采用双-[γ-(三乙氧基硅)丙基]四硫化物(BTESPT)硅烷钝化液对热镀铝锌钢板进行了钝化处理.研究了在5%NaCl溶液中未钝化、硅烷钝化及铬酸盐钝化热镀铝锌钢板的极化曲线和电化学交流阻抗谱.通过中性盐雾试验比较了硅烷钝化膜与铬酸盐钝化膜的耐蚀性能.结果表明:经硅烷钝化液钝化后的热镀铝锌钢板,其腐蚀电位和电流密度下降,极化电阻增大,硅烷钝化膜抑制了热镀铝锌钢板的腐蚀过程,使得耐蚀性能远远高于铬酸盐钝化后的热镀铝锌钢板.
参考文献
[1] | 郑环宇,安茂忠,赖勤志.镀锌层无铬钝化工艺的研究[J].材料保护,2005(09):18-21. |
[2] | 韩克平.镀锌层表面硅酸盐防腐膜的研究[J].腐蚀科学与防护技术,1997(02):167. |
[3] | Dalbin S;Maurin G;Nogueira RP;Persello J;Pommier N .Silica-based coating for corrosion protection of electrogalvanized steel[J].Surface & Coatings Technology,2005(2/3):363-371. |
[4] | 杨柳,刘光明,钱余海,杜楠.镀锌钢板铈盐钝化的电化学性能研究[J].表面技术,2006(06):11-14. |
[5] | Kunitsuqu Aramaki .A self-healing protective film prepared on zinc by treatment in a Ce (NO3) 3 solution and modification with Ce (NO3) 3[J].Corrosion Science,2005,47(05):1285-1298. |
[6] | 胡会利,李宁,程瑾宁.镀锌植酸钝化膜耐蚀性的研究[J].电镀与环保,2005(06):21-25. |
[7] | 宫丽,卢燕平.纳米硅溶胶/丙烯酸复合防蚀薄膜的研究[J].材料保护,2005(01):17-19. |
[8] | 吴森纪.有机硅及其应用[M].上海:上海科学技术文献出版社,1990:315-320. |
[9] | Kogure M.;Paterson R.;Hosaka M.;Kim JJ.;Mcfadzean S.;Ohya H. .PROPERTIES OF NEW INORGANIC MEMBRANES PREPARED BY METAL ALKOXIDE METHODS .2. NEW INORGANIC ORGANIC ANION-EXCHANGE MEMBRANES PREPARED BY THE MODIFIED METAL ALKOXIDE METHODS WITH SILANE COUPLING AGENTS[J].Journal of Membrane Science,1997(1):161-169. |
[10] | Amar Prasad Yadav;Atsushi Nishikata;Tooru Tsuru .Degradation mechanism of galvanized steel in wet-dry cyclic environment containing chloride ions[J].Corrosion Science,2004(2):361-376. |
[11] | Danqing Zhu;Wim J. van Ooij .Corrosion protection of AA 2024-T3 by bis-[3-(triethoxysilyl)propyl]tetrasulfide in sodium chloride solution. Part 2: mechanism for corrosion protection[J].Corrosion Science,2003(10):2177-2197. |
[12] | 周宁琳.有机硅聚合物导论[M].北京:科学出版社,2000:169-172. |
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