双子型表面活性剂12-3-12与阴离子表面活性剂SDS混合系统在不同配比下生成不同的自组织体(包括胶束、囊泡、液晶)。分别以这些自组织体为模板,利用碳酸化法合成了具有贝壳珍珠层“砖-泥”结构的碳酸钙-环糊精仿生复合材料。以X射线衍射、红外光谱、扫描电子显微镜测试表征产品组成与形貌,通过不同类型的自组织体模板与碳酸钙-环糊精复合材料形貌的对比研究,探讨模板与材料形貌的关系,为新型材料的设计合成提供了新的思路。
Different self-assemblies in gemini surfactant 1 2-3-1 2/SDS mixed aqueous solution,including mi-celles,vesicles and liquid crystal,are used as templates to prepare calcium carbonate-cyclodextrin composite materials with brick-and-mortar structures like nacre.Structure of materials was studied by XRD,IR and SEM experiments.Relation between materials’morphologies and templates was investigated,and some new ideas to design and prepare new materials are provided.
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