为提高锂离子电池聚烯烃多孔膜的亲电液性,增加其离子导电性能,采用辐射聚合甲氧基聚氧化乙烯丙烯酸酯对聚烯烃隔膜进行表面改性.改性后的隔膜对高极性电解液具有良好的湿润性.由于对电解液更高的吸附作用,通过吸附更多的液态电解液,使膜更易传导锂离子.改性膜作为隔膜制备的碳/正极材料锂离子电池不仅具有优良的容量保持性,也具有良好的倍率放电性能.
参考文献
[1] | Aihara Y;Kodama M;Nakahara K .Electrochemical characteristics of a carbon electrode with gel polymer electrolyte for lithium-ion polymer batteries[J].Journal of Power Sources,1997,65:143-148. |
[2] | Kennedy B;Patterson D;Camilleri S .Use of lithium-ion batteries in electric vehicles[J].Journal of Power Sources,2000,90:156-162. |
[3] | Izuchi S;Ochiai S;Takeuchi K .Solid polymer electrolytes for lithium cells[J].Journal of Power Sources,1997,68(01):37-42. |
[4] | 吴大勇,刘昌炎.锂离子电池隔膜研究进展[J].新材料产业,2006(09):48-53. |
[5] | 伊廷锋,胡信国,高昆.锂离子电池隔膜的研究和发展现状[J].电池,2005(06):468-470. |
[6] | 周建军,李林.锂离子电池隔膜的国产化现状与发展趋势[J].新材料产业,2008(04):33-36. |
[7] | Lee S W;Choi S W;Jo S M.Electrochemical properties and cycle performance of electrospun poly (vinylidane fluoride)-based fibrous membrane electrolytes for Li-ion polymer battery[J].Journal of Power Sources,2006(163):41-46. |
[8] | Matoba Y;Matsui S;Tabuchi M et al.Electrochemical properties of composite polymer electrolyte applied to rechargeable lithium polymer battery[J].Journal of Power Sources,2009,137(02):284-287. |
[9] | Ananthalyengar G;Pill L K;Manian M K et al.Poly (vinylidene fluoride)-polydiphenylamine composite electrospun membrane as high-performance polymer electrolyte for lithium batteries[J].Journal of Membrane Science,2008,318:422-428. |
[10] | Tao R;Miyamoto D;Aoki T et al.Novel liquid lithium borates characterized with high lithium ion transference numbers[J].Journal of Power Sources,2004,135(1-2):267-272. |
[11] | Singhal R G;Capracotta M D;Martin J D et al.Transport properties of hectorite based nanocomposite single ion conductors[J].Journal of Power Sources,2008,141(02):247-255. |
[12] | 孙小青,孙卫东,王华,高毅.微孔滤膜在锂离子电池隔膜中的应用[J].塑料,2003(02):39-43. |
[13] | Yang MJ;Li WL;Wang GG;Zhang JQ .Preparation and characterization of a novel microporous PE membrane supporting composite gel polymer electrolyte[J].Solid state ionics,2005(37/38):2829-2834. |
[14] | Wang Y.;Travas-Sejdic J.;Steiner R. .Polymer gel electrolyte supported with microporous polyolefin membranes for lithium ion polymer battery[J].Solid state ionics,2002(3/4):443-449. |
[15] | Min Kim;Jong Hyeok Park .Inorganic thin layer coated porous separator with high thermal stability for safety reinforced Li-ion battery[J].Journal of Power Sources,2012(Aug.15):22-27. |
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