欢迎登录材料期刊网

材料期刊网

高级检索

概述了有关CH4和CO2重整反应在固体氧化物燃料电池(SOFC)中的研究进展.对该反应在SOFC阳极活化及重整的反应机理进行了探讨;讨论了反应温度、压力等因素对阳极表面产生积碳的影响,分析了有利于消除积碳、促进反应进行的压力及温度范围;介绍了开发新型、高效、抗积碳的阳极材料来改善SOFC阳极积碳状况的方法,如:在阳极材料中添加不同的活化成分、助剂及选择不同载体等.

参考文献

[1] Wang S B;Lu G Q M.CO2 reforming of methane on Ni catalysts:Effects of the support phase and preparation technique[J].Applied Catalysis B:Environmental,1998(16):269-277.
[2] 王亚权;张再义;陈建滨.甲烷二氧化碳氧气氧化重整的研究[J].化学工程师,1996(55):9-11.
[3] 朱建华;胡玉海 .甲烷-二氧化碳重整反应制取合成气的新进展[J].江苏化工,1998,26(02)
[4] Mariana M.V.M.Souza;Martin Schmal .Combination of carbon dioxide reforming and partial oxidation of methane over supported platinum catalysts[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2003(1):83-92.
[5] Vankeulen ANJ.;Hoebink JHBJ.;Ross JRH.;Seshan K. .TAP INVESTIGATIONS OF THE CO2 REFORMING OF CH4 OVER PT/ZRO2[J].Journal of Catalysis,1997(2):306-314.
[6] Nagaoka K;Seshan K;Aika K I.Carbon deposition during carbon dioxide reforming of methane-comparison between Pt/Al2 O3 and Pt/ZrO2[J].Journal Of Catalysis,2001(197):34-42.
[7] Moon D J;Ry(u) J W.Electrocatalytic refoming of carbon dioxide by methane in SOFC system[J].Catalysis Today,2003(87):255-264.
[8] Takeguchi T;Kani Y.Study on steam reforming of CH4 and C2 hydrocarbons and carbon deposition on Ni-YSZ cermets[J].Journal of Power Sources,2002(112):588-595.
[9] 许峥,张鎏,张继炎.Ni/γ-Al2O3催化剂上CH4-CO2重整体系中积碳-消碳的研究[J].催化学报,2001(01):18-22.
[10] 孙希贤.甲烷二氧化碳转化制备富含一氧化碳合成气[J].高等学校化学学报,1992(10):1302.
[11] 魏俊梅;李文英;谢客昌 .二氧化碳重整甲烷过程中催化剂积碳现象的讨论[J].煤炭转化,1997,20(01):32-39.
[12] Shams A;Johnson C D.Effect of pressure on the carbon deposition route in CO2 reforming of13 CH4[J].Catalysis Today,2003(84):17-25.
[13] Takeguchi T;Kikuchi R.Effect of precious metal addition to Ni-YSZ cermets on reforming of CH4 and electrochemical activity as SOFC anode[J].Catalysis Today,2003(84):217-222.
[14] Sauvet A L;Fouletier J.Surface properties and physicochemical characterizations of a new type of anode material,La1-x SrxCr1-y RuyO3-δ,for asolid oxide fuel cell under methane at intermediate temperature[J].Journal Of Catalysis,2002(209):25-34.
[15] 吴俊荣.CH4与CO2重整制合成气研究进展[J].广州大学学报(自然科学版),2003(05):430-437.
[16] Xu Guolin .Studies of reforming natural gas with carbon dioxide to produce synthesis gas X.The role of CeO_2 and MgO promoters[J].Journal of molecular catalysis, A. Chemical,1999(0):47-54.
[17] Mobius H H;Rohland B .[P].US 3377203,1968-04-09.
[18] Taeyoon Kim;Sangjin Moon;Suk-In Hong .Internal carbon dioxide reforming by methane over Ni-YSZ-CeO_2 catalyst electrode in electrochemical cell[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2002(1/2):111-120.
[19] 陈仰光;任杰;吴东 .甲烷、二氧化碳重整催化剂的研究Ⅱ.MgO_CeO2双金属氧化物对Ni/γ-Al2O3催化剂抗积炭性能的影响[J].石油化工,1994,23(12):771-775.
[20] 姬涛,董新法,林维明.CH4、CO2和O2制合成气镍基催化剂的研究Ⅲ.助剂CeO2的作用[J].天然气化工,2001(01):23-26.
[21] Lemonidou A A;Vasalos I A.Carbon dioxide reforming of methane over 5 wt.% Ni/CaO-Al2 O3 catalyst[J].Applied Catalysis A:General,2002(228):227-235.
[22] P. Vernoux;J. Guindet;M. Kleitz .Gradual internal methane reforming in intermediate-temperature solid-oxide fuel cells[J].Journal of the Electrochemical Society,1998(10):3487-3492.
[23] Vernoux P.;Fouletier J.;Hammou A.;Guillodo M. .Alternative anode material for gradual methane reforming in solid oxide fuel cells[J].Solid state ionics,2000(1/4):425-431.
[24] Bradford M C J.Catalytic reforming of methane with carbon dioxide over nickel catalysts[J].Applied Catalysis A:General,1996(142):73-96.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%