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电化学阻抗谱(EIS)是研究染料敏化太阳能电池内部电子和离子输运过程的重要技术之一,测试了不同的聚乙二醇4000 (PEG)添加量、不同静置时间和不同光照强度的DSSCs的EIS,利用等效电路对阻抗谱的各个部分进行拟合,讨论了TiO2/电解质界面的复合反应速率常数、电子寿命、扩散系数、电子传递电阻和电子在薄膜中的传输电阻等参数,探讨了实验条件对电池电极的界面特性的影响.

参考文献

[1] O'Regan B;Gr(a)tzel M .A low cost high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J].Nature,1991,353:737-740.
[2] R. Kern;R. Sastrawan;J. Ferber;R. Stangl;J. Luther .Modeling and interpretation of electrical impedance spectra of dye solar cells operated under open-circuit conditions[J].Electrochimica Acta,2002(26):4213-4225.
[3] Christophe J.Barbe;Francine Arendse;Pascal COmte .Nanocrystalline titanium oxide electrodes for photovoltaic applications[J].Journal of the American Ceramic Society,1997(12):3157-3171.
[4] Aswani Yella;Hsuan-Wei Lee;Hoi Nok Tsao;Chenyi Yi;Aravind Kumar Chandiran;Khaja Nazeeruddin;Eric Wei-Guang Diau;Chen-Yu Yeh;Shaik M Zakeeruddin;Michael Gratzel .Porphyrin-Sensitized Solar Cells with Cobalt (Ⅱ/Ⅲ)-Based Redox Electrolyte Exceed 12 Percent Efficiency[J].Science,2011(Nov.4 TN.6056):629-634.
[5] Wang Q;Moser J E;Gr(a)tzel M .Electrochemical Imped ance spectroscopic analysis of dye-sensitized solar cells[J].Journal of Physical Chemistry B,2005,109:14945-14953.
[6] Adachi M;Sakamoto M;Jiu JT;Ogata Y;Isoda S .Determination of parameters of electron transport in dye-sensitized solar cells using electrochemical impedance spectroscopy[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(28):13872-13880.
[7] 陶勇,廖志君,伍登学,王自磊,李健,戴建洪,刘成士.染料敏化太阳能电池阻挡层的制备及其性能研究[J].功能材料,2011(07):1177-1179.
[8] Anneke Hauch;Andreas Georg .Diffusion in the electrolyte and charge-transfer reaction at the platinum electrode in dye-sensitized solar cells[J].Electrochimica Acta,2001(22):3457-3466.
[9] Schwarzburg K;Willig F .Diffusion impedance and space charge capacitance in the nanoporous dye-sensitized electrochemical solar cell[J].Journal of Physical Chemistry B,2003,107:3552-3555.
[10] Bisquert J .Theory of the impedance of electron diffusion and recombination in a thin layer[J].Journal of Physical Chemistry B,2002,106:325-333.
[11] Bisquert J;Cahen D;Hodes C et al.Physical chemical principles of photovoltaic conversion with nanopartieulate,mesoporous dye sensitized solar cells[J].Journal of Physical Chemistry B,2004,108:8106-8118.
[12] Juan Bisquert .Theory of the impedance of charge transfer via surface statesin dye-sensitized solar cells[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2010(1/2):43-51.
[13] Bisquert J. .Chemical capacitance of nanostructured semiconductors: its origin and significance for nanocomposite solar cells[J].Physical chemistry chemical physics: PCCP,2003(24):5360-5364.
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