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拟定了用负载8-羟基喹啉的活性炭对水中痕量钨(Ⅵ)进行预富集的方法,探讨了活性炭吸附钨(Ⅵ)及有机试剂的作用机理。在实验条件下,100mg活性炭负载8-羟基喹啉后,可以大大提高对钨(Ⅵ)的吸附效果,同时除去干扰测定的金属离子,最后用分光光度法测定水中痕量钨(Ⅵ)。利用本方法对温泉水样品中的痕量钨(Ⅵ)进行分析测定,结果令人满意。

Accumulation of W(Ⅵ) was studied using active carbon impregnated with 8-hydroxyquinoline. The optimal conditions were selected. The mechanism of adsorption of W(Ⅵ) by active carbon and the mechanism of the effect of 8-hydroxyquinoline was also discussed. By this process, the adsorption capacity of active carbon for W(Ⅵ) was greatly improved, and W(Ⅵ) can be separated from many ions such as Fe3+, Cu2+, Co2+, Ni2+, Mn2+, Hg2+, Cd2+, Zn2+, Pb2+, Sn2+, Al3+, Ti(Ⅵ) etc. This method is simple, sensitive, rapid and repeatable, it has been used to determine trace W(Ⅵ) in spring water with satisfactory results.

参考文献

[1] Jackwerth E;Lohmar J;Wittler G .[J].Fresenius Zeitschrift fuer Analytische Chemie,1973,266
[2] Vanderborght B M;Van Grieken R E .[J].Analytical Biochemistry,1977,89:399.
[3] 分析化学[J].分析化学,2001(08):925.
[4] 江祖成;刘怀志 .[J].分析测试学报,1998,17(01):59.
[5] 顾惕人;Manes M .[J].化学学报,1984,42(06):509.
[6] Mattson J S;Mark H B Jr.Activated Carbon[M].New York:Marcel Dekker,1971
[7] Snoeyink V L;Weber W J .[J].Progress in Surface and Membrane Science,1972,5:63.
[8] Norde W;Traaye J;Brash J L.Proteins at Surface[M].Washington:American Chemical Society,1981
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