,Cirera A,Sanz F,Peiro F,Cornet A,Morante J R.Chem Mater[J],2001,13:4 362
[47]	Xie B P,Xiong Y,Chen R M,Chen J,Cai P X.Catal Comm[J],2005,6:699
[48]	Zhang L L,Tang Y W,Bao J C,Lu T H,Li C.J Power Sources[J],2006,162:177
[49]	Narayanan S R,Vamos E,Surampudi S,Frank H,Halpert G,Suryaprakash G K,Smart M C,Knieler R,Olah G A,Kosek J,Cropley C.J Eletrochem Soc[J],1997,144:4 195
[50]	Wang J T,Lin W F.Electrochim Acta[J],1998,43:3 821

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

直接甲醇燃料电池中甲醇替代燃料的研究进展

Research Progress on Methanol-alternative Fuels for Direct Methanol Fuel Cell

参考文献