研究磷酸表面处理和复合SiO2涂层对Ti-6Al-4V合金600℃下空气中抗氧化性能的影响.结果表明:600℃氧化24h后,磷酸表面处理使Ti-6Al-4V合金平均氧化速率下降了近75％,复合非晶SiO2涂层样品600℃等温氧化100h后,平均氧化速率比空白样品降低一个数量级,抗氧化性能与单独的磷酸处理比较进一步提高.磷酸表面处理和复合SiO2涂层样品的氧化膜致密性增强且与基体的黏附性良好,二者氧化膜中TiO2的体积分数均低于空白样品.磷酸表面处理形成的TiP2O7层与SiO2涂层共同抑制了O的内扩散和Ti的外扩散.
参考文献
| [1] | 陈玉勇,杨非,孔凡涛,肖树龙.V/Nb对Ti-45Al-9（V,Nb,Y）合金抗氧化性能的影响[J].稀有金属材料与工程,2011(03):429-432. |
| [2] | Xiong YM;Zhu SL;Wang FH .The oxidation behavior and mechanical performance of Ti60 alloy with enamel coating[J].Surface & Coatings Technology,2005(2/3):195-199. |
| [3] | ZHANG Z X;DONG H;BELL T et al.The effect of gold predeposition on the oxidation behavior of CPTi and Ti6Al4V alloy[J].Oxidation of Metals,2006,66(1-2):91-106. |
| [4] | Vickridge IC.;Gilberd PW.;Morrison Y.;Johnson PB. .High dose He implantation in two Ti alloys: Effects on structure and thermal oxidation[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,1998(0):1068-1073. |
| [5] | 王振霞,王文波,贺志勇,赵晋香,徐重.钛（TA2）及钛合金（TC4）表面等离子渗Nb研究[J].热加工工艺,2005(09):1-2,28. |
| [6] | 李佳,夏长清,古一,吴安如,武文花.真空热处理对Ti6Al4V基体/NiCrAlY涂层体系组织结构及元素扩散行为的影响[J].中国有色金属学报,2004(11):1889-1894. |
| [7] | 潘晓龙;李争显;黄春良 等.钛合金表面熔结AlSiCrTi涂层的高温性能[J].热加工工艺,2007,36(24):68-73. |
| [8] | 梁城,高万振,潘邻,陶锡麒,夏春怀,宋燕.钛合金表面激光熔覆Ni基梯度涂层的研究[J].材料保护,2006(11):32-34. |
| [9] | Yu CZ;Zhu SL;Wei DZ;Wang FH .Amorphous sol-gel SiO2 film for protection of Ti6Al4V alloy against high temperature oxidation[J].Surface & Coatings Technology,2007(12):5967-5972. |
| [10] | M. Zhu;M. Li;Y. Li .Influence of sol-gel derived Al_2O_3 film on the oxidation behavior of a Ti_3Al based alloy[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1/2):177-183. |
| [11] | HAUGSRUD R .On the influence of sol-gel derived CeO2 coatings on high-temperature oxidation of Co,Ni and Cu[J].Corrosion Science,2002,44(07):1569-1583. |
| [12] | KLEININ L C.Sol-gel Technology for Thin Films,Fibers,Preforms,Electronics and Speciality Shapes[M].New York:Noyes Publications,1986:17. |
| [13] | S.Y. Brou;R. Siab;G. Bonnet .On dipping of gamma-TiAl in low-concentration phosphoric acid solution and consecutive oxidation resistance at 800 deg C[J].Scripta materialia,2007(6):517-520. |
| [14] | Andersen AMK.;Hanson JC.;Vogt T.;Norby P. .Preparation and characterization of a new 3-dimensional zirconium hydrogen phosphate, tau-Zr(HPO4)(2). Determination of the complete crystal structure combining synchrotron x-ray single-crystal diffraction and neutron powder diffraction[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,1998(5):876-881. |
| [15] | DU H L;DATTA P K;LEWIS D B et al.Air oxidation behaviour of Ti6Al4V alloy between 650 and 850℃[J].Corrosion Science,1994,36(04):631-642. |
| [16] | 徐仰涛,夏天东,闫健强,赵文军.合金元素对Co-Al-W合金高温氧化行为的影响[J].中国有色金属学报,2010(11):2168-2177. |
| [17] | Brou SY;Bonnet G;Grosseau-Poussard JL .Formation and evolution of phosphorus-containing species during high-temperature oxidation of TiAl dipped in a low-concentrated phosphoric acid solution[J].Surface & Coatings Technology,2009(9):1138-1143. |
| [18] | HAUGSRUD R;GUNNAES A E;SIMON C R .Effects of solgel-derived silica coatings on high-temperature oxidation of Ni[J].Oxidation of Metals,2001,56(5-6):453-465. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%