以目前应用最广泛的刷镀镀层之一--镍-磷镀层为对象,利用自制多功能刷镀电源、原子力显微镜等设备,测得了刷镀时间与刷镀电流之间的关系,通过数据处理求得了二者之间的函数关系,在此基础上进一步求得了电流密度(刷镀电流/刷镀面积)与刷镀时间之间的函数关系;利用原子力显微镜测得镀层界面处、接近界面处和远离界面处的镀层颗粒形貌,结合刷镀电流密度与刷镀时间之间的关系,建立了刷镀镀层生长的模型.模型具有重要的指导意义:根据所建立的模型可以控制镀层颗粒的大小,改善镀层质量,为实际生产提供参考和指导.
The most widely used Ni-P coating by brush plating was researched. In the experiment, a self-made multi-purpose brush power, atomic force microscope( AFM ) and other equipment were used, the correlation of plating time and plating current was measured, and the function was also obtained. According to the function, the correlation of current density that plating current devide by plating area and plating time was obtained. The particle morphologies in coating interface, close to the interface and away from the interface were measured by the AFM. Combined with the rela-tionship between plating current density and plating time, the mechanism of coating growth model was established. The model is significance to control the coating structure. The purpose of the paper is providing reference for production ap-placation by the model to control plating layer quality.
参考文献
[1] | 罗建东,阮锋.一种较为经济的快速电刷镀工艺[J].腐蚀与防护,2007(05):266-268,252. |
[2] | 罗建东 .大型成形模具电刷镀强化方法及其机理研究[D].广州:华南理工大学,2007. |
[3] | 张允诚;胡如南.电镀手册[M].北京:国防工业出版社,2004:576-577. |
[4] | 傅建,储凯,李东.塑料成型模具Ni-P合金化学镀表面强化[J].机械工程材料,2002(09):17-19,24. |
[5] | Ratzker .Electro-deposition and corrosion performance of nickel-phosphorous amorphous alloys[J].Plating and Surface Finishing,1986,26(09):74-75. |
[6] | Parker L.Electroless nickel:state of the art[J].Plating and Surface Finishing,1992(03):29-31. |
[7] | 罗建东,阮锋,闫军威.电源波形对电刷镀的影响[J].电镀与环保,2006(01):28-29. |
[8] | 罗建东,阮锋.Ni-P电刷镀在拉深不锈钢材料模具上的应用[J].华南理工大学学报(自然科学版),2007(12):17-22. |
[9] | 黄子勋;吴纯素.电镀理论[M].北京:中国农业机械出版社,1981:14-31. |
[10] | 王鸿建.电镀工艺学[M].哈尔滨:哈尔滨工业大学出版社,1995:9-10. |
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