分别采用静态坩埚抗渣法和回转抗渣法,对w(Cr2 O3)=10%的A和B两种Al2 O3-Cr2 O3砖进行了抗渣性能对比。结果发现:两种砖的化学组成、显气孔率、体积密度和抗热震性相近,B砖强度优于A砖的。但由于与B砖相比,A砖内部气孔尺寸更小,所用电熔白刚玉骨料形貌平滑,较为致密,粒度呈连续式分布,且A砖中Al2 O3-Cr2 O3固溶体发育较小,相互交错,形成了孔隙较小的空间网状结构,这种显微结构显著降低了熔渣对耐火材料的渗透和破坏,使A砖的抗渣性优于B砖的。因此,制备微气孔化结构的制品是提高Al2 O3-Cr2 O3材料抗渣性能的有效途径。
The slag resistance of two Al2 O3-Cr2 O3 bricks (with 10 mass%Cr2 O3 )A and B were researched using static crucible method and rotary slag method,respectively.The results show that,two Al2 O3-Cr2 O3 bricks have similar properties such as apparent porosity,bulk density,thermal shock resistance,and chem-ical compositions.Brick B has higher strength than brick A.Compared with brick B:brick A has smaller in-ner pores,because the white corundum aggregates in brick A are smoother and denser with continuous particle size distribution;Al2 O3-Cr2 O3 solid solution in brick A is smaller,crossing and forming net structure with small gaps,which reduces the penetration and wear of slag to refractories,meaning that brick A has better slag resistance than brick B.It’s obvious that optimizing microstructure is an effective way to im-prove the slag resistance of Al2 O3-Cr2 O3 materials.
参考文献
[1] | 尹洪基.垃圾熔融炉用Al2O3-Cr2O3砖的改进[J].耐火与石灰,2010(01):34-36. |
[2] | 孙红刚,闫双志.浅谈HIsmelt炼铁工艺用耐火材料[C].第5届中国金属学会青年学术年会论文集,2010:402-406. |
[3] | 王刚,方旭,孙红刚,闫双志.改善水煤浆气化炉内衬耐火材料抗侵蚀性能的探讨[J].煤化工,2009(04):45-47. |
[4] | 孙红刚,闫双志,王刚,耿可明,王金相.不同气氛中高铬材料的抗煤熔渣性研究[J].耐火材料,2010(04):264-267. |
[5] | Bennett J P;Kwong K S;Powell C.An analysis of the causes of failure in high chrome oxide refractory materials from slagging gasifi-ers[A].Orlando,US,2005:935-939. |
[6] | Collins W K;Dahlin C L;Bennett J P et al.SEM evaluation of ad-vanced refractory failures in slagging gasifiers[J].Microsc Micro-anal,2005,11(z2):1582-1584. |
[7] | James P B .Refractory linermaterials used in slagging gasifiers[J].Refract Appl News,2004,9(05):20-25. |
[8] | 李丹,冯宝琦,侯书波,张涛.煤焦浆气化炉用耐火材料的选择[J].大氮肥,2007(04):283-286. |
[9] | Bilkerman J J.Surface chemistry[M].New York:Academic Press,Inc,1958:23-26. |
[10] | 蒋明学;陈肇友 .炉渣在耐火材料中的等温渗透[J].硅酸盐学报,1980,18(03):256-261. |
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