聚苯胺对金属防腐蚀有较好的效果,本征态聚苯胺对金属的防腐蚀性目前研究较少.采用化学氧化法合成了本征态聚苯胺(EB),以动电位扫描法研究了不同介质溶液中EB对45钢的腐蚀防护性能.XRD图谱分析表明,所合成的EB具有一定的结晶性,在2θ=19.18°处有一很强的衍射峰,在2θ=24.4°处出现了一较弱的衍射峰.极化曲线表明,涂覆有本征态聚苯胺的45钢的腐蚀电流减小,腐蚀速度降低;EB对45钢有一定的防腐蚀作用.
参考文献
[1] | Mirmohseni A.;Oladegaragoze A. .Anti-corrosive properties of polyaniline coating on iron[J].Synthetic Metals,2000(2):105-108. |
[2] | Ozyilmaz AT;Erbil A;Yazici B .Investigation of corrosion behaviour of stainless steel coated with polyaniline via electrochemical impedance spectroscopy[J].Progress in Organic Coatings: An International Review Journal,2004(1):47-54. |
[3] | Ogurtsov N A;Pud A A;Kamarchik P et al.Corrosion inhibition of aluminum alloy in chloride mediums by undoped and doped forms of polyaniline[J].Synthetic Metals,2004,143:41-47. |
[4] | Ozyilmaz AT;Tuken T;Yazici B;Erbil M .The electrochemical synthesis and corrosion performance of polyaniline on copper[J].Progress in Organic Coatings: An International Review Journal,2005(2):92-97. |
[5] | Yfantis A.;Paloumpa I.;Schmeisser D.;Yfantis D. .Novel corrosion-resistant films for Mg alloys[J].Surface & Coatings Technology,2002(0):400-404. |
[6] | 陆珉;吴意华;姜海夏 等.高导电率聚苯胺[J].功能材料,1998,29(05):483-485. |
[7] | Talo A.;Forsen O.;Ylasaari S.;Passiniemi P. .POLYANILINE/EPOXY COATINGS WITH GOOD ANTI-CORROSION PROPERTIES[J].Synthetic Metals,1997(1/3):1333-1334. |
[8] | Santos JR.;Motheo AJ.;Mattoso LHC. .Investigation of corrosion protection of steel by polyaniline films[J].Electrochimica Acta,1998(3/4):309-313. |
[9] | Ahmad N;Macdiarmid A G .Inhibition of corrosion of steels with exploitation of conducting polymers[J].Synthetic Metals,1996,78:103-110. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%