采用双极脉冲磁控溅射法制备氮掺杂碳膜并作为对电极应用在染料敏化太阳能电池(DSSC)中。研究了氮掺杂对碳膜的结构与性能的影响。用 X 射线光电子能谱(XPS)对氮掺杂碳膜进行薄膜表面元素分析，用四探针测试仪对氮掺杂碳膜的方块电阻进行测试，用扫描电镜对氮掺杂碳膜表面形貌进行分析。组装电池，用太阳光模拟器测试电池的光电转化率。研究结果表明，经过氮掺杂的碳膜，表面形貌致密，当N2的体积分数为30%时，薄膜中 N 元素含量为15.21%，薄膜的方块电阻为9.4Ω/□，电池的光电转化率为1.16%。
The nitrogen-doped carbon film was prepared by bipolar pulsed magnetron sputtering as counter elec-trode in dye-sensitized solar cells(DSSC).The structures and properties were investigated.The surface elemen-tal of nitrogen-doped carbon film was analyzed by X-ray photoelectron spectroscopy.The sheet resistance of ni-trogen-doped carbon film was detected by four point probe.The surface morphologies were observed by scan-ning electron microscopy.The performance of DSSC was tested by solar simulator after the cell built up.The results indicated that the surface morphology of nitrogen-doped carbon film was high density,when volume fraction of nitrogen was 30%,the nitrogen content in the film was 15.21%,the sheet resistance was 9.4Ω/□. The counter electrode exhibited a good photovoltaic performance,the efficiency reached 1 .1 6%.
参考文献
| [1] | Kay A.;Gratzel M. .LOW COST PHOTOVOLTAIC MODULES BASED ON DYE SENSITIZED NANOCRYSTALLINE TITANIUM DIOXIDE AND CARBON POWDER[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1996(1):99-117. |
| [2] | Martin CM;Burlakov VM;Assender HE .Modeling charge transport in composite solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(7/8):900-915. |
| [3] | 张亚,杨兵初,周聪华,王丽丽,童思超.碳球模板剂对TiO_2光阳极微结构及其光电性能影响研究[J].功能材料,2012(19):2716-2719. |
| [4] | O′regan B;Gratzel M .A low-cost,high-efficiency solar cell based on dye-sensitized colloidal TiO2 films[J].Nature,1991,353(24):737-740. |
| [5] | Christophe J;Gratzel M .Nanocrystalline titanium oxide electrodes for photovoltaic application[J].Journal of the American Chemical Society,1997,80(12):3157-3171. |
| [6] | 张娓娓,刘贵山,胡志强,郑传柯,颜世博.碳材料在太阳能电池对电极中的研究进展[J].材料导报,2009(z2):291-294. |
| [7] | Fang, B.;Fan, S.-Q.;Kim, J.H.;Kim, M.-S.;Kim, M.;Chaudhari, N.K.;Ko, J.;Yu, J.-S. .Incorporating hierarchical nanostructured carbon counter electrode into metal-free organic dye-sensitized solar cell[J].Langmuir: The ACS Journal of Surfaces and Colloids,2010(13):11238-11243. |
| [8] | I. Banerjee;Neelam Kumari;Ashis K. Singh;Mukesh Kumar;Pinaki Laha;A.B. Panda;S.K. Pabi;P.K. Barhai;S.K. Mahapatra .Influence of RF power on the electrical and mechanical properties of nano-structured carbon nitride thin films deposited by RF magnetron sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2010(24):7240-7244. |
| [9] | 赵蕾,付永辉,刘登益,朱晓东,何家文.离子束辅助磁控溅射制备类石墨碳膜的结构与性能研究[J].无机材料学报,2005(01):181-186. |
| [10] | Sea-Fue Wang;K. Koteswara Rao;Thomas C.K. Yang .Investigation of nitrogen doped diamond like carbon films as counter electrodes in dye sensitized solar cells[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2011(5):1969-1974. |
| [11] | Beshkov G. .XPS spectra of thin CN_x films prepared by chemical vapor deposition[J].Diamond and Related Materials,1999(2 Mar):591-594. |
| [12] | 李合琴,何晓雄,王淑占,巫邵波,赵之明.掺氮类金刚石薄膜的显微结构和光谱学研究[J].真空科学与技术学报,2008(03):225-229. |
| [13] | 李红凯,林国强,董闯,闻立时.氮含量对脉冲偏压电弧离子镀CNx薄膜结构与性能的影响[J].金属学报,2008(08):917-921. |
| [14] | 肖剑荣,徐慧,王焕友,邓超生,李明君.含氮氟化类金刚石（FN-DLC）薄膜的研究：（Ⅳ）氮掺杂对薄膜结构的影响[J].物理学报,2007(05):3004-3009. |
- 下载量()
- 访问量()
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%