欢迎登录材料期刊网

材料期刊网

高级检索

在硅酸盐电解液中添加复合添加剂硝酸镧(La(NO3)3)和纳米氧化锌(纳米ZnO)对铸造铝合金进行微弧氧化实验。通过涡流测厚仪、扫描电镜、显微硬度计、X射线衍射仪等分析复合添加对膜层的厚度、硬度、腐蚀性能的影响。结果表明,复合添加剂La(NO3)3+纳米ZnO的加入可提高膜层的耐蚀性,增加膜层的厚度和硬度。当La(NO3)3含量为0.5g/L,纳米 ZnO 含量为3g/L时,获得的膜层厚度和硬度较大。

Ceramic coatings were fabricated on ZL205A aluminum alloy during micro-arc oxidation by mixing La (NO3 )3 and nano-ZnO into the metasilicate electrolyte.The effects of compound additive of La (NO3 )3 and nano-ZnO in electrolyte on thickness,hardness,corrosion resistance and microstructure of the ceramic coatings were analyzed.The results show that nano-ZnO was deposited on the surface layer of the ceramic coatings in micro-arc oxidation reaction process.The corrosion resistance of the coatings was thus improved.Both the thickness and hardness of the ceramic coatings increased a lot.The optimal addition amount of La(NO3 )3 and nano-ZnO in the electrolyte was 0.5 and 3g/L.

参考文献

[1] 郭平义,王晓瑶,邵勇.1050纯铝微弧氧化陶瓷层的生长动力学与腐蚀性能研究[J].腐蚀科学与防护技术,2011(06):490-494.
[2] 钟涛生,李小红,蒋百灵.6061铝合金微弧氧化陶瓷层生长速度[J].应用化学,2009(06):692-696.
[3] 李玉海;赵艳;李宝毅 等.不同电解液对2A12铝合金微弧氧化膜耐磨性能的影响[J].功能材料,2011,42(02):354-357.
[4] Gnedenkov SV.;Gordienko PS.;Khrisanfova OA.;Scorobogatova TM. Sinebrukhov SL. .Formation of BaTiO3 coatings on titanium by microarc oxidation method[J].Journal of Materials Science,2002(11):2263-2265.
[5] 蒋百灵,张淑芬.氧化镁陶瓷层的组织结构及耐蚀性能[J].西安理工大学学报,2000(04):327-329.
[6] Timoshenko A V;Opara B K .Formation of protective wear resistant oxide coatings on aluminum alloys by the microplasma methods from aqueous electrolyte solutions[J].Proc International Corrosion Congress,1993,12(01):280-293.
[7] Krishniyer A;Ramasubramanian M;Popov B N et al.Electro deposition & characterizations zinc-nickel-phos-phorus alloys[J].Plating &Surface Finishing,1999,86(01):99-103.
[8] Xue WB.;Lai YC.;Chen RY.;Deng ZW. .Analysis of phase distribution for ceramic coatings formed by microarc oxidation on aluminum alloy[J].Journal of the American Ceramic Society,1998(5):1365-1368.
[9] Krysmann W;Kurze P;Dittrich K H .Process characteris-tics and parameters of anodic oxidation by spark discharge (ANOF)[J].Crys Res & Tech,1984,19(07):973-978.
[10] 国春艳,刘向东,张雅萍,车广东,王颖辉,王欢.电解液中Ce(NO_3)_3含量对ZAlSi12合金微弧氧化层特性的影响[J].材料热处理学报,2010(03):132-135,141.
[11] 杨巍,蒋百灵,鲜林云,时惠英.溶质离子在铝合金微弧氧化陶瓷膜形成过程中的作用机理[J].中国有色金属学报,2009(03):464-468.
[12] 索相波,马世宁,邱骥,吕庆星.纳米SiO_2复合处理对7A52铝合金微弧氧化陶瓷层孔隙率及性能的影响[J].航空材料学报,2009(06):66-69.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%