均三嗪系列膨胀型阻燃剂具有抑烟、低毒、无腐蚀、阻燃效果佳等优点,在无卤膨胀阻燃高聚物领域具有很好的应用潜力。综述了均三嗪系列膨胀型阻燃剂的合成及应用,以三聚氰胺或三聚氯氰为基,通过化学反应重建或复配等方法可以得到一系列无卤膨胀阻燃剂,同时介绍了上述阻燃剂对高聚物的阻燃情况,最后提出了均三嗪系列阻燃剂未来的发展方向。
1 ,3 ,5-triazine-based intumescent flame retardants exhibit excellent potential applications in the field of halogen-free retarded polymers,owing to their good characteristics like smoke suppression,low toxicity,no corrosion,high flame retardant efficiency,etc.Their recent researches and developments were reviewed on the synthesis and application of 1,3,5-triazine-based intumescent flame retardants,the compounds/derivatives based on melamine and cyanuric chloride.Finally,the developing trend of 1 ,3 ,5-triazine-based intumescent flame retardants was prospected.
参考文献
[1] | Shui-Yu Lu;Ian Hamerton .Recent developments in the chemistry of halogen-free flame retardant polymers[J].Progress in Polymer Science,2002(8):1661-1712. |
[2] | Jimenez M;Duquesne S;Bourbigot S .Intumescent fire protective coating: Toward a better understanding of their mechanism of action[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2006(1/2):16-26. |
[3] | Laoutid, F;Bonnaud, L;Alexandre, M;Lopez-Cuesta, JM;Dubois, P .New prospects in flame retardant polymer materials: From fundamentals to nanocomposites[J].Materials Science & Engineering. R, Reports,2009(3):100-125. |
[4] | Bourbigot Serge;Duquesne Sophie .Fire retardant poly-mers:recent developments and opportunities[J].Journal of Materials Chemistry,2007,17(22):2283-2300. |
[5] | Mngomezulu Mfiso E;John Maya J;Jacobs Valencia et al.Review on flammability of biofibres and biocomposites[J].Carbohydrate Polymers,2014,111(13):149-182. |
[6] | Chen Li;Wang Yuzhong .A review on flame retardant technology in China.Part Ⅰ:development of flame re-tardants[J].Polymers for Advanced Technologies,2010,21(1):1-26. |
[7] | 尹朝露,李风,张泽江.无卤阻燃全水发泡聚氨酯硬质泡沫的结构与性能研究[J].功能材料,2013(z2):285-288. |
[8] | Yu, GP;Liu, C;Wang, JY;Chu, CB;Jian, XG .Synthesis of phenyl-s-triazine-based copoly(aryl ether)s derived from hydroquinone and resorcinol[J].Polymer Degradation and Stability,2009(11):2065-2071. |
[9] | Yang, K.;Xu, M.-J.;Li, B. .Synthesis of N-ethyl triazine-piperazine copolymer and flame retardancy and water resistance of intumescent flame retardant polypropylene[J].Polymer Degradation and Stability,2013(7):1397-1406. |
[10] | Hongbo Liang;Wenfang Shi;Ming Gong .Expansion behaviour and thermal degradation of tri(acryloyloxyethyl) phosphate/methacrylated phenolic melamine intumescent flame retardant system[J].Polymer Degradation and Stability,2005(1):1-8. |
[11] | 莫羡忠,廖正福,甘春芳.三聚氰胺磷酸盐的制备及其在膨胀型防火涂层中的应用[J].功能材料,2004(z1):1725-1727. |
[12] | 宝冬梅,刘吉平.六对醛基苯氧基环三磷腈的合成及其热性能研究[J].功能材料,2013(03):396-400. |
[13] | Liu Y;Wang Q .Catalytic action of phospho-tungstic acid in the synthesis of melamine salts of pentaerythritol phosphate and their synergistic effects in flame retarded polypropylene[J].Polymer Degradation and Stability,2006(10):2513-2519. |
[14] | Chen YH.;Liu YA.;Wang Q.;Yin HA.;Aelmans N.;Kierkels R. .Performance of intumescent flame retardant master batch synthesized through twin-screw reactively extruding technology: effect of component ratio[J].Polymer Degradation and Stability,2003(2):215-224. |
[15] | Shiqiang Song;Jiajun Ma;Ke Cao;Guanjun Chang;Yawen Huang;Junxiao Yang.Synthesis of a novel dicyclic silicon-/phosphorus hybrid and its performance on flame retardancy of epoxy resin[J].Polymer Degradation and Stability,2014:43-52. |
[16] | Gong-Peng Lin;Li Chen;Xiu-Li Wang .Aluminum Hydroxymethylphosphinate and Melamine Pyrophosphate: Synergistic Flame Retardance and Smoke Suppression for Glass Fiber Reinforced Polyamide 6[J].Industrial & Engineering Chemistry Research,2013(44):15613-15626. |
[17] | Zhong Yuhua;Wu Wei;Wu Ren et al.The flame re-tarding mechanism of the novolac as char agent with the fire retardant containing phosphorous-nitrogen in ther-moplastic poly(ether ester)elastomer system[J].Poly-mer Degradation and Stability,2014,105:166-177. |
[18] | 王宇旋,姜宏伟.交联三嗪类聚合物的制备及其成炭性研究[J].高分子学报,2009(04):325-330. |
[19] | Giacomelli Giampaolo;Porcheddu Andrea.1,3,5-Tria-zines comprehensive heterocyclic chemistry Ⅲ[M].Ox-ford:Elsevier,2008:197-290. |
[20] | Prokhorov, A.M.;Kozhevnikov, D.N. .Reactions of triazines and tetrazines with dienophiles (review)[J].Chemistry of heterocyclic compounds,2012(8):1153-1176. |
[21] | 鲁建,刘柯,王玉忠.三嗪衍生物的合成及其用于ABS的阻燃研究[J].四川大学学报(自然科学版),2002(03):513-517. |
[22] | Lijun Qian;Yong Qiu;Jing Liu;Fei Xin;Yajun Chen .The Flame Retardant Group-Synergistic-Effect of a Phosphaphenanthrene and Triazine Double-Group Compound in Epoxy Resin[J].Journal of Applied Polymer Science,2014(3):39709-1-39709-8. |
[23] | Wang Xin;Hu Yan;Song Lei et al.Effect of a triazine ring-containing charring agent on fire retardancy and thermal degradation of intumescent flame retardant ep-oxy resin[J].Polymers for Advanced Technologies,2011,22(12):2480-2487. |
[24] | Xiao-Ping Hu;Ya-Lan Li;Yu-Zhong Wang .Synergistic Effect of the Charring Agent on the Thermal and Flame Retardant Properties of Polyethylene[J].Macromolecular materials and engineering,2004(2):208-212. |
[25] | 刘刚,刘述梅,生启,赵建青,章永化,张正虎.含磷三嗪环聚合物的合成与表征[J].石油化工,2007(02):173-177. |
[26] | Xu, Z.-Z.;Huang, J.-Q.;Chen, M.-J.;Tan, Y.;Wang, Y.-Z. .Flame retardant mechanism of an efficient flame-retardant polymeric synergist with ammonium polyphosphate for polypropylene[J].Polymer Degradation and Stability,2013(10):2011-2020. |
[27] | Xinqing Su;Yuwen Yi;Jie Tao;Hongqiang Qi;Dongyan Li.Synergistic effect between a novel triazine charring agent and ammonium polyphosphate on flame retardancy and thermal behavior of polypropylene[J].Polymer Degradation and Stability,2014:12-20. |
[28] | Yun Liu;Jing Zhao;Cheng-Liang Deng .Flame-Retardant Effect of Sepiolite on an Intumescent Flame-Retardant Polypropylene System[J].Industrial & Engineering Chemistry Research,2011(4):2047-2054. |
[29] | C.Gao;D.Yan .Hyperbranched polymers:from synthesis to applications[J].Progress in Polymer Science,2004(3):183-275. |
[30] | 陈荣国,房小明,肖荔人,陈庆华.超支化聚酰胺酯的研究进展[J].材料工程,2009(11):92-98. |
[31] | 靳玉娟,高鹏翔,钱立军,杨楠,徐佳明,杨林焱.超支化芳胺三嗪聚合物的合成及其对聚丙烯阻燃性能影响的研究[J].中国塑料,2013(05):77-81. |
[32] | Sibdas Singha Mahapatra;Niranjan Karak .s-Triazine containing flame retardant hyperbranched polyamines: Synthesis, characterization and properties evaluation[J].Polymer Degradation and Stability,2007(6):947-955. |
[33] | Ke, CH;Li, J;Fang, KY;Zhu, QL;Zhu, J;Yan, Q;Wang, YZ .Synergistic effect between a novel hyperbranched charring agent and ammonium polyphosphate on the flame retardant and anti-dripping properties of polylactide[J].Polymer Degradation and Stability,2010(5):763-770. |
[34] | Li, J.;Ke, C.;Xu, L.;Wang, Y. .Synergistic effect between a hyperbranched charring agent and ammonium polyphosphate on the intumescent flame retardance of acrylonitrile-butadiene- styrene polymer[J].Polymer Degradation and Stability,2012(7):1107-1113. |
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