以纳米铝粉、纳米氧化铅和纳米三氧化二铋为原料,利用超声分散复合法制备了超级铝热剂Al/PbO和Al/Bi2O3.采用X射线粉末衍射(XRD)、扫描电镜及能谱分析(SEM-EDS)和红外光谱(FT-IR)对原料和产物的物相、组成、形貌和结构进行分析表征；利用真空安定性实验仪(VST)和差示扫描量热仪(DSC)研究了两种超级铝热剂与硝化棉(NC)、吸收药(NC+NG)、黑索今(RDX)、吉纳(DINA)和二号中定剂(C2)五种双基系推进剂主要组分的混合体系的相容性.结果表明,VST法和DSC法实验一致判断纳米超级铝热剂与双基系推进剂主要组分NC,NC+NG和DINA有较好的相容性；而Al/PbO和Al/Bi2O3分别与RDX和Q组成的混合物体系则有不同的分析结果,VST法判断为相容,而DSC法却认为体系敏感,分析了不同方法得出不同结论的原因.
参考文献
| [1] | 刘子如.含能材料热分析[M].北京:国防工业出版社,2008 |
| [2] | 安亭,赵凤起,张平飞.纳米含能材料制备研究的最新进展[J].纳米科技,2009(06):60-67. |
| [3] | 安亭,赵凤起,肖立柏.高反应活性纳米含能材料的研究进展[J].火炸药学报,2010(03):55-62,67. |
| [4] | PAMELA J;KASTE B .Novel energetic materials for the future force:the army pursues the next generation of Propellants and explosives[J].The Amptiac Newsletter,2004,8(04):85-89. |
| [5] | PUSZYNSKI J A.Challenges in processing of nanoenergetic materials[A].Georgia:NATAS,2008:45/1-45/14. |
| [6] | Edward L. Dreizin .Metal-based Reactive Nanomaterials[J].Progress in energy and combustion science,2009(2):141-167. |
| [7] | WALKER J D .Exploring the synthesis and characterization of nanoenergetic materials from sol-gel chemistry[D].USA:Georgia Institute of Technology,2007. |
| [8] | 王毅 .纳米及纳米复合材料在铝热剂中的应用研究[D].南京理工大学,2008. |
| [9] | VALLIAPPAN S;SWIATKIEWICZ J;PUSZYNSKI J A .Reactivity of aluminum nanopowders with metal oxides[J].Powder Technology,2005,156(2-3):164-169. |
| [10] | Tillotson TM.;Simpson RL.;Hrubesh LW.;Satcher JH.;Poco JF.;Gash AE. .Nanostructured energetic materials using sol-gel methodologies[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2001(1/3):338-345. |
| [11] | Jan A. Puszynski;Christopher J. Bulian;Jacek J. Swiatkiewicz .Processing and Ignition Characteristics of Aluminum-Bismuth Trioxide Nanothermite System[J].Journal of Propulsion & Power,2007(4):698-706. |
| [12] | John J. Granier;Michelle L. Pantoya .Laser ignition of nanocomposite thermites[J].Combustion and Flame,2004(4):373-383. |
| [13] | GANGOPADHYAY S;SHENDE R;SUBRAMANIAN S et al.Ordered nanoenergetic thermites as self-assembled nanostructures with tunable combustion properties[P].USA Patent:2007095445 A1,2007-05-03. |
| [14] | Anand Prakash;Alon V. McCormick;Michael R. Zachariah .Synthesis and Reactivity of a Super-Reactive Metastable Intermolecular Composite Formulation of Al/KMnO_4[J].Advanced Materials,2005(7):900-903. |
| [15] | Michelle L.Pantoya;John J.Granier .Combustion Behavior of Highly Energetic Thermites:Nano versus Micron Composites[J].Propellants, Explosives, Pyrotechnics,2005(1):53-62. |
| [16] | 周超,李国平,罗运军.溶胶-凝胶法制备Fe2O3/Al纳米复合材料[J].火炸药学报,2010(03):1-4. |
| [17] | GJB 73713-1994.Compatibility test pressure transducer method[S]. |
| [18] | 岳璞,衡淑云,韩芳,张腊莹,何少蓉.三种方法研究ADN与几种粘合剂的相容性[J].含能材料,2008(01):66-69. |
| [19] | GJB 772A-1997.502.1.Stability and compatibility DTA and DSC[S]. |
| [20] | 严启龙,李笑江,廖林泉,张晓宏,刘子如.四硝基并哌嗪（TNAD）与推进剂组分相容性的DSC法评估[J].含能材料,2008(03):309-314. |
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