利用纯金板作阳极,不锈钢板作阴极,配位体Y为电解液,在阳离子膜电解槽中电解制备无氰水溶性金溶液,探索了该工艺各种参数和反应条件.研究结果表明,电化学合成该溶液的最佳条件为:阳极电解液Y浓度1～3mol/L,阴极电解液Y浓度0.1～1.0mol/L,槽电压 15～20V,温度30℃～40℃,电解时间3h;实验所得的无氰水溶性金溶液质量浓度为1.26g/L,电流效率可达到5%.
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