综述了高温硫化加成型硅橡胶的特点和技术进展,以及催化剂/抑制剂体系的研究动向及进展.着重介绍了近年来采用的新型催化剂/抑制剂体系,通过对铂催化剂进行改进制备微胶囊化铂催化剂和铂-抑制剂配合物等方法,使得催化剂活性得到很好地抑制,从而实现高温加成硫化.
参考文献
[1] | 冯圣玉;张洁;李美玉.有机硅高分子及其应用[M].北京:化学工业出版社,2004 |
[2] | 黄荣华;张先亮;张晓阳.有机硅树脂结构对加成型硅橡胶性能的影响[A].成都:中国氟硅有机材料工业协会有机硅专业委员会,2004:268-271. |
[3] | 杜作栋 .新型高模量硅橡胶的研制[J].合成橡胶工业,1989,12(01):25-28. |
[4] | 杨立明 .新型加成型硅橡胶的合成及某些性质[J].合成橡胶工业,1992,15(01):38-41. |
[5] | 黄文润.加成型硅橡胶的技术进展[A].成都:有机硅材料编辑部,2008:1-11. |
[6] | 易有彬;张静.高性能加成型液体硅橡胶的合成研究[A].成都:有机硅材料编辑部,2008:41-43. |
[7] | 黄文润.加成型硅橡胶基础聚合物的精制及基料配置[A].成都:有机硅材料编辑部,2008:29-37. |
[8] | 戴丽娜;赵云峰;张志杰.胶体二氧化硅增强的加成型硅橡胶[A].成都:有机硅材料编辑部,2008:38-40. |
[9] | FEHN ARMIN DR .Addition-crosslinkable adhesive silicone composition[P].日本专利:2007302893,2007-11-22. |
[10] | AKEDA TAKASHI;HARADA YOSHIFUMI .Addition-type silicone adhesive composition[P].日本专利:2007009189,2007-01-18. |
[11] | ARAKI TADASHI;MIYAO TAKESHI .Self-adhesive organopolysiloxane composition[P].日本专利:2007002088,2007-01-11. |
[12] | 谭必恩,赵华,潘慧铭.加成型硅橡胶铂催化剂的制备及其活性研究[J].中国胶粘剂,2001(04):1-4. |
[13] | 葛建芳,贾德民.加成型硅橡胶硫化过程中催化剂的活性抑制和防失效研究[J].绝缘材料,2004(03):36-38. |
[14] | KONINGS M S;OSMAN J D .Compositions containing inorganic,organic and organometallic palladium hydrogen scavengers[P].美国专利:5684060,1997-11-04. |
[15] | 赵萍,唐颂超,徐志君,王庆海,潘泳康.影响加成型有机硅隔离剂剥离力的因素[C].2004全国高分子材料科学与工程研讨会论文集,2004:359-362. |
[16] | WILLING DAVID .Catalysts for the reaction of Si-H with organic compounds containing aliphatic unsaturation[P].美国专利:3419593,1968-12-31. |
[17] | KARSTEDT B .Platinum-vinylsiloxanes[P].美国专利:3715334,1973-02-06. |
[18] | 冯圣玉;张洁 .加成型高温硫化硅橡胶抑制剂的研究[J].合成橡胶工业,1989,12(05):318-320. |
[19] | GUST J KOOKOOTSEDES .Acetylenic inhibited platinum catalyzed organopolysiloxane composition[P].美国专利:3445420,1969-05-20. |
[20] | MYRON T M .Novel organosiloxane inhibitors for hydrosilation reactions[P].美国专利:4785066,1988-11-15. |
[21] | PHILIP J M .Liquid injection,molding inhibitors for curable composition[P].美国专利:5506289,1996-04-09. |
[22] | 陈福田 .加成硫化硅橡胶的技术进展[J].合成橡胶工业,1983,6(03):232-235. |
[23] | LINDON J A;MALIN A .Heat curable polysiloxane composition[P].美国专利:4325975,1982-04-20. |
[24] | SCHUYLER B;SMITH .Heat activated curing system for organosilicon compounds[P].美国专利:3532649,1970-10-06. |
[25] | 幸松民;王一璐.有机硅合成工艺与产品应用[M].北京:化学工业出版社,2003 |
[26] | SARUYAMA;TOSHIO .Heat-curing organopolysiloxane composition[P].欧洲专利:0651008,1999-06-23. |
[27] | CATHERINE G .Silicone composition crisslinkable into dlastomet by hydrosilylation,in the presence of carbine based metal catalysts,and catalysis[P].美国专利:20040236054,2004-11-25. |
[28] | FEHN A;ACHENBACH F;DIETL S .Curable polysiloxane compositions[P].欧洲专利:0982370,2000-12-20. |
[29] | SUMPTER C A;LEWIS L N .One part heat curable organopolysilaxane compositions[P].欧洲专利:0490523,1996-07-24. |
[30] | MATSUSHITA TAKAO;FUCHIGAMI HIROSHI .Silicone rubber composition for pressure forming[P].日本专利:4055471,1992-12-26. |
[31] | FUJII KIMIHIRO .Self-adhesive sheet[P].日本专利:4057873,1992-02-25. |
[32] | FUJIOKA KAZUTOSHI;YOSHIDA TAKEO .Thermosetting silicone elastomer[P].日本专利:7070442,1995-03-14. |
[33] | 黄荣华;董亚巍;张先亮.单组分加成型硅橡胶[A].成都:有机硅材料编辑部,2008:18-22. |
[34] | SOEDA HARUO;TSUGITA MAKOTO .Movie camera having still picture photographing function and method of photographing still picture therewith[P].美国专利:5382974,1996-02-20. |
[35] | FEHN ARMIN DR;ACHENBACH FRANK DR .Curable organopolysiloxane composition[P].欧洲专利:0994159,2001-04-04. |
[36] | FEHN ARMIN;ACHENBACH FRANK;DIETL STEFAN .Curable organopolysiloxane compositions[P].德国专利:19837855,2000-02-24. |
[37] | RANDOLPH G N;MIDLAND;MICH .Crosslinker-platinum catalyst-inhabitors and method of preparation thereof[P].美国专利:3989666,1976-11-02. |
[38] | LARRY N L;JUDITH STEIN .The chemistry of fumarate and maleate inhibitors with platinum hydrosilylation catalysis[J].Journal of Organomtallic Chemistry,1996,521:221-227. |
[39] | EDWARD J B .Sterically hindered reagents for use in single component siloxane cure system[P].美国专利:20050272881,2005-12-08. |
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