介绍了纳米SiO2粒子链补强硅橡胶的机理.主要是因为纳米粒子链与聚硅氧烷分子链缠结和吸附,进行了无机与有机分子链水平的复合,复合体能随着基体形变而通过自身的屈服变形过程吸收大量的能量,从而补强硅橡胶.
参考文献
[1] | Cochrane H;Lin C S .The influence of fumed silica properties on the processing,curing and reinforcement properties of silicone rubber[J].Rubber Chemistry and Technology,1993,166(01):48-53. |
[2] | Schaefer DW.;Suryawanshi C.;Pakdel P.;Ilavsky J.;Jemian PR. .Challenges and opportunities in complex materials: silica-reinforced elastomers[J].Physica, A. Statistical mechanics and its applications,2002(1/4):686-695. |
[3] | McCarthy DW.;Schaefer DW.;Mark JE. .Synthesis, structure, and properties of hybrid organic-inorganic composites based on polysiloxanes. I. Poly(dimethylsiloxane) elastomers containing silica[J].Journal of Polymer Science, Part B. Polymer Physics,1998(7):1167-1189. |
[4] | Aranguren MI.;Macosko CW.;Mora E. .COMPOUNDING FUMED SILICAS INTO POLYDIMETHYLSILOXANE - BOUND RUBBER AND FINAL AGGREGATE SIZE[J].Journal of Colloid and Interface Science,1997(2):329-337. |
[5] | H. Barthel .Surface interactions of dimethylsiloxy group-modified fumed silica[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,1995(2/3):217-226. |
[6] | Fumito Yatsuyanagi;Nozomu Suzuki;Masayoshi Ito;Hiroyuki Kaidou .Effects of secondary structure of fillers on the mechanical properties of silica filled rubber systems[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(23):9523-9529. |
[7] | Sheldon K. Friedlander;Hee Dong Jang;Kevin H. Ryu .Elastic behavior of nanoparticle chain aggregates[J].Applied physics letters,1998(1/6):173-175. |
[8] | Friedlander S K .Polymer-like behavior of inorganic nanoparticle chain aggregates[J].Journal of Nanoparticle Research,1999,1(01):9-15. |
[9] | Friedlander S K .Synthesis of nanoparticles and their agglomerates: Aerosol reactors[OL].http://www.wtec.org/Loyola/nano/us.review |
[10] | Ogawa K;Vogt T;Ullmann M et al.Elastic properties of nanoparticle chain aggregates of titania,alumina and iron oxide generated by laser ablation[J].Journal of Applied Physics,2000,87(01):63-73. |
[11] | 幸松民;王一璐.有机硅合成工艺及产品应用[M].北京:化学工业出版社,2000 |
[12] | 李光亮.有机硅高分子化学[M].北京:北京科学技术出版社,1998 |
[13] | Hommel H;Bokobza L .Investigation of Molecular Mobility of Silica-Filled Poly(Dimethylsiloxane) Networks by Electron Paramagnetic Resonance Spectroscopy[OL].http://nte-serveur.univ-lyon1.fr |
[14] | Zhang Liqun;Wang Yiqing;Wang Yizhong .Research on dispersed states of the bulking and strengthening agents in the rubber matrix[J].Journal of Beijing University of Chemical Techenology,2000,27(02):10-14. |
[15] | Van Damme H .Polymer Physical Chemistry and Spectroscopy[OL].http://www.espci.fr |
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