用聚乙烯醇缩丁醛作为配制硼硅酸盐玻璃/α-Al2 O3流延浆料的粘结剂，流延成型制备玻璃/Al2 O3生料带，研究了 PVB 对玻璃/Al2 O3复合料生料带密度、力学性能、微观结构及其烧结性能等的影响。实验结果表明，随着 PVB 分子量和羟基含量减小，生料带拉伸强度和断裂伸长率降低、体积密度增加、生料带排胶热分解温度降低，对烧结瓷体密度和介电性能的影响较小。
In this paper,the borosilicate glass/Al2 O3 tape was prepared with the binder system of polyvinyl bu-tyral (PVB)by tape casting.The effect of PVB on the bulk density,the microstructure and mechanical property of green tape was detailly studied.The results showed that with the decreasing of molecular weight and hydrox-yl content of PVB,the decomposition temperature,the tensile strength and breaking elongation of green tape were reduced;the bulk density was increased;the density and dielectric properties of the sintered ceramic did not change obviously.
参考文献
| [1] | 吴黎,朱丽慧,黄清伟,刘庆峰.有机添加剂对氧化铝流延浆料流变性能的影响[J].电子元件与材料,2012(03):45-48. |
| [2] | Rodrigo M .The role of slip additives in tape casting tech-nology:part I-solvents and dispersants[J].Laboratory Report,1992,71(10):1521-1531. |
| [3] | Yoshihiko lmanaka.Multilayered low temperature cofired ceramics(LTCC)technology[M].Japan:Fujitsu Labora-tories Ltd,2005 |
| [4] | Mistler R.E;Twiname E R.Tape casting:theory and practice[M].New York:Wiley,2006 |
| [5] | Rodrigo M .The role of slip additives in tape casting tech-nology:part II-binder and plasticizers[J].Laboratory Re-port,1992,71(11):1647-1657. |
| [6] | Raymond A. Cutler;Brian Kleinlein .Effect of the hydroxyl content and molecular weight of polyvinyl butyral on tape properties[J].Journal of the European Ceramic Society,2009(15):3211-3218. |
| [7] | Brook R J;Cahn R W;Haasen P.Processing of ce-ramics[M].Weinheim:VCH Verlagsgesellschaft mbH,1996 |
| [8] | Howard Kevin E;Lakeman Charles D E;Payne David A .Surface chemistry of various poly(vinyl butyral)polymers adsorbed onto alumina[J].J Am Ceram Soc,1990,73(08):2543-2546. |
| [9] | Xuesong Lu;Julian R.G. Evans;Stephen N. Heavens .A comparison of the tape casting of α- and β-alumina[J].Journal of the European Ceramic Society,2012(16):4219-4228. |
| [10] | Han Zhenyu;Ma Jusheng;Xu Zhonghua .Sintering proeess analysis of low temperature cofired ceramics I organics pyrolysis in low temperature phase[J].Jour-nal of Functional Materials,2001,32(03):272-276. |
| [11] | L. A. Salam;R. D. Matthews .Pyrolysis of polyvinyl butyral (PVB) binder in thermoelectric green tapes[J].Journal of the European Ceramic Society,2000(9):1375-1383. |
| [12] | Institute 214 of CNIGC .The sintering process of large LTCC substrate[P].CNP:102863223A,2013-01-09. |
| [13] | 马振伟,刁讯刚,王天民,周济.排胶制度对迭层式片式电感性能的影响[J].稀有金属材料与工程,2005(z2):1077-1080. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%