铝化物涂层在高温氧化过程中主要以两种方式退化,一是涂层的表面氧化退化,二是涂层的内扩散退化。DZ40M钴基高温合金铝化物涂层经900℃和1000℃两个温度下的高温氧化后的组织结构变化表明,该涂层在900℃时以氧化引起的退化为主,而在1000℃时则以内扩散引起的退化为主。通过理论分析可知,涂层以何种退化方式为主,既取决于氧化温度,也取决于涂层本身的组成和结构。
The structure change was observed and analyzed for the aluminidecoating on a representative Co-base superalloy DZ40M during high-temperatureo xidation in air. It is discovered that, this coating, which is prepared by low-p ressure chemical vapor deposition (LP-CVD), degrades mainly by oxidation on the surface of the coating at 900℃, but mainly by inner-diffusion of Al inward to the substrate at 1000℃.
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