用溶胶-凝胶法合成的无机/有机杂化材料结合SiC+ C混合粉料制成了反应烧结碳化硅陶瓷素坯,并对由这种素坯制成的碳化硅陶瓷进行了物相鉴定和显微结构观察:借助Si-C相图对反应烧结碳化硅的烧结机理进行了研究,分析表明其主要烧结机理为溶解-再沉淀型。
Reaction-sintered silicon carbide(RSSiC) green bodies have been prepared using inorganic/organic hy-brid synthesized by sol - gel process and SiC + C mixture as adhesive and shaping powder, respectively.For the SiC ceramics made from these green bodies, phases identification and microstructural observationwere performed. Studies on the sintering mechanism of RSSiC were carried out by means of Si- C phasediagram. Theoretical analysis shows that the principal mechanism is solution-reprecipitation.
参考文献
[1] | Singh M;Behrendt D R .Microstructure and mechanical properties of reaction-formed silicon carbide (RFSC) ceramics[J].Materials Science and Engineering A,1994,187:183-187. |
[2] | Robert P Messner;Chiang Yet- Ming .Liquid-phase reaction-bonding of silicon carbide using alloyed silicon - molybdenum rnelts[J].Journal of the American Ceramic Society,1990,73(05):1193-1200. |
[3] | Singh M;Behrendt D R .Reactive melt infiltration of silicon-niobium alloys in microporous carbons[J].Journal of Materials Research,1994,9(09):1701-1708. |
[4] | Ness J N;Page T F .Microstructural evolution in reaction-bonded silicon carbide[J].Journal of Materials Science,1986,21(04):1377-1397. |
[5] | Me ng G W;Zhang L D;Qin Y .Formation of β-SiC nanorods with amorphous SiOz wrappi ng layers[J].Journal of Materials Science Letters,1999,18(15):1255-1257. |
[6] | Minnear W P .Interfacial energies in the Si - SiC System and the Si +C reaction[J].Journal of the American Ceramic Society,1982,65(01):C10-C11. |
[7] | HASET;Suzaki H .Rise in temperature of SiC pellet involving reaction sintering[J].Journal of Nuclear Materials,1976,59(01):42-48. |
[8] | Swain M V;郭景坤.陶瓷结构与性能[M].北京:科学出版社,1998:153-232. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%