欢迎登录材料期刊网

材料期刊网

高级检索

在过去的十多年时间里,石墨烯以其优异的物理性能、化学可调性以及潜在的应用前景引起了广泛关注。然而本征石墨烯是一种零带隙的半金属,这极大地限制了其在很多领域的应用。因此,石墨烯的能带调控并将其由金属性转变为半导体性的相关研究,具有极其重要的意义。综述了现阶段在石墨烯电子结构和能带调控方面的研究进展,并深入探讨了半导体性石墨烯的应用领域和前景,为石墨烯的应用和产业化提供借鉴。

During the last decade,graphene has been extensively paid attentions,due to its extraordinary physi-cal properties,chemical tunability,and potential for various applications.However,graphene was an intrinsic semimetal with a zero bandgap,which considerably hampers its applications in many areas.Therefore,it was significantly important to study the band engineering of graphene,and transform graphene from metal into sem-iconductor with a sizable bandgap.In this paper,we present an overview of the research progress on graphene electronic structures and its bandgaps in recent years,and also explore the potential application areas of the semiconducting graphene.It was expect to provide fundamental references for the future applications and indus-trializations of graphene.

参考文献

[1] K. S. Novoselov;D. Jiang;F. Schedin;T. J. Booth;V. V. Khotkevich;S. V. Morozov;A. K. Geim .Two-dimensional atomic crystals[J].Proceedings of the National Academy of Sciences of the United States of America,2005(30):10451-10453.
[2] Meyer Jannik C;Geim A K;Katsnelson M I et al.The structure of suspended graphene sheets[J].NATURE,2007,446(7131):60-63.
[3] A.FASOLINO;J.H.LOS;M.I.KATSNELSON .Intrinsic ripples in graphene[J].Nature materials,2007(11):858-861.
[4] Novosolov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].SCIENCE,2004,306(5696):666-669.
[5] Beenakker CWJ .Colloquium: Andreev reflection and Klein tunneling in graphene[J].Reviews of Modern Physics,2008(4 Pt.1):1337-1354.
[6] Zhang Yuanbo;Tan Yanwen;Stormer Horst L et al.Experimental observation of the quantum Hall effect and Berry's phase in graphene[J].NATURE,2005,438(7065):201-204.
[7] Novoselov K S;Geim A K;Moorozov S V et al.Two-dimensional gas of massless dirac fermions in graphene[J].NATURE,2005,438(10):197-200.
[8] Ezawa, M .Peculiar width dependence of the electronic properties of carbon nanoribbons[J].Physical review. B, Condensed Matter And Materials Physics,2006(4):5432-1-5432-8-0.
[9] Bolotin, KI;Sikes, KJ;Jiang, Z;Klima, M;Fudenberg, G;Hone, J;Kim, P;Stormer, HL .Ultrahigh electron mobility in suspended graphene[J].Solid State Communications,2008(9/10):351-355.
[10] Keun Soo Kim;Yue Zhao;Houk Jang;Sang Yoon Lee;Jong Min Kim;Kwang S. Kim;Jong-Hyun Ann;Philip Kim;Jae-Young Choi;Byung Hee Hong .Large-scale Pattern Growth Of Graphene Films For Stretchable Transparent Electrodes[J].Nature,2009(7230):706-710.
[11] Balandin AA;Ghosh S;Bao WZ;Calizo I;Teweldebrhan D;Miao F;Lau CN .Superior thermal conductivity of single-layer graphene[J].Nano letters,2008(3):902-907.
[12] Nair RR;Blake P;Grigorenko AN;Novoselov KS;Booth TJ;Stauber T;Peres NM;Geim AK .Fine structure constant defines visual transparency of graphene.[J].Science,2008(5881):1308-1308.
[13] Robert J. Young;Ian A. Kinloch;Lei Gong;Kostya S. Novoselov .The mechanics of graphene nanocomposites: A review[J].Composites science and technology,2012(12):1459-1476.
[14] C. N. R. Rao;A. K. Sood;K. S. Subrahmanyam .Graphene: The New Two-Dimensional Nanomaterial[J].Angewandte Chemie,2009(42):7752-7777.
[15] Nathan O. Weiss;Hailong Zhou;Lei Liao;Yuan Liu;Shan Jiang;Yu Huang;Xiangfeng Duan .Graphene: An Emerging Electronic Material[J].Advanced Materials,2012(43):5782-5825.
[16] Xiao Huang;Xiaoying Qi;Freddy Boey .Graphene-based composites[J].Chemical Society Reviews,2012(2):666-686.
[17] Bai Song;Shen Xiaoping .Graphene-inorganic nanocom-posites[J].RSC Advances,2012,2(01):64-98.
[18] Choi, W;Lahiri, I;Seelaboyina, R;Kang, YS .Synthesis of Graphene and Its Applications: A Review[J].Critical Reviews in Solid State and Materials Sciences,2010(1):52-71.
[19] Xu Yuxi;Shi Gaoquan .Assembly of chemically modi-fied graphene:methods and applications[J].Journal of Materials Chemistry,2011,21(10):3311-3323.
[20] David S. Hecht;Liangbing Hu;Glen I ruin .Emerging Transparent Electrodes Based on Thin Films of Carbon Nanotubes, Graphene, and Metallic Nanostructures[J].Advanced Materials,2011(13):1482-1513.
[21] Son Young-Woo;Marvin L Cohen;Steven G Louie .Half-metallic grapheen nanoribbons[J].NATURE,2006,444(7117):347-349.
[22] Saleh Ghoreishi Seyed;Kamyar Saghafi;Farshi Morav-vej et al.A novel graphene nano-ribbon field effect transistor with schotiky tunneling drain and ohmic tun-neling source[J].Modern Physics Letters B,2013,27(26):1350189.
[23] Moon;J.S.;Seo;H.-C.;Stratan;F.;Antcliffe;M. .Lateral Graphene Heterostructure Field-Effect Transistor[J].IEEE Electron Device Letters,2013(9):1190-1192.
[24] Zhuo Wang;Andrew P. Cook;Xuesong Yang;Zhihong Liu;Qingkai Yu;Maggie Y. Chen .Graphene-based Flexible Field Effect Transistor with Inkjet Printed Silver Electrodes[J].Current Nanoscience,2013(5):635-637.
[25] Zhu Hongwei;Xu Zhiping;Xie Dan.Graphene-struc-ture,preparation methods and properties characteriza-tion[M].北京:清华大学出版社,2011:120-121.
[26] Czerw R;Terrones M;Charlier J C et al.Identification of electron donor states in N-doped carbon nanotubes[J].Nano Letters,2001,9(01):457-460.
[27] Aran K. Manna;Swapan K. Pati .Doping single-walled carbon nanotubes through molecular charge-transfer: a theoretical study[J].Nanoscale,2010(7):1190-1195.
[28] Xu, X.;Jiang, S.;Hu, Z.;Liu, S. .Nitrogen-doped carbon nanotubes: High electrocatalytic activity toward the oxidation of hydrogen peroxide and its application for biosensing[J].ACS nano,2010(7):4292-4298.
[29] Reddy, A.L.M.;Srivastava, A.;Gowda, S.R.;Gullapalli, H.;Dubey, M.;Ajayan, P.M. .Synthesis of nitrogen-doped graphene films for lithium battery application[J].ACS nano,2010(11):6337-6342.
[30] Wei, DC;Liu, YQ;Wang, Y;Zhang, HL;Huang, LP;Yu, G .Synthesis of N-Doped Graphene by Chemical Vapor Deposition and Its Electrical Properties[J].Nano letters,2009(5):1752-1758.
[31] Li Xiaolin;Wang Hailiang;Robinson Joshua T et al.Simultaneous nitrogen-doping and reduction of graphene oxide[J].Journal of the American Chemical Society,2008,131(43):15939-15944.
[32] Nan Li;Zhiyong Wang;Keke Zhao .Large scale synthesis of N-doped multi-layered graphene sheets by simple arc-discharge method[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(1):255-259.
[33] Zhang Yupeng;Cao Bing;Zhang Bin et al.The pro-duction of nitrogen-doped graphene from mixed amine+ ethanol flames[J].THIN SOLID FILMS,2012,520(23):6850-6855.
[34] Dmitry V. Kosynkin;Amanda L. Higginbotham;Alexander Sinitskii;Jay R. Lomeda;Ayrat Dimiev;B. Katherine Price;James M. Tour .Longitudinal Unzipping Of Carbon Nanotubes To Form Graphene Nanoribbons[J].Nature,2009(7240):872-876.
[35] Liying Jiao;Li Zhang;Xinran Wang;Georgi Diankov;Hongjie Dai .Narrow Graphene Nanoribbons From Carbon Nanotubes[J].Nature,2009(7240):877-880.
[36] Jinming Cai;Pascal Ruffieux;Rached Jaafar;Marco Bieri;Thomas Braun;Stephan Blankenburg;Matthias Muoth;Ari P. Seitsonen;Moussa Saleh;Xinliang Feng;Klaus Muellen;Roman Fasel .Atomically precise bottom-up fabrication of graphene nanoribbons[J].Nature,2010(Jul.22 TN.7305):470-473.
[37] Bai, JW;Duan, XF;Huang, Y .Rational Fabrication of Graphene Nanoribbons Using a Nanowire Etch Mask[J].Nano letters,2009(5):2083-2087.
[38] Chang CP;Wu BR;Chen RB;Lin MF .Deformation effect on electronic and optical properties of nanographite ribbons[J].Journal of Applied Physics,2007(6):63506-1-63506-6-0.
[39] Gui G;Li J;Zhong JX .Band structure engineering of graphene by strain: First-principles calculations[J].Physical review, B. Condensed matter and materials physics,2008(7):075435-1-075435-6-0.
[40] Ni, Z.H.;Yu, T.;Lu, Y.H.;Wang, Y.Y.;Feng, Y.P.;Shen, Z.X. .Uniaxial strain on graphene: Raman spectroscopy study and band-gap opening[J].ACS nano,2008(11):2301-2305.
[41] Huang, M.;Pascal, T.A.;Kim, H.;Goddard, W.A.;Greer, J.R. .Electronic-mechanical coupling in graphene from in situ nanoindentation experiments and multiscale atomistic simulations[J].Nano letters,2011(3):1241-1246.
[42] Yupeng Zhang;Chengzhi Luo;Weiping Li .Strain induced chemical potential difference between monolayer graphene sheets[J].Nanoscale,2013(7):2616-2619.
[43] Ruge Quhe;Ma Jianhua;Zeng Zesheng et al.Tunable band gap in few-layer graphene by surface adsorption[J].Scientific Reports,2013,3:1794.
[44] F.SCHEDIN;A.K.GEIM;S.V.MOROZOV .Detection of individual gas molecules adsorbed on graphene[J].Nature materials,2007(9):652-655.
[45] Akshay Mathkar;Dylan Tozier;Paris Cox .Controlled, Stepwise Reduction and Band Gap Manipulation of Graphene Oxide[J].Journal of physical chemistry letters,2012(8):986-991.
[46] Samarakoon, D.K.;Wang, X.-Q. .Tunable band gap in hydrogenated bilayer graphene[J].ACS nano,2010(7):4126-4130.
[47] S.-H. Cheng;K. Zou;F. Okino;H. R. Gutierrez;A. Gupta;N. Shen;P. C. Eklund;J. 0. Sofo;J. Zhu .Reversible fluorination of graphene: Evidence of a two-dimensional wide bandgap semiconductor[J].Physical review, B. Condensed matter and materials physics,2010(20):205435:1-205435:5.
[48] Chen Xu;He Daping;Mu Shichun .The research of N-doped graphene[J].PROGRESS IN CHEMISTRY,2013,25(08):1292-1301.
[49] Yanhong Lu;Fan Zhang;Tengfei Zhang.Synthesis and supercapacitor performance studies of N-doped graphene materials using o-phenylenediamine as the double-N precursor[J].Carbon: An International Journal Sponsored by the American Carbon Society,2013:508-516.
[50] Jeong Hyung Mo;Lee Jung Woo;Shin Weon Ho et al.Nitrogen-doped graphene for high-performance ultraca-pacitors and the importance of nitrogen-doped at basal planes[J].Nano Letters,2011,11(06):2472-2477.
[51] Dengyu Pan;Song Wang;Bing Zhao .Li Storage Properties of Disordered Graphene Nanosheets[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(14):3136-3142.
[52] Reddy, A.L.M.;Srivastava, A.;Gowda, S.R.;Gullapalli, H.;Dubey, M.;Ajayan, P.M. .Synthesis of nitrogen-doped graphene films for lithium battery application[J].ACS nano,2010(11):6337-6342.
[53] Haibo Wang;Chuanjian Zhang;Zhihong Liu .Nitrogen-doped graphene nanosheets with excellent lithium storage properties[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(14):5430-5434.
[54] Wang H;Maiyalagan T;Wang X et al.Review on re-cent progress in nitrogen-doped graphene:synthesis,characterization,and its potential applications[J].ACS Catalysis,2012,2(05):781-794.
[55] Qu, L.;Liu, Y.;Baek, J.-B.;Dai, L. .Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells[J].ACS nano,2010(3):1321-1326.
[56] Dongsheng Geng;Ying Chen;Yougui Chen;Yongliang Li;Ruying Li;Xueliang Sun;Siyu Ye;Shanna Knights .High oxygen-reduction activity and durability of nitrogen-doped graphene[J].Energy & environmental science: EES,2011(3):760-764.
[57] Novoselov K S;Geim A K;Morozov S V et al.Elec-tric field effect in atomically thin carbon films[J].Sci-ence,2004,306(5696):666-669.
[58] Han MY;Ozyilmaz B;Zhang YB;Kim P .Energy band-gap engineering of graphene nanoribbons[J].Physical review letters,2007(20):6805-1-6805-4-0.
[59] Lei Liao;Jingwei Bai;Yung-Chen Lin;Yongquan Qu;Yu Huang;Xiangfeng Duan .High-Performance Top-Gated Graphene-Nanoribbon Transistors Using Zirconium Oxide Nanowires as High-Dielectric-Constant Gate Dielectrics[J].Advanced Materials,2010(17):1941-945,1894.
[60] Li X;Wang X;Zhang L;Lee S;Dai H .Chemically derived, ultrasmooth graphene nanoribbon semiconductors.[J].Science,2008(5867):1229-1232.
[61] Xinran Wang;Yijian Ouyang;Xiaolin Li;Hailiang Wang;Jing Guo;Hongjie Dai .Room-Temperature All-Semiconducting Sub-10-nm Graphene Nanoribbon Field-Effect Transistors[J].Physical review letters,2008(20):235-238.
[62] F.SCHEDIN;A.K.GEIM;S.V.MOROZOV .Detection of individual gas molecules adsorbed on graphene[J].Nature materials,2007(9):652-655.
[63] Joshi Rakes K;Gomez Humberto;Alvi Farah et al.Graphene films and ribbons for sensing of O2,and 100×10-6 of CO and NO2 in practical conditions[J].Journal of Physical Chemistry C,2010,114(14):6610-6613.
[64] Wu, W.;Liu, Z.;Jauregui, L.A.;Yu, Q.;Pillai, R.;Cao, H.;Bao, J.;Chen, Y.P.;Pei, S.-S. .Wafer-scale synthesis of graphene by chemical vapor deposition and its application in hydrogen sensing[J].Sensors and Actuators, B. Chemical,2010(1):296-300.
[65] Wang ZL;Song J .Piezoelectric nanogenerators based on zinc oxide nanowire arrays.[J].Science,2006(5771):242-246.
[66] Fan, F.-R.;Lin, L.;Zhu, G.;Wu, W.;Zhang, R.;Wang, Z.L. .Transparent triboelectric nanogenerators and self-powered pressure sensors based on micropatterned plastic films[J].Nano letters,2012(6):3109-3114.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%