综述了难熔金属的概况,包括资源现状、特性及应用.重点阐述了难熔金属氧化物直接制备难熔金属的新工艺研究,主要介绍了5种工艺方法:传统熔盐电解法、新熔盐电解法、金属热还原法、气体还原法和熔盐电沉积法.同时,对它们的研究现状,优、缺点以及相互之间的区别进行分析,并展望了难熔金属的发展趋势和应用前景.
参考文献
| [1] | 刘建民,鲁雄刚,李谦,陈朝轶,程红伟,吕小旸,周国治.熔盐电解制备难熔金属的现状与展望[J].稀有金属快报,2006(09):1-6. |
| [2] | 郭青蔚.稀有高熔点金属的应用及展望[J].世界有色金属,1999(10):44-45. |
| [3] | 杨遇春.难熔金属二次资源的加工[J].有色金属再生与利用,2004(03):10-12. |
| [4] | 葛启录,周武平,韩欢庆,陈伟,褚征军.加入WTO后我国难熔金属工业发展浅析[J].粉末冶金工业,2003(01):40-45. |
| [5] | 邓炬.正在崛起的中国钛工业[J].稀有金属快报,2007(06):1-6. |
| [6] | 《有色金属提取冶金手册》编委会.有色金属提取冶金手册[M].北京:冶金工业出版社,2002:276-281. |
| [7] | 邓丽琴 .熔盐电脱氧法制备金属Nb及Nb-Ti合金[D].东北大学,2006. |
| [8] | 文友.钒的资源、应用、开发与展望[J].稀有金属与硬质合金,1996(43):51-54. |
| [9] | 陈朝轶 .金属氧化物直接制备难熔金属及合金的新工艺[D].上海大学,2008. |
| [10] | 崔静涛 .电化学还原法生产金属钛的阴极制备及反应研究[D].西安建筑科技大学,2008. |
| [11] | 聂新苗 .二氧化钛熔盐电解制取钛的实验及机理研究[D].重庆大学,2006. |
| [12] | Tu Hailing;Zhao Guoquan;Guo Qingwei.Metallurgy Material Regeneration and Environmental Protection of NonferrousMetals[M].Beijing:Chemical Indurstry Press,2003:43-58. |
| [13] | Chen G Z;Fray D J;Farthing T W .Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride[J].Nature,2000,407(21):361-363. |
| [14] | Yan XY;Fray DJ .Electrochemical studies on reduction of solid Nb2O5 in molten CaCl2-NaCl eutectic[J].Journal of the Electrochemical Society,2005(10):E308-E318. |
| [15] | Elena Gordo;George Z. Chen;Derek J. Fray .Toward optimisation of electrolytic reduction of solid chromium oxide to chromium powder in molten chloride salts[J].Electrochimica Acta,2004(13):2195-2208. |
| [16] | C. Schwandt;D. J. Fray .Determination of the kinetic pathway in the electrochemical reduction of titanium dioxide in molten calcium chloride[J].Electrochimica Acta,2005(1):66-76. |
| [17] | 刘美凤,郭占成,卢维昌.TiO2直接电解还原过程的研究[J].中国有色金属学报,2004(10):1752-1758. |
| [18] | 李颖君;王淑兰;钟和香 等.电化学还原TiO2反应机理及电极电势的研究[J].有色金属,2003,55(04):68-70. |
| [19] | Wang Shulan;Li Yingjun.Reaction Mechanism of Direct Electro-reduction of Titanium Dioxide in Molten Calcium Chloride[J].Journal of Electroanalytical Chemistry,2004(571):37-40. |
| [20] | Qian Xu;Li-Qin Deng;Yan Wu.A study of cathode improvement for electro-deoxidation of Nb2O5 in a eutectic CaCl2-NaCl melt at 1073K[J].Journal of Alloys and Compounds,2005(396):288-294. |
| [21] | 胡小锋;许茜;李海滨.电脱氧法制备金属钽的影响因素分析[J].中国稀土学报,2006(24):261-270. |
| [22] | 郭胜惠;彭金辉;张世敏 等.CaCl2体系电解还原TiO2制取钛的研究[J].稀有金属,2004,28(06):1092-1094. |
| [23] | 杜继红,奚正平,李晴宇,李争显,唐勇.电化学还原TiO2制备金属钛及反应过程的研究[J].稀有金属材料与工程,2006(07):1045-1049. |
| [24] | 扈玫珑;白晨光.钛金属制备方法的研究[J].科学导报,2005(05):418-421. |
| [25] | 邓丽琴,许茜,李兵,翟玉春,黄振奇.电脱氧法由Nb2O5直接制备金属铌[J].中国有色金属学报,2005(04):541-545. |
| [26] | 胡小锋,许茜.CaCl2-NaCl熔盐电脱氧法制备金属Ta[J].金属学报,2006(03):285-289. |
| [27] | 廖路强 .TiO<,2>原位还原制取钛过程的阴极制备及电解条件研究[D].东北大学,2003. |
| [28] | 胡小锋,许茜,李海滨,马青梅,任东琦.熔盐电脱氧法制备金属Ti的最新研究进展[J].材料导报,2006(08):101-103,106. |
| [29] | 郭春芳,董云会,于先进.熔盐电脱氧法研究进展[J].材料研究与应用,2007(03):178-181. |
| [30] | A. Krishnan;X. G. Lu;U. S. Pal .Solid Oxide Membrane Process for Magnesium Production Directly from Magnesium Oxide[J].Metallurgical and Materials Transactions, B. Process metallurgy and materials processing science,2005(4):463-473. |
| [31] | 弓丽霞,杜剑桥.电解法制取金属钛可望获得成功[J].稀有金属快报,2006(03):46-47. |
| [32] | 赵志国,鲁雄刚,丁伟中,周国治.利用固体透氧膜提取海绵钛的新技术[J].上海金属,2005(02):40-43. |
| [33] | Katsutoshi Ono;Ryosuke O. Suzuki .A New Concept for Producing Ti Sponge: Calciothermic Reduction[J].JOM,2002(2):59-61. |
| [34] | Toru H. Okabe;Takashi Oda;Yoshitaka Mitsuda .Titanium powder production by preform reduction process (PRP)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2004(1/2):156-163. |
| [35] | 鲁雄刚,周国治,丁伟中,蒋国昌,徐匡迪.带电粒子流控制技术在冶金过程中的应用及前景[J].钢铁研究学报,2003(05):69-73. |
| [36] | Kraft E H .Summary of emerging titanium cost reduction technologies[R].Report by EHK technologies.Vancouver,WA,2004. |
| [37] | 段淑贞;乔芝郁.熔盐化学原理和应用[M].北京:冶金工业出版社,1990:202. |
| [38] | Stubergh J R;Liu Zhonghua.Preparation of pure silicon by electrowinning in a bytownite melt[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1996(27B):178-182. |
| [39] | Suzuki R.O.;Ishikawa M. .MoSi_2 coating on molybdenum using molten salt[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):285-291. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%