欢迎登录材料期刊网

材料期刊网

高级检索

以活性炭为还原剂,采用溶胶-凝胶法制备双钙钛矿结构巨磁电阻材料Sr_2FeMoO_6.经XRD物相分析证明,产品为四方晶系Sr_2FeMoO_6,空间群为I4/mmm,晶胞参数:a=0.558nm,c=0.7882nm.SEM形貌分析表明,粉体颗粒分散性较好,粒子基本为球形,尺寸在100nm以下.磁性能测试结果表明,样品的居里温度高于室温,1T磁场下室温饱和磁化强度为13.59A·m~2·kg~(-1).

With activated carbon for reducing agent, the sol-gel method was used to prepare the giant magnetoresistance materials Sr_2FeMoO_6, which was the double perovskite oxide. XRD pattern demonstrated that the as-synthesized sample was Sr_2FeMoO_6 with tetragonal crystal structure and I4/mmm space group, and unit cell parameter was a=0.558nm, c=0.7882nm. The SEM photograph showed that the primary particles were spherical in shape and the grain size was below 100nm. Magnetism testing results showed that the Curie temperature was above room temperature and the saturation magnetization of the sample was 13.59A·m~2·kg~(-1) under 1T at room temperature.

参考文献

[1] J.M. Daughton .GMR applications[J].Journal of Magnetism and Magnetic Materials,1999(2):334-342.
[2] 肖利霞,袁松柳,王永强,尹诗岩.(1-x)La2/3Ca1/3MnO3/xCr2O3复合材料的电输运性质和磁电阻效应[J].稀有金属材料与工程,2007(06):981-984.
[3] Bonaedy, T;Song, KM;Sung, KD;Hur, N;Sung, JH .Magnetoelectric and magnetodielectric properties of (1-x)Ba0.6Sr0.4TiO3-(x)La0.7Ca0.3MnO3 composites[J].Solid State Communications,2008(9/10):424-427.
[4] 陈志高,陈水源,黄志高,赖恒,都有为.La-(Ca-Ba-Sr)-Mn-O锰氧化物高低温输运特性[J].稀有金属材料与工程,2004(10):1023-1028.
[5] JIN S;TIEFEL T H;MCCORMACK M et al.Thousandfold change in resistivity in magnetoresistive La-Ca-Mn-O films[J].Science,1994,264:413-415.
[6] XIONG G C;LI Q;JU H L et al.Giant mangnetoresistance in epitaxial Nd_(0.17)Sr_(0.13)MnO_3-δ thin films[J].Applied Physics Letters,1995,66:1427-1429.
[7] ZENER C .Interaction between the d-shells in the transition metals:Ⅱ.Ferromagnetic compounds of manganese with perovskite structure[J].Physical Review,1951,82:403-405.
[8] KOBAYASHI K -I;KIMURA T;SAWADA H et al.Room-temperature magnetoresistance in an oxide material with an ordered double-perovskite structure[J].Nature,1998,395(15):677-680.
[9] C. L. Yuan;S. G. Wang;W. H. Song;T. Yu;J. M. Dai;S. L. Ye;Y. P. Sun .Enhanced intergrain tunneling magnetoresistance in double perovskite Sr_2FeMoO_6 polycrystals with nanometer-scale particles[J].Applied physics letters,1999(24):3853-3855.
[10] Zhang Q;Rao GH;Xiao YG;Dong HZ;Liu GY;Zhang Y;Liang JK .Crystal structure, magnetic and electrical-transport properties of rare-earth-doped Sr2FeMoO6[J].Physica, B. Condensed Matter,2006(1/2):233-238.
[11] G. Narsinga Rao;Saibal Roy;Chung-Yuan Mou .Effect of La doping on magnetotransport and magnetic properties of double perovskite Sr_2FeMoO_6 system[J].Journal of Magnetism and Magnetic Materials,2006(2):348-355.
[12] Aldica G;Plapdanu C;Badica P;Valsangiacom C;Stoica L .Synthesis by oxalic (citric) route and electrical and magnetic characterization of Sr2FeMoO6 perovskite[J].Journal of Magnetism and Magnetic Materials,2007(2):665-670.
[13] NIEBIEKIKWIAT D;CANEIRO A;SANCHEZ R D S .Oxygen-induced grain boundary effects on magnetotransport properties of Sr_2FeMoO_(6+δ)[J].Physical Review B,2001,64(18):18046.
[14] NIEBIEKIKWIAT D;CANEIRO A;SANCHEZ R D S et al.Enhancement of the low field magnetoresistance by grain boundary modification in Sr_2FeMoO_(6+δ)[J].Physical Review B:Condensed Matter,2002,320(1-4):107-110.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%