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利用增重法研究了新型Cr19Ni28Ti合金在700、800和900℃空气中的高温氧化行为,绘制了高温氧化动力学增重曲线,并利用XRD、SEM和EDS对氧化膜进行了表征.结果表明,700、800和900℃氧化增重分别为0.07、0.1和0.45mg/cm2,具有良好的抗氧化性;高温氧化动力学曲线符合抛物线规律.700℃氧化100h的氧化膜主要由Mn1.5Cr1.5O4、Fe(Ni)Cr2O4和Cr2O3组成;800℃氧化后增加了产物Fe2.95Si0.05 O4;900℃氧化Ti已经开始向金属表面扩散,并与氧发生反应,生成了TiO2.

参考文献

[1] 王起江,洪杰.超超临界电站锅炉用新型管材的研制[J].宝钢技术,2008(05):44-48,53.
[2] 安小勇.超超临界锅炉高温材料的选择和应用[J].科技创新导报,2010(30):99-100.
[3] 王顶磊.660MW超临界锅炉高温受热面氧化皮产生原因及应对策略[J].科技信息,2012(15):403-404.
[4] Sundararajan T;Kuroda S;Kawakita J;Seal S .High temperature corrosion of nanoceria coated 9Cr-1Mo ferritic steel in air and steam[J].Surface & Coatings Technology,2006(6):2124-2130.
[5] 程晓农,王荣荣,李冬升,戴起勋,黄燕,刘瑜,陶亚平.800H合金的高温抗氧化性能[J].材料热处理学报,2012(06):95-99.
[6] 李冬升,戴起勋,王国建,李丹,邵新中,王荣荣.Super304H奥氏体不锈钢的抗高温氧化性能[J].江苏大学学报(自然科学版),2012(05):581-585.
[7] 戴炎彬,游碧龙,刘少光,苏茂,赵合勇,徐玉松.循环流化床锅炉风帽合金的组织及抗高温氧化性能研究[J].功能材料,2012(08):1068-1071,1075.
[8] Kuang Wenjun;Wu Xinqiang .The oxidation behavior of 304 stainless steel in oxygenated high temperature water[J].Corrosion Science,2010,52(12):4081-4087.
[9] M.Siddique,N.Hussain,M.Shafi.Identification of Iron Oxides Qualitatively/Quantitatively Formed during the High Temperature Oxidation of Superalloys in Air and Steam Environments[J].材料科学技术学报(英文版),2009(04):479-482.
[10] 赵越,杨功显,袁超,郭建亭,刘常升.铸造镍基高温合金K447的高温氧化行为[J].腐蚀科学与防护技术,2007(01):1-4.
[11] Wang Haitao,Wang Yuqing,Yu Huashun,Min Guanghui,Wang Zhifu.Effects of composite scale on high temperature oxidation resistance of Fe-Cr-Ni heat resistant alloy[J].中国铸造,2009(02):109-114.
[12] 梁英教;车荫昌.无机物热力学数据手册[M].沈阳:东北大学出版社,1993:8.
[13] 柏跃磊,赫晓东,朱春城.Fe-Ni-Al合金在900℃时的氧化行为研究[J].哈尔滨工业大学学报,2008(01):65-68.
[14] Alvarez M G;Olmedo A M;Villegas M .Corrosion behaviour of Alloy 800 in high temperature aqueous solutions long term autoclave studies[J].Journal of Nuclear Materials,1996,229(01):93-101.
[15] Cobo S J;Palmiere E J;Rainforth W M .Mechanism of oxidation of austcnitic stainless steels under conditions of hot rolling in steckel mills[J].Chemistry and Materials Science,2008,39(10):2477-2485.
[16] Ishitsuka T;Inoue Y;Ogawa H .Effect of silicon on the steam oxidation resistance of a 9 %Cr heat resistant steel[J].Oxidation of Metals,2004,61(1/2):125-142.
[17] Microstructure and analysis of oxide scales formed on Cr-Si-Ni compacts in air and H_2O-containing atmosphere[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2010(6):p.2098.
[18] 王新建,朱雪梅,张彦生,吴志立,张瓦利.Fe-Mn-Al与Fe-Mn奥氏体合金的高温氧化性能与组织结构[J].大连铁道学院学报,2004(01):69-73.
[19] 朱雪梅,王新建,刘明,张彦生.Fe-30Mn-9Al奥氏体钢高温循环氧化特征[J].腐蚀科学与防护技术,2005(01):31-33,38.
[20] S.H. Nie;Y. Chen;X. Ren;K. Sridharan;T.R. Allen .Corrosion of alumina-forming austenitic steel Fe–20Ni–14Cr–3Al–0.6Nb–0.1Ti in supercritical water[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2010(2/3):231-235.
[21] L. Tan;T.R. Allen;Y. Yang .Corrosion behavior of alloy 800H (Fe-21Cr-32Ni) in supercritical water[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2011(2):703-711.
[22] KimDJ;HuangX;SeoDY et al.Cyclic oxidation and interdiffusion behavior of a NiCrAlY coated powder metallurgy beta gamma TiAl-2Nb-2Mo Alloy[J].Chemistry and Materials Science,2012,78(1-2):31-50.
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