综述了近年来国内外光度法测定痕量铅(Ⅱ)的研究进展.对直接显(褪)色光度法、催化动力学光度法、阻抑动力学光度法、荧光光度法、共振光散射法、化学发光分析法以及相关联用技术从反应体系、介质条件、线性范围、检出限、实际应用对象等方面进行了归纳.对光度法测定铅(Ⅱ)的研究方向和发展前景进行了展望:深入探讨反应机理,建立合理、便捷的铅(Ⅱ)光度分析新体系以提高分析检测的选择性和重现性;开发灵敏度高、选择性强、稳定性好的无毒或低毒新型显色剂以改善检测方法;加强与高效分离、富集检测技术联用,简化分析检测过程以减少测定干扰,实现对痕量铅(Ⅱ)的准确测定.
The development of spectrophotometriodetermination of lead(Ⅱ) is reviewed. The main anal-ysis methods include conventional spectrophotometry, catalytic kinetic spectrophotometry , inhibition kinetic spectrophotometry, fluorescence speetrophotometry , resonance light scattering, chemilumi-nescence analysis and coupling technique. The system, condition, linear range, detection limit and ap-plications of each method are summarized. The development trend of spectrophotometric method for the determination of lead(Ⅱ) in the future is also discussed. Firstly, the reaction mechanism was ex-plored for the purpose of setting up a novel reasonable and simple spectrophotometric analysis system of lead(Ⅱ) to improve selectivity and reproducibility. Secondly, new ehromogenic reagents were devel-oped which are of high sensitivity, selectivity, stability, and non or low toxicity to improve detection methods. Thirdly, by combining with the high effective separation and enrichment technology analyti-cal process was simplified to reduce interference, realizing the accurate determination of trace lead(Ⅱ).
参考文献
| [1] | 沈健,黄杉生,金丽霞,屈永霞,李瑞娜,余锡宾.Y2O3：Eu纳米颗粒荧光猝灭法测定水中的Pb2+[J].上海师范大学学报（自然科学版）,2007(04):83-87. |
| [2] | 毛红,赵连佳.石墨炉原子吸收法测定次氯酸钠消毒剂中铅的方法研究[J].中国卫生检验杂志,2006(05):561-562. |
| [3] | 周庆祥,白画画,代文华,丁玉杰,汪卫东,赵新宁.浊点萃取-火焰原子吸收光谱法测定环境水样中痕量铅[J].河南师范大学学报（自然科学版）,2007(02):115-118. |
| [4] | Eder C. Lima;Jorge L. Brasil;Ana H. D. P. Santos .Evaluation of Rh, Ir, Ru, W-Rh, W-Ir and W-Ru as permanent modifiers for the determination of lead in ashes, coals, sediments, sludges, soils, and freshwaters by electrothermal atomic absorption spectrometry[J].Analytica chimica acta,2003(2):233-242. |
| [5] | Scancar J;Milacic R;Falnoga I;Cemazar M;Bukovec P .Use of nitric acid in sample pretreatment for determination of trace elements in various biological samples by ETAAS.[J].Journal of Pharmaceutical and Biomedical Analysis: An International Journal on All Drug-Related Topics in Pharmaceutical, Biomedical and Clinical Analysis,2000(6):993-1002. |
| [6] | Kili(c) Z;Acar O;Ulasan M et al.Determination of lead,copper,zinc,magnesium,calcium and iron in fresh eggs by atomic absorption spectrometry[J].Food Chemistry,2002,76(01):107-116. |
| [7] | MariaS.Di nezio;Miriam E.Palomeque;Beatriz S.Fernandez Band .A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2004(2):405-409. |
| [8] | Yusof NA.;Ahmad M. .A flow-through optical fibre reflectance sensor for the detection of lead ion based on immobilised gallocynine[J].Sensors and Actuators, B. Chemical,2003(2):201-209. |
| [9] | 刘丽萍,毛红,张妮娜,张勐,沙博郁.电感耦合等离子体质谱法（ICP-MS）测定运动员食品中铅、砷、镉、铜[J].质谱学报,2006(02):90-93. |
| [10] | Shuyu Chen;Zhifeng Zhang;Huaming Yu;Wenqi Liu;Mei Sun .Determination of trace lead by hydride generation-inductively coupled plasma-mass spectrometry[J].Analytica chimica acta,2002(2):177-188. |
| [11] | TOMIOKA Kenichi,OGUMA Koichi,SEKI Tatsuya.环境样品中痕量铅的流动注射在线分离及分光光度检测[J].环境化学,2003(03):211-214. |
| [12] | 石邦辉,孔祥生,康云华.双硫腙分光光度法测定水中微量铅的改进[J].中华预防医学杂志,2003(04):273-275. |
| [13] | 宋永华.改良双硫腙分光光度法测定水中铅的评价[J].四川省卫生管理干部学院学报,2007(04):266-267. |
| [14] | 刘晓红,李广超.用双硫腙分光光度法同时测定Zn2+、Cd2+和Pb2+[J].徐州师范大学学报(自然科学版),2001(01):40-43. |
| [15] | 龚兰新,康新平,朱冻慧,雷娟.Pb（Ⅱ）一双硫腙一PAR分光光度法测定样品中的铅[J].新疆师范大学学报(自然科学版),2004(02):37-39. |
| [16] | 徐茂军.双硫腙水相直接光度法测定食品中铅[J].中华预防医学杂志,2002(01):52-54. |
| [17] | Comitre ALD;Reis BF .Automatic flow procedure based on multicommutation exploiting liquid-liquid extraction for spectrophotometric lead determination in plant material[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2005(4):846-852. |
| [18] | MariaS.Di nezio;Miriam E.Palomeque;Beatriz S.Fernandez Band .A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2004(2):405-409. |
| [19] | 丁静,孙舒婷,张诺,韩颜颜,陈欣,魏琴.卟啉类显色剂在重金属离子分析中的研究及应用[J].分析测试技术与仪器,2008(01):3-9. |
| [20] | Li Zaijun;Tang Jian;Yang Yuling;Pan Jiaomal .Spectrophotometric determination of trace lead in water after preconcentration using mercaptosephadex[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2003(1):123-130. |
| [21] | Li ZJ;Tang JA;Pan JM .The determination of lead in preserved food by spectrophotometry with dibromohydroxyphenylporphyrin[J].Food Control,2004(7):565-570. |
| [22] | Hu Q;Yang G;Yin J et al.Determination of trace lead,cadmium and mercury by on-line column enrichment followed by RP-HPLC as metal-tetra-(4-bromophenyll)-porphyrin chelates[J].Talanta,2002,57(04):751-756. |
| [23] | Bozkurt, SS;Ayata, S;Kaynak, I .Fluorescence-based sensor for Pb(II) using tetra-(3-bromo-4-hydroxyphenyl)porphyrin in liquid and immobilized medium[J].Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy,2009(4):880-883. |
| [24] | 李竹云.二溴羟基苯基荧光酮光度法测定铅的研究[J].分析科学学报,2003(03):255-257. |
| [25] | 向先国,钟宁.苯芴酮水相显色反应分光光度法测定食品中微量铅[J].预防医学情报杂志,2006(04):402-404. |
| [26] | Ahmed M J;Mamun M A .Spectrophotometric determination of lead in industrial,environmental,biological and soil samples using 2,5-dimercapto-1,3,4-thiadiazole[J].Talanta,2001,55(01):43-54. |
| [27] | 南海军,刘忠芳,刘绍璞,郭丽冰,问国强.铅（Ⅱ）-碘化物-溴化十四烷基吡啶三元络合体系的共振瑞利散射光谱及其分析应用研究[J].光谱实验室,2008(02):249-253. |
| [28] | 余金保,余端略.光度法测定茶叶中可溶性微量铅[J].井冈山师范学院学报,2001(06):8-9. |
| [29] | 袁东,王蓉,孙建光,谭文渊.胶束增敏分光光度法测定牛奶中微量铅[J].四川理工学院学报（自然科学版）,2007(03):38-40. |
| [30] | 潘振声,潘教麦.二溴对氯偶氮羧胂分光光度法测定微量铅[J].冶金分析,2007(01):54-56. |
| [31] | Guozhen Fang;Shuangming Meng;Guizhi Zhang;Jiaomai Pan .Spectrophotometric determination of lead in foods with dibromo-p-methyl-bromosulfonazo[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2001(4):585-589. |
| [32] | Fang G;Liu Y;Meng S et al.Speetrophotometrie determination of lead in vegetables with dibromo-p-methyl-carboxysulfonazo[J].Talanta,2002,57(06):1155-1160. |
| [33] | 范晓燕,董杰.Pb（Ⅱ）-双硫腙-PAR水相光度法测定样品中铅[J].理化检验-化学分册,2001(06):258-260. |
| [34] | 马淞江,李方文.用分光光度法测定电镀废水中的微量铅（Ⅱ）[J].材料保护,2007(02):75-76. |
| [35] | 周连文,刘彦钦,韩士田,石屹.meso-四（4-甲氧基苯基）卟啉分光光度法测定痕量铅的研究[J].光谱实验室,2004(01):24-26. |
| [36] | 王涛,韩士田.水溶性meso-四（4-氯-3-磺酸钠基苯基）卟啉测定食品中铅（Ⅱ）含量的研究[J].食品科学,2008(02):300-301. |
| [37] | 俞善辉,彭志华,吴斌才.微乳液中铅与新显色剂meso-四（2,5-二氟苯基）卟啉的显色反应的研究[J].分析试验室,2003(04):40-43. |
| [38] | 俞善辉,王冰,彭志华,吴斌才.微乳液介质中meso-四（3-羟基苯基）卟啉与铅显色反应的研究[J].理化检验-化学分册,2002(11):546-548. |
| [39] | 俞善辉,蔡正艳,彭志华,高美荣,吴斌才.meso-四（2,5-二氟苯基）卟啉的合成及其与铅（Ⅱ）的显色反应[J].化学试剂,2002(04):223-224,228. |
| [40] | 王正矩,韩文华,廖鸿斌,刘薇.Meso-四-（3,5-二溴-4-羟基苯）卟啉分光光度测定陶瓷中的铅[J].中国陶瓷,2003(01):44-45,3. |
| [41] | 李方,郑怀礼.卟啉配合物-巯基棉体系分光光度法测定中药中铅、镉、铜[J].光谱学与光谱分析,2004(02):197-199. |
| [42] | 周连文,韩士田,刘彦钦,李新民.在阴离子表面活性剂存在下meso-四-（4-吡啶）卟啉与铅的显色反应[J].光谱实验室,2004(06):1063-1065. |
| [43] | 周君,孙嘉彦,桑文军,陈彩红.铅（Ⅱ）-DBONBF-CTMAB吸光光度法测定铅[J].理化检验-化学分册,2004(01):54-54,58. |
| [44] | 付佩玉,曹伟,王正祥,张仁冰.微乳液介质中5′-硝基水杨基荧光酮光度法测定微量铅[J].分析化学,2000(05):597-600. |
| [45] | 魏琴,杜斌,吴丹,欧庆瑜.三甲氧基苯基荧光酮光度法测定生物样品中铅[J].光谱学与光谱分析,2004(11):1400-1403. |
| [46] | 魏琴,寿崇琦,杜斌,欧庆瑜.邻氯基苯基荧光酮光度法测定食品中痕量铅[J].理化检验-化学分册,2004(01):12-14. |
| [47] | 魏琴,李慧芝,杜斌,吴丹,欧庆瑜.微乳液增敏邻硝基苯基荧光酮光度法测定食品中痕量铅[J].分析科学学报,2003(06):540-542. |
| [48] | 李竹云.二溴羟基苯基荧光酮光度法测定铅的研究[J].分析科学学报,2003(03):255-257. |
| [49] | 王丰,李冬梅,冯柏栋,迪拉热.溴代十六烷基三甲基胺存在下铅与苯基荧光酮显色反应的研究[J].理化检验-化学分册,2002(12):607-608. |
| [50] | 潘振声,潘教麦.二溴对氯偶氮羧胂分光光度法测定微量铅[J].冶金分析,2007(01):54-56. |
| [51] | 李竹云.偶氮氯膦-Ⅲ分光光度法测定微量铅的研究[J].食品科学,2002(09):93-96. |
| [52] | 袁莉,任小娜,马永钧.Pb2+-TTA-偶氮磺Ⅲ高灵敏反应用于测定食品添加剂中的Pb[J].分析试验室,2006(11):23-26. |
| [53] | 严德明,吕明,杨闯,崔运成.铅-二甲酚橙-甲基紫三元络合物光度法测定痕量铅[J].吉林师范大学学报(自然科学版),2004(04):53-54. |
| [54] | 宗烨;胡浩;杭永和 等.铅-铋-三溴偶氮胂混合多核络合物显色反应的研究及应用[J].理化检验-化学分册,1996,32(11):356-357. |
| [55] | 郝廷瑶;李华林;齐志贤 等.三溴偶氮肿与铅显色反应的研究及应用[J].冶金分析,1992,12(01):48-50. |
| [56] | 禹雷;刘琴 .双波长分光光度法测定废水痕量铅[J].淮北煤炭师范学院学报,2000,21(04):30-34. |
| [57] | 赵云霞,董云会.催化动力学分光光度法测定微量铅的研究[J].分析科学学报,2003(06):573-575. |
| [58] | 姚绍龙.萃取催化显色动力学光度法测定痕量铅的研究[J].四川师范大学学报(自然科学版),2001(06):599-601. |
| [59] | 黄湘源,陈永晖,季明德.胶束催化动力学光度法测定痕量铅[J].分析化学,2001(12):1484. |
| [60] | Sicilia D;Rubio S;Perez-Bendito D .Improved method for the kinetic catalytic determination of lead(Ⅱ) in dodecyhrimethylammonium micelles[J].Analytica Chimica Acta,1992,266(01):43-50. |
| [61] | 黄湘源,陈永晖,陈虹.催化动力学光度法同时测定痕量铅和镉[J].分析试验室,2002(06):67-70. |
| [62] | 姚绍龙.萃取催化显色动力学光度法测定痕量铅的研究[J].四川师范大学学报(自然科学版),2001(06):599-601. |
| [63] | 张长水,赵武.一种催化动力学光度法测定铅的新方法[J].河南师范大学学报(自然科学版),2003(02):66-69. |
| [64] | 李丽敏,王夕婷.酸性铬兰K褪色分光光度法测定罐头中的铅[J].分析试验室,2007(07):92-94. |
| [65] | 陈伟,郝玉锋,衣秀娟.催化动力学光度法测定茶叶中微量铅[J].预防医学论坛,2004(05):556-557,575. |
| [66] | 李慧芝,杨春霞,姜润田,李洪民.巯基葡聚糖凝胶分离富集动力学光度法测定微量铅[J].分析试验室,2001(01):48-50. |
| [67] | 陈中兰.新型螯合棉分离抑制动力学光度法测定痕量铅[J].分析试验室,2001(06):23-25. |
| [68] | 陈国树,张富生,罗刚.动力学光度法测定痕量铅的研究[J].分析试验室,1994(01):59. |
| [69] | 刘佳铭,梁卫东.阻抑-褪色光度法测定痕量铅（Ⅱ）[J].光谱实验室,2001(05):613-617. |
| [70] | 黄美珍,邹小勇.阻抑动力学光度法测定痕量铅[J].分析试验室,2009(03):19-22. |
| [71] | 田久英,卢菊生,吴宏.阻抑过氧化氢氧化偶氮胂I褪色动力学光度法测定痕量铅和镉[J].冶金分析,2008(03):64-67. |
| [72] | 黄美珍.阻抑动力学光度法测定皮蛋中铅的研究[J].佛山科学技术学院学报（自然科学版）,2008(02):36-38. |
| [73] | 陈国树,张富生,罗刚.动力学光度法测定痕量铅的研究[J].分析试验室,1994(01):59. |
| [74] | 陈中兰.新型螯合棉分离抑制动力学光度法测定痕量铅[J].分析试验室,2001(06):23-25. |
| [75] | 袁冬梅.苹果中微量铅的荧光光度法测定[J].应用化工,2005(06):373-374. |
| [76] | 邓昌爱,夏良树,刘传湘.荧光光度法测定蔬果类罐头食品中的微量铅[J].光谱实验室,2006(03):652-654. |
| [77] | 王诚,冯锋,陈泽忠,卢珍,白云峰,孟双明,林森.新型荧光试剂1-（8-喹啉）-3-（2-吡啶）-三氮烯的合成及其分析应用[J].高等学校化学学报,2008(06):1133-1136. |
| [78] | 龙立平,聂伟安,钟桐生,雷存喜.基于卟啉衍生物荧光熄灭的Pb2+光化学传感器[J].应用化学,2007(07):806-809. |
| [79] | 王树玲,吴晓东,于俊生,陈德芳.荧光光谱法测定中成药中微量铅[J].分析试验室,2003(04):29-32. |
| [80] | 吴根华,汪春华.荧光法研究Pb2+与牛血清白蛋白的相互作用[J].光谱学与光谱分析,2005(02):246-248. |
| [81] | Holynska B;Ostaehowica B;Wegrzynek D .Simple method of determination of copper,mercury and lead in potable water with preliminary pre-concentration by total reflection Xray fluorescence spectrometry[J].Spectrochimica Acta Part B:Atomic Spectroscopy,1996,51(07):769-773. |
| [82] | 李永新,赵丹华,卓淑娟,朱昌青,王伦.共振光散射增强法测定痕量铅[J].安徽师范大学学报(自然科学版),2002(03):260-261,265. |
| [83] | 曾铭.巯基棉分离富集-共振光散射法测定环境水样中痕量铅和镉[J].冶金分析,2007(11):44-47. |
| [84] | 王小红,李树伟,张万诚,苏小东,何艺,潘建章.铅-BSA-刚果红体系共振光散射光谱法测定铅的研究[J].四川师范大学学报(自然科学版),2004(02):198-201. |
| [85] | 李小燕,李树伟,王小红,何艺,潘建章,曾铭.共振光散射比浊法测定环境水样中Pb（Ⅱ）[J].西南民族大学学报（自然科学版）,2005(02):192-194. |
| [86] | Cui YR;Cui FL;Wang L;Zhang QZ;Xue WX;Jing F;Sun JH .Determination of lead in Yellow River using ammonium molybdate as a molecular probe by resonance light scattering technique[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2008(10):1719-1724. |
| [87] | 朱粉霞,杨德玉,张小燕,范晓东,张勤.流动注射化学发光法测定食品营养添加剂中铅[J].食品科学,2003(08):119-121. |
| [88] | 胡涌刚,李欣欣,杨泽玉.Luminol-K3[Fe（CN）6]化学发光法测定汽油中的铅[J].应用化工,2004(03):51-53. |
| [89] | 易钢,徐溢.KMnO4-Luminol化学发光分析体系的研究及尿中铅的测定[J].临床检验杂志,2003(z1):73-75. |
| [90] | 徐溢,唐守渊,夏之宁,易钢.测定汽油中铅的 KMnO4-Luminol 化学发光体系[J].分析测试学报,2001(05):59-61. |
| [91] | 吴永平,高智席,王满力.流动注射化学发光增敏法测定白酒中痕量铅[J].酿酒科技,2007(05):102-104,107. |
| [92] | 瞿鹏,魏敏,李保新,章竹君.流通式化学发光传感器测定汽油中的铅（Ⅱ）[J].应用化学,2008(03):326-329. |
| [93] | 唐守渊,徐溢.Luminol-H2O2化学发光法测定汽油中铅[J].理化检验-化学分册,2003(01):23-25. |
| [94] | 潘元海,刘湘生,何小青,王长华.铅形态的高效液相色谱-电感耦合等离子体质谱分析[J].分析化学,2005(11):1560-1564. |
| [95] | 黄海涛,李忠,陈章玉,王保兴,施红林,杨光宇.固相萃取富集-高效液相色谱法测定烟草和烟草添加剂中的重金属元素[J].理化检验-化学分册,2004(05):251-254. |
| [96] | Szpunar J.;Makarov A.;Doco T.;Williams P.;Medina B. Lobinski R.;Pellerin P. .Speciation analysis for biomolecular complexes of lead in wine by size-exclusion high-performance liquid chromatography inductively coupled plasma mass spectrometry[J].Journal of Analytical Atomic Spectrometry,1998(8):749-754. |
| [97] | Ebdon L.;Rivas C.;Hill SJ. .Lead speciation in rainwater by isotope dilution-high performance liquid chromatography inductively coupled plasma mass spectrometry[J].Spectrochimica Acta. Part B, Atomic Spectroscopy,1998(2):289-297. |
| [98] | 韩得满,贾文平,梁华定,严秀平.流动注射在线置换吸附预富集-火焰原子吸收联用技术测定痕量铅[J].分析化学,2007(11):1643-1646. |
| [99] | 谭春华,梁桂琼,尹诗衡,范广涵,汤志勇.流动注射在线离子交换预富集 HG-AFS测定痕量铅[J].光谱实验室,2004(02):317-320. |
| [100] | 王爱霞,张宏,刘琳琳.流动注射在线分离富集火焰原子吸收法测定环境样品中的铅和镉[J].分析化学,2001(11):1284-1287. |
| [101] | Kuramochi M;Tomioka K;Fujinami M;Oguma K .Rapid determination of lead extracted by acetic acid from glazed ceramic surfaces by flow injection on-line preconcentration and spectrophotometric detection[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2005(2):287-291. |
| [102] | Cankur O;Korkmaz D;Ataman OY .Flow injection-hydride generation-infrared spectrophotometric determination of Pb[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2005(3):789-793. |
| [103] | Yantasee W;Timchalk C;Fryxell GE;Dockendorff BP;Lin YH .Automated portable analyzer for lead(II) based on sequential flow injection and nanostructured electrochemical sensors[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2005(2):256-261. |
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