以水滑石为前驱体,制备了一系列铁镁铝复合氧化物,并采用XRD对其结构进行表征.研究这类氧化物脱除低浓度二氧化硫的反应活性.结果表明:含铁水滑石焙烧产物吸附低浓度二氧化硫的性能良好.在大于600℃吸附温度下,具有较好吸附性能.吸附剂本身制备条件对吸附性能影响较明显.负载Fe2O3后吸附性能明显提高.氢还原是再生吸附剂的可行方法.
参考文献
[1] | 南京化学工业公司研究院.低浓度二氧化硫烟气脱硫[M].上海:上海科学技术出版社,1981 |
[2] | 杨硕芳.湿法烟气脱硫技术综述[J].环境工程,1989(02):1-5. |
[3] | Pinnavaia T J;Amarasekera J .Layered double hydroxide sorbents for the removal of SOx from flue gas resulting from coal combustion[P].US 5116587,1992-05-26. |
[4] | Lange J;Brumsack H J .Total sulphur analysis in geological and biological materials by coulometric titration following combustion[J].Fresenius'Journal of Analytical Chemistry,2004,286(05):361-366. |
[5] | 俞卫华,倪哲明,王力耕,周春晖,郭志强,葛忠华.镁铝水滑石的制备和脱硝性能的研究[J].科技通报,2003(04):330-333. |
[6] | Yoo J S;Bhattacharyya A A;Radlowski C A .De-SOx Catalyst:An XRD study of Magnesium aluminate spinel and its solid solution[J].Industrial and Engineering Chemistry Research,1991,30:1444-1448. |
[7] | Pinnavaia T J;Amarasekera J;Polansky C A .Layered double hydroxide sorbents for the removal of SO.sub.x from flue gas and other gas streams[P].US 5114898,1992-19. |
[8] | Pinnavaia T J;Amarasekera J;Polansky C A .Process using sorbents for the removal of SO from flue gas[P].US 5114691,1992. |
[9] | Palomares A E;Lopez-nieto J M;Lazaro F J et al.Reactivity in the removal of SOx and NOx on Co/Mg/Al mixed oxides derived from hydrotalcites[J].Applied Catalysis B:Environmental,1999,20:257-266. |
[10] | Corma A.;Rey F.;Marquez F.;Palomares AE. .SIMULTANEOUS CATALYTIC REMOVAL OF SOX AND NOX WITH HYDROTALCITE-DERIVED MIXED OXIDES CONTAINING COPPER, AND THEIR POSSIBILITIES TO BE USED IN FCC UNITS[J].Journal of Catalysis,1997(1):140-149. |
[11] | 王学中,刘玉敏,吴越.水滑石衍生复合氧化物的CO催化还原NO的性能[J].物理化学学报,1999(01):50. |
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