采用射频磁控溅射技术在柔性基体PI(聚酰亚胺)上制备了纳米CeO2-TiO2复合薄膜.借助X射线衍射(XRD)、原子力显微镜(AFM)和紫外-可见光谱仪分别研究了薄膜的物相结构、表面生长形貌和薄膜的紫外-可见光透过率及光学能隙,并用WS-2000型薄膜划痕仪测定薄膜与基体的界面结合强度.实验结果表明:沉积态的薄膜为非晶态,经200℃退火处理4h后,转化为良好的晶态,薄膜中主要含有锐钛矿相结构;溅射功率对薄膜的形貌,光学性能及界面结合力均有影响.尤其当溅射功率为120W时,薄膜的综合性能最优;平均晶粒尺寸110nm,表面粗糙度为160nm,吸光率达80%,光学能隙Eg仅为(2.65±0.05)eV,划痕法测量涂层与基体的附着力为60N.
参考文献
[1] | Lewis LN;Spivack JL;Gasaway S;Williams ED;Gui JY;Manivannan V;Siclovan OP .A novel UV-mediated low-temperature sintering of TiO2 for dye-sensitized solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(7/8):1041-1051. |
[2] | Suwalsky M;Schneider C;Mansilla HD;Kiwi J .Evidence for the hydration effect at the semiconductor phospholipid-bilayer interface by TiO2 photocatalysis[J].Journal of Photochemistry and Photobiology, B. Biology: Official Journal of the European Society for Photobiology,2005(3):253-258. |
[3] | T. Anukunprasert;C. Saiwan;E. Traversa .The development of gas sensor for carbon monoxide monitoring using nanostructure of Nb-TiO_2[J].Science and technology of advanced materials,2005(3/4):359-363. |
[4] | Busani T;Devine RAB .Dielectric and infrared properties of TiO2 films containing anatase and rutile[J].Semiconductor Science and Technology,2005(8):870-875. |
[5] | L. Zhou;S. Yan;B. Tian .Preparation of TiO_2-SiO_2 film with high photocatalytic activity on PET substrate[J].Materials Letters,2006(3):396-399. |
[6] | Sanchez B;Coronado JM;Caudal R;Portela R;Tejedor I;Anderson MA;Tompkins D;Lee T .Preparation of TiO2 coatings on PET monoliths for the photocatalytic elimination of trichloroethylene in the gas phase[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2006(3/4):295-301. |
[7] | 张乃枝 .溅射法制备CeO<,2>-TiO<,2>薄膜的结构性能研究[D].武汉理工大学,2004. |
[8] | 井立强,孙晓君,辛柏福,王百齐,蔡伟民,付宏刚.掺杂镧和铈的TiO2纳米粒子的结构相变[J].材料科学与工艺,2004(02):148-152. |
[9] | Siegert M;Plischke;MSiegert M .Instability in surface growth with different[J].Physical Review Letters,1992,68:2035-2038. |
[10] | 吴自勤;王兵.薄膜生长[M].北京:科学出版社,2001 |
[11] | 肖循.纳米TiO2薄膜紫外-可见透射光谱研究[J].湖北民族学院学报(自然科学版),2005(03):246-248. |
[12] | Barnett S A;Shinn M .Plastic and elastic properties of com-positionally modulated thin films[J].Annual Review of Materials Science,1994,24:481-511. |
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