采用传统的干压成型法制备了Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3无铅压电陶瓷,研究了不同K0.5Bi0.5TiO3含量对Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3陶瓷的微观结构与电性能的影响规律.结果表明,Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3无铅压电陶瓷随K0.5Bi0.5TiO3含量增加,晶格常数增大,密度减小,晶粒尺寸减小,压电常数先增大后减小,介电常数增大,介电损耗增加,机械品质因数下降,而居里温度不断升高,在200℃附近存在由铁电相向反铁电相转变的一个相变点,组分为0.84 Na0.5Bi0.5TiO3-0.16 K0.5Bi0.5TiO3的陶瓷位于准同型相界附近,具有最佳的压电性能.
参考文献
[1] | Hui-dong Li;Chu-de Feng;Wen-long Yao .Some effects of different additives on dielectric and piezoelectric properties of (Bi_(1/2)Na_(1/2))TiO_3-BaTiO_3 morphotropic-phase-boundary composition[J].Materials Letters,2004(7/8):1194-1198. |
[2] | ALESSANDRA SANSON;ROGER W WHATMORE .Properties of Bi4Ti3O12 (Na1/2 Bi1/2) TiO3 piezoelectric ceramics[J].Japanese Journal of Applied Physics,2002,41:7127-7130. |
[3] | Jing XZ.;Li YX.;Yin QG. .Hydrothermal synthesis of Na0.5Bi0.5TiO3 fine powders[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2003(1/3):506-510. |
[4] | Yueming Li;Wen Chen;Jing Zhou .Dielectric and ferroelectric properties of lead-free Na_(0.5)Bi_(0.5)TiO_3-K_(0.5)Bi_(0.5)TiO_3 ferroelectric ceramics[J].Ceramics International,2005(1):139-142. |
[5] | TAKANAKA T;MARUYAMA K I;SAKATA K .Na1/2Bi1/2 TiO3 BaTiO3 system for lead-free piezoelectric ceramics[J].Japanese Journal of Applied Physics,1991,224:2236-2239. |
[6] | SUCHANICZ J;MERCURIO I P;MARCHET P et al.Axial pressure influence on dielectric and ferroelectric properties of Na0.5Bi0.5TiO3 ceramics[J].Physica Status Solidi,2001,225:459-466. |
[7] | SUVHANICZ J .Investigations of the phase transitions in Na0.5Bi0.5TiO3[J].Ferroelectrics,1995,172:455-458. |
[8] | 赁敦敏,肖定全,朱建国,余萍,鄢洪建.从发明专利看无铅压电陶瓷的研究与发展--无铅压电陶瓷2O年发明专利分析之一[J].功能材料,2003(03):250-253. |
[9] | SASAKI A;CHIBA T;MAMIYA Y et al.Dielectric and piezoelectric properties of Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3 system[J].Japanese Journal of Applied Physics,1999,38:5564-5567. |
[10] | WANG T B;WANG L E;LU Y K et al.Electro-physical properties of ceramics of Na0.5Bi0.5TiO3-K0.5Bi0.5TiO3 system in Na-rich region[J].Journal of the Chinese Ceramic Society,1986,14(01):14-22. |
[11] | ELKECHAI O;MANIER M;PMERCURIO J .Na0.5Bi0.5TiO3 K0.5Bi0.5TiO3 (NBT-KBT) system:a structure and electrical study[J].Physica Status Solidi,1996,157(a):499-506. |
[12] | Dielectric relaxor properties of K_(0.5)Bi_(0.5)TiO_(3) ferroelectrics prepared by sol-gel method[J].Journal of Applied Physics,2003(4):2548-2552. |
[13] | Juhyun Yoo;Dongon Oh;Yeongho Jeong .Dielectric and piezoelectric characteristics of lead-free Bi_(0.5)(Na_(0.84)Ko_(0.16))_(o.5)TiO_3 ceramics substituted with Sr[J].Materials Letters,2004(29):3831-3835. |
[14] | WADA TAKAHIRO;FUKUI AKIKO;MATSUO YOSHIHIRO .Preparation of (K0.5 Bi0.5)TiO3 ceramics by polymerized complex method and their properties[J].Japanese Journal of Applied Physics,2002,41:7025-7028. |
[15] | 赁敦敏,肖定全,朱建国,余萍,鄢洪建.BNT基无铅压电陶瓷的研究与进展--无铅压电陶瓷20年发明专利分析之二[J].功能材料,2003(04):368-370,374. |
[16] | 曲远方.功能陶瓷材料[M].北京:化学工业出版社,2003 |
[17] | 许煜寰.铁电与压电材料[M].北京:科学出版社,1978 |
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