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用原位生成法成功制备了纳米 CdS/壳聚糖复合粒子,并用于染料废水中甲基橙的可见光催化降解,研究了相关因素对甲基橙光降解率的影响.结果表明,该光催化降解反应为一级反应;酸性媒介更有利于甲基橙光催化降解;适量的复合粒子在第6次重复使用时,反应60 min甲基橙的降解率仍可达81.51%,显示出好的抗光腐蚀能力和重复使用寿命.

The nano-CdS/chitosan composite particles were prepared successfully by using in-situ synthesis method,the photocatalytic degradation of methyl orange wastewater using the catalyst was investigated under visible light,the influences of correlative factors on methyl orange degradation rate were investigated.The ex-perimental results indicated that oxidation reaction of photocatalytic degradation was first order reaction,the methyl orange wastewater could be more efficiently degradated in an acid media,when the proper dosage of composite particles were used for the sixth times,the degradation rate of methyl orange was still 81.51% after 60 min,indicating the composite particles had a good ability to inhibit light corrosion and long reusage life.

参考文献

[1] Zhu Huayue;Jiang Ru;Xiao Ling et al.Photocatalytic decolorization and degradation of Congo Red on innovative crosslinked chitosan/nano-CdS composite catalyst under visible light irradiation[J].Journal of Hazardous Materi-als,2009,169(3):933-940.
[2] Hirai T.;Watanabe T.;Shiojiri S.;Komasawa I.;Miyamoto M. .Effects of thiols on photocatalytic properties of nano-CdS-polythiourethane composite particles[J].Journal of Chemical Engineering of Japan,1998(6):1003-1006.
[3] Guoqing Guan;Tetsuya Kida;Katsuki Kusakabe;Kunio Kimura;Eiichi Abe .Photocatalytic activity of CdS nanoparticles incorporated in titanium silicate molecular sieves of ETS-4 and ETS-10[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1):71-78.
[4] Lee J;Park H;Choi W .Selective photocatalytic oxidation of NH3 to N2 on platinized TiO2 in water[J].Environmental Science and Technology,2002,36(7):5462-5468.
[5] 陈晓慧,柳丽芬,杨凤林,张兴文,余济美.CdS/TiO2光催化去除水体中氨氮的研究[J].感光科学与光化学,2007(02):89-101.
[6] 朱华跃,蒋茹,肖玲,管玉江.仿生矿化法制备壳聚糖/纳米CdS复合粒子对猩红B光催化降解研究[J].环境工程学报,2009(04):664-668.
[7] Sadia Ameen;M. Shaheer Akhtar;Young Soon Kim.Synthesis and electrochemical impedance properties of CdS nanoparticles decorated polyaniline nanorods[J].Chemical engineering journal,2012:806-812.
[8] Sahraei R;Darafarin S .Preparation of nanocrystalline Ni doped ZnS thin films by ammonia-free chemical bath dep-osition method and optical properties[J].Journal of Lu-minescence,2014,149(5):170-175.
[9] Chen Jingni;Jiang Fang;Chen Huan .Preparation of mag-netic MCM-4/CdS composite and its visible light photo-catalytic performance[J].Journal of Functional Materi-als,2013,44(20):3007-3011.
[10] 段萍,罗玉萍,朱忠其,张瑾,柳清菊.锌掺杂TiO2光催化剂的研究[J].功能材料,2014(06):6016-6019.
[11] 沈斌,蒋茹,朱华跃.H2O2辅助TiO2/CdS/壳聚糖复合膜光催化甲基橙脱色研究[J].安全与环境学报,2010(02):25-29.
[12] 胡志彪,周云龙,张巧玲,童长青,陈武华,丁马太.纳米ZnO/高岭土复合材料的制备及性能研究[J].功能材料,2014(05):5024-5026.
[13] Narayanasamy Sobana;Manickavasakam Muruganandam;Meenakshisundaram Swaminathan .Characterization of AC-ZnO catalyst and its photocatalytic activity on 4-acetylphenol degradation[J].Catalysis Communications,2008(2):262-268.
[14] Wang Kai;Di Lanbo;Zhang Lijuan et al.Ionic liquid as-sisted synthesis and properties of mesoporous magnetic Ti02/CoFe2 O4 photocatalysts[J].Journal of Functional Materials,2014,45(10):10079-10083.
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