长期以来,电镀铬通常采用六价铬电镀液.近年来,由于六价铬对环境等方面带来污染影响,于是加紧了对三价铬电镀的研究.实际上提出用三价铬代替六价铬的研究已经有很长时间.用三价铬镀装饰铬与六价铬电镀相比,具有很多优异特性,但在实际应用中也存在一些问题,其可镀性受到一定限制.因此,用三价铬电镀功能性铬还没有被实际广泛应用.还介绍了三价铬电镀的机理及展望,并提出了有待深入研究的问题.
参考文献
[1] | E1 Sharif M;Chisholm C V .Characteristics of electrodeposited chromium[J].Transactions of the Institute of Metal Finishing,1997,75(06):208-212. |
[2] | Jamese H;Lindsay.Decorative and hard chromium plating[J].Plating and Surface Finishing,2004(08):16-17. |
[3] | El-Sharif M;Chisholim C V .Electrodeposition of thick chromium coatings from an environmentally acceptablc chromium (Ⅲ)glycine complex[J].Transactions of the Institute of Metal Finishing,1999,77(04):139-144. |
[4] | 屠振密.三价铬镀铬的国内外研究和发展[J].哈尔滨工业大学学报,1980(01):109-121. |
[5] | T. Pearson;E. Long .Electrodeposition from trivalent chromium electrolytes[J].Transactions of the Institute of Metal Finishing,1998(6):B83-B85. |
[6] | Lansdell P;Farr J P G .The corrosion resistance of chromium electroplated from trivalent and hexavalent chromium plating solutions[J].Transactions of the Institute of Metal Finishing,1997,75(06):219-223. |
[7] | Donald L;Snyder.Decorative chromium plating[J].Metal Finishing Guidebook,1999(11):40-42. |
[8] | Ibrahim K;Watson A .The role of formic acid and methanol on speciation rate and quality in the electrodeposition of chromium from trivalent electrolytes[J].Transactions of the Institute of Metal Finishing,1997,75(05):181-185. |
[9] | Ibrahim K;Watson A .Corrosion and wear resistance of thick chromium deposits from accelerated Cr (Ⅲ)electrolytes[J].Transactions of the Institute of Metal Finishing,1998,76(04):156-159. |
[10] | Solovyeva Z A .The mechanism of electrodepositing of chromium coatings with different phases structure[J].Plating and Surface Finishing,1998,85(04):87-95. |
[11] | 何湘柱,龚竹青,蒋汉瀛.Cr(Ⅲ)水溶液电沉积非晶态铬的电化学[J].中国有色金属学报,2000(01):95-100. |
[12] | 屠振密,杨哲龙.甲酸盐-乙酸盐体系三价铬电镀工艺[J].材料保护,1985(06):8. |
[13] | Tu Zhenmi;Yang Zhelong .Cathode polarization in trivalent chromium plating[J].Plating and Surface Finishing,1993,79(09):78-82. |
[14] | Tu Zhenmi;Yang Zhelong;Zhang Jingshuang.Pulse plating with a trivalent chromium plating bath[J].Plating and Surface Finishing,1990(10):55-57. |
[15] | 三价铬水溶液电镀非晶态铬工艺[J].中国有色金属学报,1999(03):646. |
[16] | 王先友.三价铬电镀工艺与机理的研究[A].合肥:中国表面工程协会电镀分会,1997:21-23. |
[17] | El Sharif M .Environmentally acceptable process from electrodeposition of hard chromium (Ⅲ)electrolyte[J].Transactions of the Institute of Metal Finishing,1995,73(01):19-25. |
[18] | M.El-Sharif .Replacing hexavalent chromium in electroplating[J].Transactions of the Institute of Metal Finishing,1997(6):B143-B147. |
[19] | Anii Baral;Robert Engelken .Modeling,optimization and comparative analysis of trivalent electrodeposition from aqueous glycine and formic acid baths[J].Journal of the Electrochemical Society,2005,152(07):C504-C512. |
[20] | 吴慧敏,康健强,左正忠,梁国柱,赵国鹏.全硫酸盐体系三价铬电镀铬的研究[J].武汉大学学报(理学版),2004(02):187-191. |
[21] | R.P. Renz;J.J. Fortman;E.J. Taylor .Electrically Mediated Process For Functional Trivalent Chromium To Replace Hexavalent Chromium: Scale-up for Manufacturing Insertion[J].Plating & Surface Finishing,2003(6):52-58. |
[22] | 胡耀红,陈力格,刘建平.三价铬镀铬工艺及其新型阳极的初步研究[J].电镀与涂饰,2004(02):19-21. |
[23] | 胡耀红,陈力格,赵国鹏,刘建平,洪榕.三价铬镀铬阳极的研究[J].材料保护,2006(04):26-28,31. |
[24] | Manich N V .Chemistry & theory of chromium deposition:part I-chemistry[J].Plaing & Surface Finishing,1997,84(05):108-114. |
[25] | 江琳才.铬(Ⅲ)离子的阴极还原过程研究[J].高等学校化学学报,1989(05):551. |
[26] | Y. B. Song;D. -T. Chin .Current efficiency and polarization behavior of trivalent chromium electrodeposition process[J].Electrochimica Acta,2002(4):349-356. |
[27] | 李国华,赖奂汶,黄清安.三价铬镀液中配体的作用[J].材料保护,2005(12):44-46. |
[28] | Smith A M;Watson A;Vaughan D H .The role of oligomeric olated species in the deposition rate of chromium from a commercial chromium(Ⅲ)electrolyte[J].TIMF,1993,71(03):106-112. |
[29] | Duan S;Li H;Zhang X et al.Hard chromium plating from a trivalent plating bath[J].Plating and Surface Finishing,1995,82(06):84-86. |
[30] | Snyder D L.Distinguishing trivalent deposits by color[J].Plating and Surface Plating,2003(11):34-39. |
[31] | 杨哲龙,屠振密,张景双,安茂忠.三价铬电镀的新进展[J].电镀与环保,2001(02):1-3. |
[32] | G. Hong;K.S.Siow;G.Zhiqiang .Hard Chromium Plating From Trivalent Chromium Solution[J].Plating & Surface Finishing,2001(3):69-75. |
[33] | R.P. Renz;J.J. Fortman;E.J. Taylor .Electrically Mediated Process For Functional Trivalent Chromium To Replace Hexavalent Chromium: Scale-up for Manufacturing Insertion[J].Plating & Surface Finishing,2003(6):52-58. |
[34] | R.P. Renz;J.J. Fortman;E.J. Taylor .Electrically Mediated Process For Functional Trivalent Chromium To Replace Hexavalent Chromium: Scale-up for Manufacturing Insertion[J].Plating & Surface Finishing,2003(6):52-58. |
[35] | Nam Kee-Seok;Lee Ku-Hyun;Shik-Cheol Kwon et al.Improved wear and corrosion resistance of chromium(Ⅲ)plating by oxynitrocarburising and steam oxidation[J].Materials Letters,2004,58:3540-3544. |
[36] | Hamid ZA;Ghayad IM;Ibrahim KM .Electrodeposition and characterization of chromium-tungsten carbide composite coatings from a trivalent chromium bath[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,2005(6):573-579. |
[37] | Donald L;Snyder .Decorative chromium plating[J].Metal Finishing,1999,97(01):219-226. |
[38] | M.R. Bayati;M.H. Shariat;K. Janghorban .Design of chemical composition and optimum working conditions for trivalent black chromium electroplating bath used for solar thermal collectors[J].Renewable energy,2005(14):2163-2178. |
[39] | Kwon S C;Kim M;Park S U et al.Charaterization of intermediate Cr-C layer fabricated by electrodeposition in hexavalent and trivalent chromium baths[J].Materials Science Forum,2005,475-479:3823-3826. |
[40] | Wang Feng;Watanabe Tohru .Preparation and characterization of the electrodepositioned Fe-Cr alloy film[J].Materials Science and Engineering,2003,A349:183-190. |
[41] | Maurice Pye .Alternatives to Decorative Hexavalent Chrome Electrodeposits[J].Transactions of the Institute of Metal Finishing,2001(5):B83-B84. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%