具有高吸附性能的载体-TiO2光催化剂复合材料制备是未来TiO2纳米光催化研究领域的重要发展方向.本文以凹凸棒石为载体,通过钛酸四丁酯-丙醇溶液浸渍-过滤-丙醇蒸发-水蒸气作用下钛酸四丁酯水解-低温煅烧程序操作,获得凹凸棒石-TiO2纳米复合光催化材料.高分辨透射电镜表征结果显示:TiO2颗粒直径5~10nm,具有锐钛矿结构,在凹凸棒石表面分布均匀.该制备方法工艺简单,钛酸四丁酯利用率高,对水中有机污染物光催化处理、抗菌消毒、空气净化等方面具有很大潜在应用价值.
参考文献
[1] | 范崇政,肖建平,丁延伟.纳米TiO2的制备与光催化反应研究进展[J].科学通报,2001(04):265-272. |
[2] | Hoffmann A J;Carraway E R;Hoffmann M R .Potocatalytic production of H2O2 and organic peroxides on quantum- sized semiconductor colloids[J].Environmental Science and Technology,1994,28(05):776-785. |
[3] | 张志军;包志成;王克欧 等.二氧化钛催化下的二苯并-对-恶英光解反应[J].环境化学,1996,15(01):47-51. |
[4] | 王怡中;符雁;汤鸿霄 .甲基橙溶液多相光催化降解研究[J].环境科学,1998,19(01):1-4. |
[5] | Q. Dai;L. Y. Shi;Y. G. Luo;J. L. Blin;D. J. Li;C. W. Yuan;B. L. Su .Effects of templates on the structure, stability and photocatalytic activity of mesostructured TiO_2[J].Journal of Photochemistry and Photobiology, A. Chemistry,2002(1/3):295-301. |
[6] | Yu-Hsiang Hsien;Chi-Fu Chang;Yu-Huang Chen;Soofin Cheng .Photodegradation of aromatic pollutants in water over TiO_2 supported on molecular sieves[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2001(4):241-249. |
[7] | J.Matos;J.-M.Herrmann;J.Laine .Effect of the Type of Activated Carbons on the Photocatalytic Degradation of Aqueous Organic Pollutants by UV-Irradiated Titania[J].Journal of Catalysis,2001(1):10-20. |
[8] | Ettireddy P.Reddy;Lev Davydov;Panagiotis Smirniotis .TiO_2-loaded zeolites and mesoporous materials in the sonophotocatalytic decomposition of aqueous organic pollutants: the role of the support[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(1):1-11. |
[9] | 王长平,王琪,董浩,张辉,李计元.载TiO2海泡石粉体的研制[J].硅酸盐通报,2004(01):31-34. |
[10] | 陈天虎,朱光,徐惠芳,王道轩,岳书仓,刘国生.安山质熔结凝灰岩中凹凸棒石断层岩的矿物学特征[J].岩石学报,2003(04):767-774. |
[11] | Xu HF.;Wang XF. .Crystallization sequence and microstructure evolution of Synroc samples crystallized from CaZrTi2O7 melts[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2000(1):100-106. |
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