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在络合剂EDTA、保护剂PVP存在的条件下,通过超声电沉积方法在硝酸银溶液中制备出形状不同的零维、一维银纳米材料.研究结果表明:当硝酸银浓度为0.0118 mol/L、硝酸银与EDTA数量比为1:1时,银纳米粒子为类球形,直径约30 nm.当加入2 g/L的PVP时,可获得直径约30 nm,长度不等的银纳米线.选区电子衍射和紫外可见吸收光谱表明,银纳米颗粒具有面心立方结构,其形貌和粒径影响微粒的光吸收特性.

参考文献

[1] 廖学红,朱俊杰,赵小宁,陈洪渊.纳米银的电化学合成[J].高等学校化学学报,2000(12):1837.
[2] 邬建辉,张传福,湛菁,吴琳琳.超声波在粉体材料制备中的应用[J].有色金属,2001(03):81-83.
[3] G.Sandmann;H.Dietz;W.Plieth .Preparation of silver nanoparticles on ITO surfaces by a double-pulse method[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2000(1/2):78-86.
[4] Junjie Zhu;Xuehong Liao;Hong-Yuan Chen .Electrochemical preparation of silver dendrites in the presence of DNA[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2001(9):1687-1692.
[5] Lei Sun;Zhijun Zhang;Hongxin Dang .A novel method for preparation of silver nanoparticles[J].Materials Letters,2003(24/25):3874-3879.
[6] Zhu JJ.;Palchik O.;Koltypin Y.;Gedanken A.;Liu SW. .Shape-controlled synthesis of silver nanoparticles by pulse sonoelectrochemical methods[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(16):6396-6399.
[7] 廖学红,朱俊杰,邱晓峰,赵小宁,陈洪渊.类球形和树枝状纳米银的超声电化学制备[J].南京大学学报(自然科学版),2002(01):119-123.
[8] 兰新哲,金志浩,赵西成,苟林峰.PVP保护还原法制备纳米金溶胶[J].稀有金属材料与工程,2003(01):50-53.
[9] 梁焕珍,Kim Dong-Jin,Chung Hun S,张洁,喻克宁,黎少华,李锐星.乙二醇中化学还原合成片状银粉[J].物理化学学报,2003(02):150-153.
[10] 陈彩凤,陈志刚.超声场中湿法制备纳米粉末的原理和方法[J].机械工程材料,2003(04):30-32.
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