介绍了一种新的制备聚合物/无机层状化合物纳米复合材料的方法，即用多钒酸作引发剂，在制备五氧化二钒干凝胶的同时，将聚乙二醇嵌入到五氧化二钒的层状结构中去，该方法简单实用，而且可以通过控制聚乙二醇的量来控制纳米复合材料的层间距，为更好地了解和控制纳米复合材料的界面结构提供了一条新思路。实验表明，PEG/VXG纳米复合材料保持了VXG的层状结构，同时增加了三维方向的有序性，且随着PEG含量的增大，层间距增大。
A new method for preparation of PEG/VXG nanocomposite wasintroduced. U sing decavanadic acid as initiator, PEG was intercalating into the layers of V 2O5 while VXG was forming. The layered distance can be controlled by the cont ent of PEG. This is a new idea for studing the interface of nanocomposite. The experiment shows that PEG/VXG nanocomposite keeps the layer structure of VXG and increases the layered distance but decreases the ordered zone.
参考文献
| [1] | LiuYu-Ju et al.IntercalationofWater-solublepolymersinV2O5xerogel[J].Advanced Materials,1993,5(05):369-372. |
| [2] | KanatzidisMG et al.[J].Journal of the American Chemical Society,1987,109:3797-3799. |
| [3] | LiuYJ;DeGroot D C;Schindler J L.[J].Journal of the Chemical Society,Chemical Communications,1993:593-596. |
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