以过氧化苯甲酰(BPO)作引发剂,通过溶液接枝聚合法把苯乙烯/丙烯酸同时接枝到原硅酸钠改性的聚偏氟乙烯(PVDF)膜上,磺化后得到聚偏氟乙烯接枝苯乙烯/丙烯酸磺酸(PVDF-g-PS/ PASA)膜.FTIR分析表明:苯乙烯和丙烯酸接枝到PVDF膜上;环境的相对湿度在20%~80%范围内,对PVDF-g-PS/ PASA膜电导率的影响基本不变,并达到0.0198S·cm-1,40℃保水率达99%.将膜应用于CO传感器中,传感器电流响应信号与CO气体浓度具有较好的线性关系.
参考文献
[1] | 贾超,李雅莉,马丽景,杨明,陈霭璠.基于固态高聚物电解质一氧化碳传感器研究[J].北京化工大学学报(自然科学版),2005(04):80-83. |
[2] | H.S. Cho;G. Sakai;K. Shimanoe;N. Yamazoe .Preparation of BiMeVO_x (Me = Cu, Ti, Zr, Nb, Ta) compounds as solid electrolyte and behavior of their oxygen concentration cells[J].Sensors and Actuators, B. Chemical,2005(2):307-314. |
[3] | Opekar F.;Stulik K. .Electrochemical sensors with solid polymer electrolytes[J].Analytica chimica acta,1999(1/3):151-162. |
[4] | Anantaraman AV.;Gardner CL. .STUDIES ON ION-EXCHANGE MEMBRANES .1. EFFECT OF HUMIDITY ON THE CONDUCTIVITY OF NAFION(R)[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,1996(2):115-120. |
[5] | Nasef MM;Zubir NA;Ismail AF;Khayet M;Dahlan KZM;Saidi H;Rohani R;Ngah TIS;Sulaiman NA .PSSA pore-filled PVDF membranes by simultaneous electron beam irradiation: Preparation and transport characteristics of protons and methanol[J].Journal of Membrane Science,2006(1):96-108. |
[6] | Xinping Qiu;Wenqiong Li;Shicao Zhang .The Microstructure and Character of the PVDF-g-PSSA Membrane Prepared by Solution Grafting[J].Journal of the Electrochemical Society,2003(7):A917-A921. |
[7] | ZHANG Shi-cao;SHEN Juan;QIU Xin-ping et al.ESR and vibrational spectroscopy study on poly (vinylidene fluoride) membranes with alkaline treatment[J].Journal of Power Sources,2006,153:234-238. |
[8] | Hsueh CL.;Peng YJ.;Wang CC.;Chen CY. .Bipolar membrane prepared by grafting and plasma polymerization[J].Journal of Membrane Science,2003(1/2):1-13. |
[9] | JOKELA K .Temperature-dependent X-ray scattering studies on radiation grafted and sulfonated poly (vinylidene floride)[J].Materials Science Forum,2000,321:90-97. |
[10] | 刘平生,李利,周宁琳,魏少华,章峻,刘瑜之,沈健.蒙脱土/聚丙烯酸高吸水性树脂的合成[J].复合材料学报,2006(03):44-48. |
[11] | BREWIS D M;MATHIESON I;CAYLESS R A et al.Pretreatment of poly(vinylidene fluoride) with potassium hydroxide[J].International Journal of Adhesion,1996,16:87-95. |
[12] | Ross G.J.;Watts J.F. .Surface modification of poly(vinylidene fluoride) by alkaline treatment 1.The degradation mechanism[J].Polymer: The International Journal for the Science and Technology of Polymers,2000(5):1685-1696. |
[13] | 索进平,崔崑,钱晓良,肖建中.新型以无机物为主的免增湿复合质子交换膜[J].复合材料学报,2004(01):23-27. |
[14] | Klaus-Dieter Kreuer;Stephen J.Paddison;Eckhard Spohr;Michael Schuster .Transport in Proton Conductors for Fuel-Cell Applications:Simulations,Elementary Reactions,and Phenomenology[J].Chemical Reviews,2004(10):4637-4678. |
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