利用氩氧混合低能离子束对双酚A型聚碳酸酯(PC)透明材料进行表面改性,并用自制丙烯酸酯胶黏剂表征了改性前后的粘接性能.结果表明:改性后的PC与丙烯酸酯胶黏剂的压剪强度得到了明显的改善.经分析,粘接性能的改善是由于低能离子束表面改性后的PC表面润湿性能的改善、表面活性的提高、表面弱电层的剥蚀和表面微交联层的生成引起的.
Ar/oxygen ion beam generated in gridless ion beam source with low energy was employed for surface modification of polycarbonate (PC) aimed at improvement of its adhesion characteristics. The results showed that the adhesion characteristic between PC and acrylate adhesive was significantly improved after modification because of ion beam bombardment resulted in excellent hydrophilicity,increasing of the polarity,denuding of the weak boundary and engendering of crosslinked boundary.
参考文献
[1] | 郭锦棠,林芳茜,刘冰,赵美华.聚碳酸酯聚氨酯的结构及性能[J].化工学报,2006(07):1709-1714. |
[2] | 刘裕明,钱露茜,胡建芳,庄将光.低温等离子体对聚碳酸酯材料表面改性的时效研究[J].高分子材料科学与工程,1999(04):141-144. |
[3] | Sanchis MR;Blanes V;Blanes M;Garcia D;Balart R .Surface modification of low density polyethylene (LDPE) film by low pressure O-2 plasma treatment[J].European Polymer Journal,2006(7):1558-1568. |
[4] | Xu XD;Kwok RWM;Lau WM .Surface modification of polystyrene by low energy hydrogen ion beam[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):182-187. |
[5] | 封伟,吴洪才.离子注入技术改性聚合物薄膜的研究进展[J].真空科学与技术学报,2000(01):51-54,50. |
[6] | BERTRAND P;PUYDT Y DE;BEUKEN J-M et al.Modification of polymer (PET) surface reactivity by low energy ion bombardment[J].Nuclear Instruments and Methods in Physics Research B:Beam Interaction with Materials and Atoms,1987,19-20(02):887-890. |
[7] | 阿方萨斯;波丘斯V.黏接与胶黏剂技术导论[M].北京:化学工业出版社,2005:127-140. |
[8] | 田军;徐锦芳;薛群基 .聚合物表面的润湿性及其应用[J].中国塑料,1996,10(06):25-32. |
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