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采用两步法制备CuGaxIn1-xSe2薄膜,Cu-In-Ga金属预制层采用铜镓合金靶及铟靶通过磁控溅射方法沉积而成,采用固态源硒化法在硒蒸气密闭环境中硒化,通过调整镓(Ga)比例及分布控制CIGS薄膜的带隙,采用镓元素梯度分布,使CIGS薄膜带隙呈现抛物线状分布,电池的量子效率得到明显提高,制备出的CIGS薄膜电池开路电压与转换效率都得到很大程度的改善,电池最高转换效率已达9.4%.

参考文献

[1] Markus E Beckl .Amy Swartzlander-guest,Rick Matson.CuIn (Ga)Se2-based Devices via a Novel Absorber Formation Process[J].Solar Energy Materials and Solar Cells,2000,64:135-165.
[2] Tarrant D E;Gay R R .Commercialization of CIS-based Thin-film PV[R].Siemens Solar Industries Camarillo,California.Final Technical Report,2001.
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[4] Olle Lundberg;Marika Bodegard;Jonas Malmstrom .Influence of the Cu(In,Ga)Se_2 Thickness and Ga Grading on Solar Cell Performance[J].Progress in photovoltaics,2003(2):77-88.
[5] Dullwebera T;Hannaa G;Shams-Kolahia W;Schwartzlanderb A Contrerasb M A Noufi R .Study of the Effect of Gallium Grading in Cu(In,Ga)Se2[J].Thin Solid Films,2000,361-362:478-481.
[6] Dullweber T.;Rau U.;Schock HW.;Hanna G. .A new approach to high-efficiency solar cells by band gap grading in Cu(In,Ga)Se-2 chalcopyrite semiconductors[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2001(1/4):145-150.
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