地聚合物是指采用天然矿物或固体废弃物及人工硅铝化合物为原料,在碱性条件下通过矿物缩聚而形成的三维网状聚合胶凝材料。地聚合物独特的结构与性质使其在固化/稳定化重金属方面具有明显优势,近年来已成为国内外研究热点。针对地聚合物固化/稳定化重金属,重点阐述了影响地聚合物固化/稳定化重金属效果的重要因素,并综述了国内外研究者对地聚合物固化/稳定化重金属作用机制的研究成果。
Geopolymer is a kind of inorganic polymer cementitious material,which has a 3D network of silico-a-luminate structures.Geopolymeric materials could be synthesized from calcined clays,industrial waste or other alumino-silicate containing source materials under alkaline conditions.Geopolymer had been a hot point in im-mobilizing heavy metals in the recent years due to its unique structure and properties.Important factors that in-fluence the solidification/stabilization of geopolymers were emphasized introduced,as well as current status of the researches on mechanism of immobilizing heavy metals are reviewed.
参考文献
[1] | 金漫彤,楼敏晓,张琼,王连军.土壤聚合物对几种重金属离子固化效果的研究[J].矿物学报,2008(01):66-70. |
[2] | 蒋建国,许鑫,张妍.城市垃圾焚烧飞灰的硅酸盐水泥稳定化效果研究[J].环境科学,2006(12):2564-2569. |
[3] | Davidovits J .Geopolymers and geopolymeric materials[J].Journal of Thermal Analysis and Calorimetry,1989,35(02):429-441. |
[4] | Davidovits J .Geopolymers[J].Journal of Thermal Anal-ysis and Calorimetry,1991,37(08):1633-1656. |
[5] | Jaarsveld V.N.;Lorenzen L. .THE POTENTIAL USE OF GEOPOLYMERIC MATERIALS TO IMMOBILISE TOXIC METALS: PART I. THEORY AND APPLICATIONS[J].Minerals Engineering,1997(7):659-669. |
[6] | Li Song .Inorganic polymer-statusin geopolymer material[J].Journal of Functional Materials,2007,38(09):3549-3552. |
[7] | J.G.S.V.Jaarsveld;J.S.J.V.Deventer .The effect of metal contaminants on the formation and properties of waste-based geopolymers[J].Cement and Concrete Research,1999(8):1189-1200. |
[8] | 徐建中,周云龙,唐然肖.地聚合物水泥固化重金属的研究[J].建筑材料学报,2006(03):341-346. |
[9] | Jianguo Zhang;John L. Provis;Dingwu Feng;Jannie S.J. van Deventer .Geopolymers for immobilization of Cr~(6+), Cd~(2+), and Pb~(2+)[J].Journal of hazardous materials,2008(2/3):587-598. |
[10] | Van Jaarsveld J G S;Van Deventer J S J;Lorenzen L .Factors affecting the immobilization of metals in geopo-lymerized flyash[J].Metallurgical and Materials Trans-actions B,1998,29(01):283-291. |
[11] | GUO Xiaolu,SHI Huisheng,XU Mingfeng.Static and Dynamic Leaching Experiments of Heavy Metals from Fly Ash-Based Geopolymers[J].武汉理工大学学报(材料科学版)(英文版),2013(05):938-943. |
[12] | 朱强,卢都友.固化重金属离子用地质聚合物基体的制备及其离子相容性[J].南京工业大学学报(自然科学版),2010(03):61-66. |
[13] | Zhang Yunsheng;Sun Wei;Chen Qianli;Chen Lin .Synthesis and heavy metal immobilization behaviors of slag based geopolymer[J].Journal of hazardous materials,2007(1/2):206-213. |
[14] | 金漫彤,张琼,楼敏晓,王连军.粉煤灰用于土壤聚合物固化重金属离子的研究[J].硅酸盐通报,2007(03):467-471. |
[15] | 施惠生,夏明,郭晓潞.粉煤灰基地聚合物反应机理及各组分作用的研究进展[J].硅酸盐学报,2013(07):972-980. |
[16] | Zheng Juanrong;Liu Lina .Test investigation on the so-lidification of heavy metal(Pb2+)by alkali-activated ce-menting materials their soaking toxicity[J].Bulletin Chinese Ceramic Society,2009,28(03):435-439. |
[17] | Van Jaarsveld J G S;Van Deventer J S J;Schwartzman A .The potential use of geopolymeric materials to immo-bilise toxic metals:Part II.Material and leaching charac-teristics[J].Minerals Engineering,1999,12(01):75-91. |
[18] | Davidovits J.Geopolymer chemistry and applications[M].France:Geopolymer Institute,2008 |
[19] | The effects of alkaline dosage and Si/Al ratio on the immobilization of heavy metals in municipal solid waste incineration fly ash-based geopolymer[J].Chemosphere: Environmental toxicology and risk assessment,2010(6):p.665. |
[20] | J.W. PHAIR;J.S.J. VAN DEVENTER .EFFECT OF SILICATE ACTIVATOR pH ON THE LEACHING AND MATERIAL CHARACTERISTICS OF WASTE-BASED INORGANIC POLYMERS[J].Minerals Engineering,2001(3):289-304. |
[21] | J. W. Phair;J. S. J. van Deventer .Characterization of Fly-Ash-Based Geopolymeric Binders Activated with Sodium Aluminate[J].Industrial & Engineering Chemistry Research,2002(17):4242-4251. |
[22] | A.Palomo;M.W.Grutzeck .Alkali-activated fly ashes A cement for the future[J].Cement and Concrete Research,1999(8):1323-1329. |
[23] | Rees CA;Provis JL;Lukey GC;van Deventer JSJ .In situ ATR-FTIR study of the early stages of fly ash geopolymer gel formation[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(17):9076-9082. |
[24] | Isabella Lancellotti;Elie Kamseu;Marco Michelazzi .Chemical stability of geopolymers containing municipal solid waste incinerator fly ash[J].Waste Management,2010(4):673-679. |
[25] | Jan Deja .Immobilization of Cr~(6+), Cd~(2+), Zn~(2+) and Pb~(2+) in alkali-activated slag binders[J].Cement and Concrete Research,2002(12):1971-1979. |
[26] | Lee WKW.;van Deventer JSJ. .The effects of inorganic salt contamination on the strength and durability of geopolymers[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2002(2/3):115-126. |
[27] | Lei Zheng;Chengwen Wang;Wei Wang .Immobilization of MSWI fly ash through geopolymerization: Effects of water-wash[J].Waste Management,2011(2):311-317. |
[28] | Lee W K W;Van Deventer J S J .The effect of ionic con-taminants on the early-age properties of alkali-activated fly ash-based cements[J].Cement and Concrete Re-search,2002,32(04):577-584. |
[29] | Blackford MG;Hanna JV;Pike KJ;Vance ER;Perera DS .Transmission electron microscopy and nuclear magnetic resonance studies of geopolymers for radioactive waste immobilization[J].Journal of the American Ceramic Society,2007(4):1193-1199. |
[30] | Hua Xu;Jannie S.J. Van Deventer .Geopolymerisation of multiple minerals[J].Minerals Engineering,2002(12):1131-1139. |
[31] | Lee WKW.;van Deventer JSJ. .Structural reorganisation of class F fly ash in alkaline silicate solutions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2002(1):49-66. |
[32] | Jin Mantong .Immobilization of heavy metals in munici-pal solid waste incineration(MSWI)fly ash with geopolymer[D].Nanj ing:Nanj ing University of Science& Technology,2011. |
[33] | T.W. Cheng;M.L. Lee;M.S. Ko;T.H. Ueng;S.F. Yang .The heavy metal adsorption characteristics on metakaolin-based geopolymer[J].Applied clay science,2012(Feb.):90-96. |
[34] | Kamel Al-Zboon;Mohammad S. Al-Harahsheh;Falah Bani Hani .Fly ash-based geopolymer for Pb removal from aqueous solution[J].Journal of hazardous materials,2011(1/3):414-421. |
[35] | Shaobin Wang;Lin Li;Z.H. Zhu .Solid-state conversion of fly ash to effective adsorbents for Cu removal from wastewater[J].Journal of hazardous materials,2007(2):254-259. |
[36] | J.Z. Xu;Y.L. Zhou;Q. Chang;H.Q. Qu .Study on the factors of affecting the immobilization of heavy metals in fly ash-based geopolymers[J].Materials Letters,2006(6):820-822. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%