欢迎登录材料期刊网

材料期刊网

高级检索

采用双(异硫氰酸甲酸)-缩二乙二酯与多元胺进行加聚反应制得主链上含有硫脲基团的新型螯合树脂(PDTU).用静态吸附法研究了PDTu树脂对金离子的吸附性能,PDTU-Ⅰ-Ⅳ对Au(Ⅲ)的吸附量分别为2.91,4.09,4.49和4.65 mmol/g.PDTu对Au(Ⅲ)的吸附容量随时间的增加、Au(Ⅲ)初始浓度的增大和温度的升高而增大,吸附数据符合Boydl液膜扩散方程和Langmuir等温式,吸附过程为吸热过程.

参考文献

[1] Asem A Aria .Adsorption of silver(Ⅰ)and gold(Ⅲ)on resins derived from bisthiourea and application to retrieval of silver ions from processed photo films[J].Hyarometallurgy,2005,80:98-106.
[2] S Siddhanta;H R Das .Separation and concentration of some platinum metal ion with a chelating resin containing thiosemicarbazide as function group[J].Tanlanta,1985,32(06):457-460.
[3] Guangju Zuo;Mamoun Muhammed .Thiourea-based coordinating polymers:synthesis and binding to noble metals[J].Reactive Polymers,1995,24:165-181.
[4] 李华,路建美,纪顺俊,王丽华,祁秀秀,肖猛.微波辐射条件下含硫螯合树脂的合成及性能[J].高分子材料科学与工程,2004(04):81-84.
[5] 胡章云 .结晶紫分光光度法快速测定金[J].江西地质科技,1997,24(02):96-98.
[6] Boya G E;Adamson A W;Myers L S .The exchange adsorption of ions from aqueous solution by organic zeolites Ⅱ.Kinetics[J].Journal of the American Chemical Society,1947,69(03):2836-2848.
[7] Ayhan Demirba;Erol Pehlivan;Fethiye Gode .Adsorption of Cu(Ⅱ),Zn(Ⅱ),Ni(Ⅱ),Pb(Ⅱ),and Cd(Ⅱ)from aqueous solution on Amberlite IR-120 synthetic resin[J].Journal of Colloid and Interface Science,2005,282:20-25.
[8] Nirmalya Maity;Gregory F Payne;Michael V Ernest et al.Caffeine adsorption from aqueous solutions onto polymeric sorbents:The effect of surface chemistry on the adsorptive affinity and adsorption enthalpy[J].Reactive Polymers,1992,17(03):273-287.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%