在SOI基上制备光电纳米器件具有良好的光电集成应用前景,通过铜膜生长法在 SOI 基上制备了形貌为类针状的 Cu(OH)2前驱体纳米线,并采用热处理法600℃条件下成功制备了 CuO 纳米线。通过扫描电镜(SEM)、透射电镜(TEM)、X 射线衍射测试(XRD)对样品结构、形貌进行了表征。 SEM、TEM测试结果表明,Cu(OH)2前驱体纳米线结构一致,尺寸均匀,表面光滑。在 Cu(OH)2前驱体纳米线上二次生长的CuO 纳米线具有类蒲草状细长光滑的结构, CuO纳米线直径约为80~100 nm,长度约为10μm, CuO 纳米线结晶性良好。
Preparation of optoelectronic nanodevices on SOI substrate has good prospects in optoelectronic inte-grated applications.CuO nanowires have been successfully prepared on the SOI substrate at 600 ℃ by the heat treatment method of Cu(OH)2 precursors nanowires,which were pre-prepared by the copper film growth meth-od.Morphology and structures of the samples were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM),and X-ray diffraction (XRD).The SEM and TEM testing results showed that Cu(OH)2 precursors nanowires were needle-like with consistent structure and smooth and uniform surface.The CuO nanowires were cattail-like with tenuous and smooth structure.The diameter of CuO nanowires was about 80-100 nm,the length of nanowires was about 10μm.A good crystalline quality of CuO nanowires were obtained.
参考文献
[1] | Duan X;Huang Y;Agarwal R et al.Single-nanowire electrically driven lasers[J].NATURE,2003,421(6920):241-245. |
[2] | K. Shantha Shankar;A.K. Raychaudhuri .Fabrication of nanowires of multicomponent oxides: Review of recent advances[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2005(5/8):738-751. |
[3] | Xia Y;Yang P;Sun Y et al.One-dimensional nano-structures:synthesis,characterization,and applications[J].Advanced Materials,2003,15(05):353-389. |
[4] | Campos, LC;Tonezzer, M;Ferlauto, AS;Grillo, V;Magalhaes-Paniago, R;Oliveira, S;Ladeira, LO;Lacerda, RG .Vapor-solid-solid growth mechanism driven by epitaxial match between solid AuZn alloy catalyst particles and ZnO nanowires at low temperatures[J].Advanced Materials,2008(8):1499-1504. |
[5] | Marabelli F.;Salghettidrioli F.;Parravicini GB. .OPTICAL GAP OF CUO[J].Physical Review.B.Condensed Matter,1995(3):1433-1436. |
[6] | Reitz JB.;Solomon EI. .Propylene oxidation on copper oxide surfaces: Electronic and geometric contributions to reactivity and selectivity[J].Journal of the American Chemical Society,1998(44):11467-11478. |
[7] | Wang C;Fu XQ;Xue XY;Wang YG;Wang TH .Surface accumulation conduction controlled sensing characteristic of p-type CuO nanorods induced by oxygen adsorption[J].Nanotechnology,2007(14):45506-1-45506-5-0. |
[8] | Soon-Chang Yeon;Woo-Yong Sung;Wal-Jun Kim;Seung-Min Lee;Ho-Young Lee;Yong-Hyup Kim .Field emission characteristics of CuO nanowires grown on brown-oxide- coated Cu films on Si substrates by conductive heating in air[J].Journal of Vacuum Science & Technology, B. Microelectronics and Nanometer Structures: Processing, Measurement and Phenomena,2006(2):940-944. |
[9] | Field emission from various CuO nanostructures[J].Applied Physics Letters,2003(16):3383-3385. |
[10] | Zhang, K.;Yang, Y.;Pun, E.Y.B.;Shen, R. .Local and CMOS-compatible synthesis of CuO nanowires on a suspended microheater on a silicon substrate[J].Nanotechnology,2010(23):235602-1-235602-7. |
[11] | Minhua Cao;Changwen Hu;Enbo Wang .The First Fluoride One-Dimensional Nanostructures: Microemulsion-Mediated Hydrothermal Synthesis of BaF_2 Whiskers[J].Journal of the American Chemical Society,2003(37):11196-11197. |
[12] | W.Wang;Y.Liu;C.Xu;C.Zheng;G.Wang;Z.Liu .A simple wet-chemical synthesis and characterization of CuO nanorods[J].Applied physics, A. Materials science & processing,2003(3):417-420. |
[13] | Wen XG;Xie YT;Choi CL;Wan KC;Li XY;Yang SH .Copper-based nanowire materials: Templated syntheses, characterizations, and applications[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(10):4729-4737. |
[14] | Suhua Wang;Qunjian Huang;Xiaogang Wen;Shihe Yang .Thermal oxidation of Cu_2S nanowires:a template method for the fabrication of mesoscopic Cu_xO (x=1,2) wires[J].Physical chemistry chemical physics: PCCP,2002(14):3425-3429. |
[15] | CuO nanostructures on copper foil by a simple wet chemical route at room temperature[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2010(6):p.693. |
[16] | Wen XG.;Zhang WX.;Yang SH. .Synthesis of Cu(OH)(2) and CuO nanoribbon arrays on a copper surface[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(14):5898-5903. |
[17] | Y W Zhu;T Yu;F C Cheong .Large-scale synthesis and field emission properties of vertically oriented CuO nanowire films[J].Nanotechnology,2005(1):88-92. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%