为了研究 Fe3 O 4形貌与其复合材料电磁吸收性能之间的关系,采用水热法制备了微粒和棒状两种形貌的 Fe3 O 4与石墨烯复合材料.利用 X 射线衍射(XRD)仪、透射电子显微镜(TEM)和矢量网络分析仪(VNA)对复合材料的结构、形貌以及电磁吸收性能进行了表征.结果表明,纳米 Fe3 O 4棒/石墨烯复合材料相比纳米 Fe3 O 4粒子/石墨烯具有更优异的电磁吸收性能,其在8~18 GHz 范围内小于-10 dB 频带宽9.8~17.9 GHz,说明材料的微波吸收性能和纳米粒子的形貌有关.
In order to study the relationship between the morphologies of Fe3 O 4 and the microwave absorption properties of its composites,Fe3 O 4 nanoparticles/graphene and Fe3 O 4 nanorod/graphene composites were pre-pared by hydrothermal method.The structure,morphology and microwave absorption properties of the com-posites were characterized by XRD,TEM and vector network analysis (VNA).The results indicated that the Fe3 O 4 nanorod/graphene composites had better microwave absorption ability than the Fe3 O 4 nanoparticles/gra-phene composites.The microwave absorption of Fe3 O 4 nanorod/graohene values less than -10 dB was in the ranges of 9.8-17.9 GHz,proving the microwave absorption performance greatly depends on the shape of nano-particles.
参考文献
[1] | Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].SCIENCE,2004,306(5696):666-669. |
[2] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
[3] | Matthew J. Allen;Vincent C. Tung;Richard B. Kaner .Honeycomb Carbon: A Review of Graphene[J].Chemical Reviews,2010(1):132-145. |
[4] | 魏从杰,段芳,倪忠斌,李晓婷,陈明清.聚苯胺纳米纤维/石墨烯复合物的制备及其电化学性能[J].功能材料,2013(04):562-565. |
[5] | Yanwu Zhu;Shanthi Murali;Weiwei Cai;Xuesong Li;Ji Won Suk;Jeffrey R. Potts;Rodney S. Ruoff .Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J].Advanced Materials,2010(35):3906-3924. |
[6] | SHUAI LIN;JINGHUA YU;FANGHUI WANG;YONGSHENG WEI;BAOGUO YUAN;HONG ZHU .MICROWAVE ABSORBING PROPERTIES OF CO/REDUCED GRAPHENE OXIDE IN KU-BAND[J].Functional materials letters,2013(4):1350042.1-1350042.4. |
[7] | Wang, Y.M.;Cao, X.;Liu, G.H.;Hong, R.Y.;Chen, Y.M.;Chen, X.F.;Li, H.Z.;Xu, B.;Wei, D.G. .Synthesis of Fe_3O_4 magnetic fluid used for magnetic resonance imaging and hyperthermia[J].Journal of Magnetism and Magnetic Materials,2011(23):2953-2959. |
[8] | 安静,何峻,赵栋梁,贺淑丽.Fe3O4纳米颗粒的溶剂热法制备及电磁特性研究[J].功能材料,2013(14):2047-2050,2055. |
[9] | Haiyan Lin;Hong Zhu;Hongfan Guo;Liufang Yu .Microwave-absorbing properties of Co-filled carbon nanotubes[J].Materials Research Bulletin,2008(10):2697-2702. |
[10] | Lan Zhang;Hong Zhu .Dielectric, Magnetic, And Microwave Absorbing Properties Of Multi-walled Carbon Nanotubes Filled With Sm_2o_3 Nanoparticles[J].Materials Letters,2009(2):272-274. |
[11] | Electromagnetic absorption properties of Sn-filled multi-walled carbon nanotubes synthesized by pyrolyzing[J].Materials Letters,2010(3):227. |
[12] | 聂海,凌味未,张怀武.低温烧结铁氧体/陶瓷复合材料的电磁性能研究[J].功能材料,2013(14):2014-2017. |
[13] | Peichao Lian;Xuefeng Zhu;Hongfa Xiang;Zhong Li;Weishen Yang;Haihui Wang .Enhanced cycling performance of Fe_3O_4-graphene nanocomposite as an anode material for lithium-ion batteries[J].Electrochimica Acta,2010(2):834-840. |
[14] | Hu, A.;Chen, X.;Tang, Y.;Tang, Q.;Yang, L.;Zhang, S..Self-assembly of Fe_3O_4 nanorods on graphene for lithium ion batteries with high rate capacity and cycle stability[J].Electrochemistry communications,2013:139-142. |
[15] | Marcano DC;Kosynkin DV;Berlin JM;Sinitskii A;Sun ZZ;Slesarev A;Alemany LB;Lu W;Tour JM .Improved Synthesis of Graphene Oxide[J].ACS nano,2010(8):4806-4814. |
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