稀土氧化物具有其独特的光、电等化学性质,在催化、发光、磁性等方面有很大的应用前景。如果将稀土氧化物制备成具有低的维数和高的比表面积的一维纳米管状,有可能增强其各方面的性能,它的开发和应用前景十分喜人。综述了稀土氧化物纳米管的制备方法,并介绍了稀土氧化物纳米管在催化、发光和磁性方面应用的进展,最后论述了还需要研究的问题和方向。
Rare earth oxide has many excellent properties and great application value,because of its unique opti-cal,electric and chemical properties,making it has great application prospects in catalysis,luminescence,mag-netism.If the rare earth oxide was prepared into a lower dimension and high specific surface area of one dimen-sional nanotubes,it was possible to enhance the performance in various aspects,the development and applica-tion prospect was very fascinated.This article summarized an overview of the preparation method of rare earth oxide nanotubes,and introduces the progress of rare earth oxide nanotubes in catalysis,luminescence and mag-netic applications.Finally discussed the need study problems and direction.
参考文献
[1] | Animesh Jha;Billy Richards;Gin Jose;Toney Teddy-Fernandez;Purushottam Joshi;Xin Jiang;Joris Lousteau .Rare-earth ion doped TeO_2 and GeO_2 glasses as laser materials[J].Progress in materials science,2012(8):1426-1491. |
[2] | WU Lingyuan,WEN Jun,QIN Yanguang,YIN Min,XIAShangda,Azeretili Ablekem.Experimental and theoretical analysis on the charge transfer band of Y2O3:Eu nanocrystals[J].稀土学报(英文版),2011(11):1009-1012. |
[3] | Linping Sun;Xinwen Guo;Guang Xiong.Ethylation of coking benzene with ethanol over nano-sized ZSM-5 zeolites: Effects of rare earth oxides on catalyst stability[J].Catalysis Communications,2012:18-21. |
[4] | Yasuhiro Yamada;Masaki Segawa;Fumiya Sato .Catalytic performance of rare earth oxides in ketonization of acetic acid[J].Journal of molecular catalysis, A. Chemical,2011(1/2):79-86. |
[5] | Cai Lili;Rao P M;Feng Yunzhe et al.Flame synthesis of 1-D complex metal oxide nanomaterials[J].Proceedings of the Combustion Institute,2013,34:2229-2236. |
[6] | Frangois Le Coz;Laurent Aruraulf;Lucien Datas .Chemical analysis of a single basic cell of porous anodic aluminium oxide templates[J].Materials Characterization,2010(3):283-288. |
[7] | Guosheng Wu;Lide Zhang;Baochang Cheng;Ting Xie;Xiaoyou Yuan .Synthesis of Eu_2O_3 Nanotube Arrays through a Facile Sol-Gel Template Approach[J].Journal of the American Chemical Society,2004(19):5976-5977. |
[8] | Kuang, Q;Lin, ZW;Lian, W;Jiang, ZY;Xie, ZX;Huang, RB;Zheng, LS .Syntheses of rare-earth metal oxide nanotubes by the sol-gel method assisted with porous anodic aluminum oxide templates[J].Journal of Solid State Chemistry,2007(4):1236-1242. |
[9] | 杨雷,唐元洪,陈江华,陈小华,王倩,张伟,姜志.Y2O3∶Eu3+纳米管阵列的荧光和拉曼光谱研究[J].功能材料,2008(02):205-208,212. |
[10] | Iijima S .Helical microtubules of graphitic carbon[J].Nature,1991,354:56-58. |
[11] | Whitby R L D;Hsu W K;Zhu Y Q et al.Novel nanoscale architectures:coated nanotubes and other nanowires[J].Philosophical Transactions of the Royal Society of London Series A Mathematical and Physical Sciences,2004,362:2127-2142. |
[12] | Zhang DS;Fu HX;Shi LY;Fang JH;Li Q .Carbon nanotube assisted synthesis of CeO2 nanotubes[J].International Journal of Quantum Chemistry,2007(2):654-660. |
[13] | Haopeng Yang;Dengsong Zhang;Liyi Shi .Synthesis and strong red photoluminescence of europium oxide nanotubes and nanowires using carbon nanotubes as templates[J].Acta materialia,2008(5):955-967. |
[14] | Weishi Huang;Jianfeng Shen;Lei Wan;Yu Chang;Mingxin Ye .Y_2O_3:Yb/Er nanotubes: Layer-by-layer assembly on carbon-nanotube templates and their upconversion luminescence properties[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2012(11):3875-3880. |
[15] | Mitsunori Yada;Masami Mihara;Shingi Mouri;Masako Kuroki;Tsuyoshi Kijima .Rare Earth (Er, Tm, Yb, Lu) Oxide Nanotubes Templated by Dodecylsulfate Assemblies[J].Advanced Materials,2002(4):309-313. |
[16] | Changfeng Wu;Weiping Qin;Guanshi Qin;Dan Zhao;Jisen Zhang;Shihua Huang;Shaozhe Lu;Huangqing Liu;Haiyan Lin .Photoluminescence from surfactant-assembled Y_(2)O_(3):Eu nanotubes[J].Applied physics letters,2003(4):520-522. |
[17] | Mao YB;Huang JY;Ostroumov R;Wang KL;Chang JP .Synthesis and luminescence properties of erbium-doped Y2O3 nanotubes[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(7):2278-2285. |
[18] | James A. Dorman;Yuanbing Mao;John R. Bargar .In Situ X-ray Diffraction and Absorption Studies of the Growth and Phase Transformation of Yttrium Hydroxide Nanotubes to Their Oxide Counterparts[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(41):17422-17427. |
[19] | Devaraju M K;Yin S;Sato T .A rapid hydrothermal synthesis of rare earth oxide activated Y(OH)3 and Y2O3 nanotubes[J].Nanotechnology,2009,20(30):305302. |
[20] | Thongtem T;Phuruangrat A;Ham D J et al.Con-trolled Gd2 O3 nanorods and nanotubes by the annealing of Gd(OH)3 nanorod and nanotube precursors and self-templates produced by a microwave-assisted hydrother-mal process[J].Crystal Engineering Communications,2010,12:2962-2966. |
[21] | Qi Zhu;Ji-Guang Li;Xiaodong Li;Xudong Sun .Selective Processing, Structural Characterization, and Photoluminescence Behaviors of Single Crystalline (Gd_(1-x)Eu_x)_2O_3 Nanorods and Nanotubes[J].Current Nanoscience,2010(5):496-504. |
[22] | FANG Jianhui,CAO Zhiyuan,ZHANG Dengsong,SHEN Xia,DING Weizhong,SHI Liyi.Preparation and CO conversion activity of ceria nanotubes by carbon nanotubes templating method[J].稀土学报(英文版),2008(02):153-157. |
[23] | Zhang Dengsong;Pan Chengsi;Shi Liyi et al.A highly reactive catalyst for CO oxidation:CeO2 nanotubes syn-thesized using carbon nanotubes as removable templates[J].Microporous and Mesoporous Materials,2009,117:193-200. |
[24] | Guozhu Chen;Federico Rosei;Dongling Ma .Interfacial Reaction-Directed Synthesis of Ce-Mn Binary Oxide Nanotubes and Their Applications in CO Oxidation and Water Treatment[J].Advanced functional materials,2012(18):3914-3920. |
[25] | Guangxing Ping;Xinyan Wang;Yuntao Wu;Laishun Qin;Kangying Shu .Synthesis and luminescent characteristic of Eu~(3+)-doped (Gd,Lu)_2O_3 nanopowders[J].Optical materials,2012(4):748-752. |
[26] | Ju, X.;Li, X.;Yang, Y.;Li, W.;Tao, C.;Feng, W..Luminescence properties of core-shell structured SiO _2@CaMoO _4:Eu ~3 phosphor[J].Journal of Solid State Chemistry,2012:109-113. |
[27] | Puchalska, M.;Zych, E. .Effect of Na co-dopant and activator concentration on luminescent properties of CaGa _4O _7:Eu ~3[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2012(11):2879-2884. |
[28] | Zunli Mo;Zhepeng Deng;Ruibin Guo;Qiangang Fu;Chao Feng;Pengwei Liu;Yu Sun .Synthesis and luminescence properties for europium oxide nanotubes[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2012(1):121-126. |
[29] | Synthesis of Magnetic, Up-Conversion Luminescent,and Mesoporous Core-Shell-Structured Nanocomposites as Drug Carriers[J].Advanced functional materials,2010(7):1166. |
[30] | Chih-Chia Huang;Tzu-Yu Liu;Chia-Hao Su .Superparamagnetic Hollow and Paramagnetic Porous Gd2O3 Particles[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(12):3840-3848. |
[31] | Park Y I;Kim J H;Lee K T et al.Nonblinking and nonbleaching upconverting nanoparticles as an optical imaging nanoprobe and T1 magnetic resonance imaging contrast[J].Agent Adv Mater,2009,21:4467-4471. |
[32] | Chang YP;Liu KH;Chao CS;Chen SY;Liu DM .Synthesis and characterization of mesoporous Gd2O3 nanotube and its use as a drug-carrying vehicle.[J].Acta biomaterialia,2010(9):3713-3719. |
[33] | Congbing Tan;Bin Ma;Jie Zhang;Yong Zuo;Wei Zhu;Yunxin Liu;Wenbin Li;Yutao Zhang.Pure red upconversion photoluminescence and paramagnetic properties of Gd_2O_3:Yb~(3+), Er~(3+) nanotubes prepared via a facile hydrothermal process[J].Materials Letters,2012:147-149. |
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