采用硬脂酸对氧化铈(CeO2)进行表面改性,并分别将CeO2和改性CeO2掺混到氯丁橡胶(CR)中,制得CeO2/CR和改性 CeO2/CR 复合材料.通过SEM、FT-IR、XRD 对改性 CeO2的结构进行了表征,研究了 CeO2/CR 和改性 CeO2/CR 复合材料的硫化性能、力学性能、耐老化性能和热稳定性.结果表明,改性 CeO2的晶型结构未发生改变并在其表面生成了硬脂酸铈盐.与添加未改性 CeO2相比,添加改性CeO2使CR的正硫化时间缩短了9．7％,CR 的力学性能、耐老化性能和热稳定性有不同程度的提高.
Surface modification process of cerium oxide (CeO2 )by stearic acid was investigated,CeO2 and modi-fied CeO2 reinforced neoprene (CR)was prepared by means of mixing.The structure of modified CeO2 was characterized by SEM,FT-IR and XRD,vulcanization properties,mechanical properties,aging resistance and thermal stability of CeO2/CR and modified CeO2/CR composite materials were evaluated.Results showed that crystal structure of modified CeO2 was not changed by modification process and stearate salt was generated on the surface.Compared with added unmodified CeO2 ,vulcanization time of CR was shortened by 9.7%,the me-chanical properties,aging resistance and thermal stability of CR enhanced in varying degrees by adding modified CeO2 .
参考文献
| [1] | Beomkeun Kim;Seong Beom Lee;Jayone Lee;Sehyun Cho;Hyungmin Park;Sanghoon Yeom;Sung Han Park .A Comparison Among Neo-Hookean Model, Mooney- Rivlin Model, and Ogden Model for Chloroprene Rubber[J].International Journal of Precision Engineering and Manufacturing,2012(5):759-764. |
| [2] | Kuwahara, H.;Sudo, S.;Iijima, M.;Ohya, S. .Dielectric properties of thermally degraded chloroprene rubber[J].Polymer Degradation and Stability,2010(12):2461-2466. |
| [3] | 钱伯章.全球氯丁橡胶市场现状分析[J].中国橡胶,2010(04):10-13. |
| [4] | Lity Alen Varghese;Eby Thomas Thachil .Studies on the adhesive properties of neoprene-phenolic blends[J].Journal of Adhesion Science and Technology: The International Journal of Theoredtical and Basic Aspects of Adhesion Science and Its Applications in All Areas of Technology,2004(2):181-193. |
| [5] | Sung-Seen Choi;Jong-Chul Kim .Chlorine Effect on Thermal Aging Behaviors of BR and CR Composites[J].Bulletin of the Korean Chemical Society,2010(9):2613-2617. |
| [6] | Takenoshita Yoichiro .Update on process in chloroprene rubber(CR)[J].Journal of the Society of Rubber Indus-try Japan,2005,78(02):81-82. |
| [7] | GilIen Kenneth T;Assink Roger A;Bernstein Robert .Condition monitoring approaches applied to the polychlo-roprene cable jacketing material[J].Polymer Degradation and Stability,2004,84(03):413-419. |
| [8] | Liu Zuohua;Zeng Fengjuan;Du Jun et al.Experimental investigation on curing performance of neoprene rubber modified by BBr3[J].Journal of Functional Materials,2013,44(16):2393-2396. |
| [9] | Faika F Hanna;Kamal N;Abdel-Nour;Salwa L Abdel-Messieh .Dielectric properties of some synthetic rubber mixtures:part Ⅰ.Neoprene-carbon black mixtures[J].Polymer Degradation and Stability,1992,35(01):29-52. |
| [10] | LUO Yongyue,YANG Changjin,WANG Yueqiong,HE Canzhong,ZHONG Jieping,LIAO Shuangquan,PENG Zheng,LIU Xingxun.Effect of neodymium stearate on cure and mechanical properties of epoxidized natural rubber[J].稀土学报（英文版）,2012(07):721-724. |
| [11] | Liu Li;Wang Cheng;Zhang Fazhong et al.Lumines-cence of EPDM rubber ultrafine fibers containing nano-dispersed Eu-complexs[J].Journal of Rare Earths,2012,30(09):860-865. |
| [12] | Miao Shui .Polymer surface modification and characterization of particulate calcium carbonate fillers[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2003(1/4):359-366. |
| [13] | 刘力,张立群,金日光.稀土/高分子复合材料的研究进展[J].中国稀土学报,2001(03):193-199. |
| [14] | 刘洋,李旭日,王娜,杨凤,方庆红.远红外橡胶功能复合材料的制备及在汽油活化中的应用研究[J].功能材料,2014(09):9057-9060. |
| [15] | 计臣,李智敏,吴友平.淀粉/NaAA/CR吸水复合材料的性能在去离子水和盐溶液中的差异[J].功能材料,2012(16):2161-2165. |
| [16] | Fu Hai .Application research of cerium oxide in natural rubber[D].Inner Mongolia:Inner Mongolia University of Science and Technology,2009. |
| [17] | Teng-fei Gan,Bao-qing Shentu,Zhi-xue Weng.MODIFICATION OF CeO2 AND ITS EFFECT ON THE HEAT-RESISTANCE OF SILICONE RUBBER[J].高分子科学（英文版）,2008(04):489-494. |
| [18] | 肖建斌.氧化铈对硅橡胶耐热性和耐油性的影响[J].有机硅材料,2008(01):28-31. |
| [19] | Gilbert M;Sutherland I;Guest A .Characterization of coated particulate filler[J].Journal of Materials Sci-ence,2000,35(02):391-397. |
| [20] | 曾凤娟,刘作华,左赵宏,杜军,陶长元.氯丁橡胶的改性研究进展[J].化工进展,2013(06):1347-1351. |
| [21] | Li Mei;Shi Zhenxue;Liu Zhaogang et al.Study on ce-rium oxide modified natural rubber[J].Journal of Rare Earths,2007,25(s):138-141. |
| [22] | 史振学,李梅,柳召刚,胡艳宏.稀土在橡胶生产中的应用[J].稀土,2006(02):75-80. |
| [23] | Ma Depeng;Tan Jinglin;Li Yuling.Curing char-acteristics,morphology,thermal stability,mechanicalproperties,and irradiation resistance of methylethylsili-cone/methylphenylsilicone rubber blends[J].Journal of Applied Polymer Science |
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